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Yengeç Kitininden Kitosan Üretimi

Year 2017, Volume: 10 Issue: 2, 213 - 219, 22.12.2017

Abstract

Kitosan, doğada selülozdan sonra en çok
bulunan kitinin deasetilasyonu sonucu elde edilen suda çözünebilen bir
aminopolisakkarittir. Günümüzde kitosan tekstilde, kozmetikte, tıbbi kullanımlarda,
tarım alanlarında vb. sektörlerde kullanım alanı bulmuştur. Kitosanın çeşitli
alanlarda değerlendirilmesiyle hem ekonomik açıdan kazanç hem de çevre kirliliği
ve doğal döngü açısından oldukça büyük yarar sağlanmaktadır. Kitosan yapısı itibariyle
antibakteriyel, antifungal etkilere sahip olmakla beraber gerek insan sağlığına
gerekse de doğaya hiçbir zararı yoktur. Bu çalışmada kitin ve kitosanın
özelliklerinden, kitosanın üretiminden ve son olarak yengeç kitininden farklı
sürelerde üretilen kitosanların yıkama, sabit tartım ve asetilasyon dereceleri
hakkında bilgi verilmiştir.

References

  • Burkhanova, N.D., Yugai, S.M., Pulatova, K.P., Voropaeva, G.V., Rashidova, S.S., 2000. Structural Investigations of Chitin and its Deacetylation Products. Chemistry of Natural Compounds, 36, 352-355.
  • Geçer, A., Kavak, D., Salgın, U., Yıldız, N., Erol, M., Çalımlı, A., 2004. Kitin/Kitosan Lifler Üzerine Kalsiyum Fosfat Birikiminin İncelenmesi. 11. Ulusal Kimya Mühendisliği Kongresi, 2-5 Eylül, Eskişehir.
  • Gökçe, Y., 2008. Kitosan Nanoparçacıklarının Sentezi. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, 81 s., Ankara.
  • Guang, W.Y., 2002. The Effect of Chitosan and its Derivatives on the Dyeability of Silk. Hong Kong Polytechnic University, Ph.D.Thesis,.100s., Hong Kong.
  • Guo, X.F., Kikuchi, K., Matahira, Y., Sakai, K., Ogawa, K., 2002. Water-Soluble Chitin of Low Degree of Deacetylation, Journal of Carbohydrate Chemistry, 21, 149-161.
  • Han, Z.,Zeng, Y., Lu, H., Zhang, L., 2015. Determination of the Degree of Acetylation and the Distribution of Acetyl Groups in Chitosan by HPLC Analysis of Nitrous Acid Degraded and PMP Labeled Products. Carbohydrate Research, 413(2), 75-84.
  • Illum, L., (1998). Chitosan and its Use as a Pharmaceutical Excipient, Pharmaceutical Research, 15, 1326-1331.
  • Kristl, J., Smid-Korbar, J., Strue, E., Schara, M., Rupprecht, H., 1993. Hydrocolloids and gels of chitosan as drug carriers, International Journal of Pharmaceutics, 99, 13-19.
  • Liu, D., Wei, Y., Yao, P., Jiang, L., 2006. Determination of the Degree of Acetylation of Chitosan by UV Spectrophotometry Using Dual Standards. Carbohydrate Research, 341(6), 782-785.
  • Meyers, S.P., No, H.K., Lee, K.S., 1989. Isolation and characterization of chitin fromcrawfish shell waste, Journal of Agricultural and Food Chemistry, 37, 575.
  • Muzzarelli, R.A.A., Boudrant, J., Meyer, D., Manno, N., DeMarchis, M., Paoletti, M.G., 2012. Current Views on Fungal Chitin/Chitosan, Human Chitinases, Food Preservation, Glucans, Pectins and Inulin: A Tribute to Henri Braconnot, Precursor of the Carbohydrate Polymers Science, on the Chitin Bicentennial. Carbohydrate Polymers, 87, 995-1012.
  • Nemtsev, S.V., Gamzazade, A.I., Rogozhin, S.V., Bykova, V.M., Bykov, V.P., 2002. Deacetylation of chitin under homogeneous conditions. Applied Biochemistry and Microbiology, 38 521-526.
  • Özbek, E.N., 2010. Serbest Dişeti Grefti Verici Bölge İyileşmesi Üzerine Kitosan Filmin Etkinliğinin Değerlendirilmesi. Başkent Üniversitesi, Sağlık Bilimleri Enstitüsü, Doktora Tezi, 62 s., Ankara.
  • Singla, A.K., Chawla, M., 2001. Chitosan: some pharmaceutical and biological aspects-an update. Journal of Pharmacy and Pharmacology, 53, 1047-1067.
  • Taşar, C.Ö., 2015. Batık Kültürde Steril Olmayan Koşullarda Fungal Kitosan Üretimi. Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, 83 s., Erzurum.

Production of Chitosan the Crab Chitin

Year 2017, Volume: 10 Issue: 2, 213 - 219, 22.12.2017

Abstract



Chitosan
is a water-soluble amino polysaccharide obtained after deacetylation of chitin,
which is most commonly found after cellulose in nature. Today, chitosan is used
in textiles, cosmetics, medical uses, agricultural fields etc. sectors have
found use. The evaluation of chitosan in various fields provides a great
benefit in terms of economic profit as well as environmental pollution and
natural cycle. With its chitosan structure, it has antibacterial, antifungal
effects, and there is no harm to human health or nature. In this study,
information about the characteristics of chitin and chitosan, the production of
chitosan, and finally the rinsing, fixed weighing and acetylation ratios of
chitosan produced at different times from the crab chitin were given.



References

  • Burkhanova, N.D., Yugai, S.M., Pulatova, K.P., Voropaeva, G.V., Rashidova, S.S., 2000. Structural Investigations of Chitin and its Deacetylation Products. Chemistry of Natural Compounds, 36, 352-355.
  • Geçer, A., Kavak, D., Salgın, U., Yıldız, N., Erol, M., Çalımlı, A., 2004. Kitin/Kitosan Lifler Üzerine Kalsiyum Fosfat Birikiminin İncelenmesi. 11. Ulusal Kimya Mühendisliği Kongresi, 2-5 Eylül, Eskişehir.
  • Gökçe, Y., 2008. Kitosan Nanoparçacıklarının Sentezi. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, 81 s., Ankara.
  • Guang, W.Y., 2002. The Effect of Chitosan and its Derivatives on the Dyeability of Silk. Hong Kong Polytechnic University, Ph.D.Thesis,.100s., Hong Kong.
  • Guo, X.F., Kikuchi, K., Matahira, Y., Sakai, K., Ogawa, K., 2002. Water-Soluble Chitin of Low Degree of Deacetylation, Journal of Carbohydrate Chemistry, 21, 149-161.
  • Han, Z.,Zeng, Y., Lu, H., Zhang, L., 2015. Determination of the Degree of Acetylation and the Distribution of Acetyl Groups in Chitosan by HPLC Analysis of Nitrous Acid Degraded and PMP Labeled Products. Carbohydrate Research, 413(2), 75-84.
  • Illum, L., (1998). Chitosan and its Use as a Pharmaceutical Excipient, Pharmaceutical Research, 15, 1326-1331.
  • Kristl, J., Smid-Korbar, J., Strue, E., Schara, M., Rupprecht, H., 1993. Hydrocolloids and gels of chitosan as drug carriers, International Journal of Pharmaceutics, 99, 13-19.
  • Liu, D., Wei, Y., Yao, P., Jiang, L., 2006. Determination of the Degree of Acetylation of Chitosan by UV Spectrophotometry Using Dual Standards. Carbohydrate Research, 341(6), 782-785.
  • Meyers, S.P., No, H.K., Lee, K.S., 1989. Isolation and characterization of chitin fromcrawfish shell waste, Journal of Agricultural and Food Chemistry, 37, 575.
  • Muzzarelli, R.A.A., Boudrant, J., Meyer, D., Manno, N., DeMarchis, M., Paoletti, M.G., 2012. Current Views on Fungal Chitin/Chitosan, Human Chitinases, Food Preservation, Glucans, Pectins and Inulin: A Tribute to Henri Braconnot, Precursor of the Carbohydrate Polymers Science, on the Chitin Bicentennial. Carbohydrate Polymers, 87, 995-1012.
  • Nemtsev, S.V., Gamzazade, A.I., Rogozhin, S.V., Bykova, V.M., Bykov, V.P., 2002. Deacetylation of chitin under homogeneous conditions. Applied Biochemistry and Microbiology, 38 521-526.
  • Özbek, E.N., 2010. Serbest Dişeti Grefti Verici Bölge İyileşmesi Üzerine Kitosan Filmin Etkinliğinin Değerlendirilmesi. Başkent Üniversitesi, Sağlık Bilimleri Enstitüsü, Doktora Tezi, 62 s., Ankara.
  • Singla, A.K., Chawla, M., 2001. Chitosan: some pharmaceutical and biological aspects-an update. Journal of Pharmacy and Pharmacology, 53, 1047-1067.
  • Taşar, C.Ö., 2015. Batık Kültürde Steril Olmayan Koşullarda Fungal Kitosan Üretimi. Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, 83 s., Erzurum.
There are 15 citations in total.

Details

Subjects Engineering
Journal Section Makaleler
Authors

Ufuk ELİBÜYÜK

Meliha OKTAV BULUT

Publication Date December 22, 2017
Published in Issue Year 2017 Volume: 10 Issue: 2

Cite

APA ELİBÜYÜK, U., & OKTAV BULUT, M. (2017). Production of Chitosan the Crab Chitin. Erzincan University Journal of Science and Technology, 10(2), 213-219.