Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Berrin Topuz

doi:10.18185/erzifbed.469433

Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Öz

Mikrokristal naftalin (MN) üzerinde pH 3.0-8.0 aralığında potasyum 2,6-dimetilmorfolinditiyokarbamat (KMDMMDTC) ligantı kullanılarak büyük hacimli sulu çözeltilerden Cu(II) iyonu önderiştirilmiştir. Cu(II)-DMMDTC kompleksi içeren MN, 5 mL asetonda çözülerek Cu(II) iyonu kör çözeltiye karşı 431 nm’de spektrofotometrik metot ile tayin edildi. pH, numune çözeltisinin hacmi, DMMDTC yüklü MN miktarı, çalkalama süresi, yabancı iyon etkisi gibi katı faz ekstraksiyon (SPE) metodunun temel parametreleri incelendi. Aseton çözeltisinde 0,09 µgmL^-1 tayin sınırı ile lineer kalibrasyon aralığı 0,05-5,0 µgmL^-1’dir. Sudaki potansiyel yabancı iyonların etkisi araştırıldı ve önerilen metot ilaç ve çevresel numunelerden Cu(II) iyonunun tayini için uygulanarak % 90 üzerinde geri kazanım değerleri elde edildi. Doğruluk, sertifikalı referans madde NW-TMDA-70.2 analizi ve geri kazanım deneyleri ile değerlendirildi.

Anahtar Kelimeler

Potasyum-2-6-dimetilmorfolinditiyokarbamat,SPE metot,Eser Cu(II) tayini.

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Berrin Topuz
Türkiye

Yayımlanma Tarihi

24 Mart 2019

Gönderilme Tarihi

11 Ekim 2018

Kabul Tarihi

14 Mart 2019

Yayımlandığı Sayı

Yıl 2019 Cilt: 12 Sayı: 1

DOI

https://doi.org/10.18185/erzifbed.469433

IZ

https://izlik.org/JA77CW47RZ

Kaynak Göster

RIS / Bibtex

APA

Topuz, B. (2019). Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology, 12(1), 367-378. https://doi.org/10.18185/erzifbed.469433

AMA

1.Topuz B. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 2019;12(1):367-378. doi:10.18185/erzifbed.469433

Chicago

Topuz, Berrin. 2019. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology 12 (1): 367-78. https://doi.org/10.18185/erzifbed.469433.

EndNote

Topuz B (01 Mart 2019) Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology 12 1 367–378.

IEEE

[1]B. Topuz, “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”, Erzincan University Journal of Science and Technology, c. 12, sy 1, ss. 367–378, Mar. 2019, doi: 10.18185/erzifbed.469433.

ISNAD

Topuz, Berrin. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology 12/1 (01 Mart 2019): 367-378. https://doi.org/10.18185/erzifbed.469433.

JAMA

1.Topuz B. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 2019;12:367–378.

MLA

Topuz, Berrin. “Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini”. Erzincan University Journal of Science and Technology, c. 12, sy 1, Mart 2019, ss. 367-78, doi:10.18185/erzifbed.469433.

Vancouver

1.Berrin Topuz. Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini. Erzincan University Journal of Science and Technology. 01 Mart 2019;12(1):367-78. doi:10.18185/erzifbed.469433

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