The Effect of Cu doping on Fatigue Properties of TiZrNbN Coatings
Year 2020,
Volume: 13 Issue: 1, 181 - 189, 20.03.2020
Hossein Ahmad Aghdam
Ayşenur Keleş
,
Ozlem Baran
,
Yaşar Totik
,
İhsan Efeoglu
Abstract
The
fatigue properties are very important for cutting tools due to service life. To
improve fatigue properties of cutting tools, transition metal nitrides with
soft metal (Cu, Ni etc.) have been coated on cutting tool materials. To
investigate Cu effect on fatigue properties, TiZrNbN and Cu doped TiZrNbN
coatings were deposited on M2 high speed steel using reactive closed field
unbalanced magnetron sputtering (CFUBMS) in bias voltage of -80V, coating
pressure of 0.33 Pa and Cu target current of 0.6 A. Microstructure properties
of the coatings were determined by X-Ray Diffraction (XRD), Scanning Electron
Microscope (SEM) and Energy Dispersive Spectroscopy (EDS). Mechanical
properties of the coatings were examined with microhardness tester and scratch
tester. Fatigue properties of the coatings were examined using multi-pass
scratch tester. According to the results, the microhardness of Cu doped TiZrNbN
is better than TiZrNbN. On the other hand, the adhesion and fatigue properties
of TiZrNbN are the highest.
References
- 1. O. Baran, A. Keles, H. Cicek, Y. Totik, and I. Efeoglu: 'The mechanical and tribological properties of Ti Nb, V N films on the Al-2024 alloy', Surf. Coat. Technol., 2017, 332, 312-318.2. J. Stallard, S. Poulat, and D. G. Teer: 'The study of the adhesion of a TiN coating on steel and titanium alloy substrates using a multi-mode scratch tester', Tribol. Int., 2006, 39(2), 159-166.3. A. Bloyce, P. Y. Qi, H. Dong, and T. Bell: 'Surface modification of titanium alloys for combined improvements in corrosion and wear resistance', Surf. Coat. Technol., 1998, 107(2-3), 125-132.4. F. Bidev, O. Baran, E. Arslan, Y. Totik, and I. Efeoglu: 'Adhesion and fatigue properties of Ti/TiB2/MoS2 graded-composite coatings deposited by closed-field unbalanced magnetron sputtering', Surf. Coat. Technol., 2013, 215, 266-271.5. C. Montero-Ocampo, E. A. Ramirez-Ceja, and J. A. Hidalgo-Badillo: 'Effect of codeposition parameters on the hardness and adhesion of TiVN coatings', Ceramics International, 2015, 41(9), 11013-11023.6. B. A. Latella, B. K. Gan, K. E. Daviesb, D. R. McKenzie, and D. G. McCulloch: 'Titanium nitride/vanadium nitride alloy coatings: mechanical properties and adhesion characteristics', Surf. Coat. Technol., 2006, 200(11), 3605-3611.7. A. Keles, H. Cicek, O. Baran, Y. Totik, and I. Efeoglu: 'Determining the critical loads of V and Nb doped ternary TiN-based coatings deposited using CFUBMS on steels', Surf. Coat. Technol., 2017, 332, 168-173.8. I. Grimberg, V. N. Zhitomirsky, R. L. Boxman, S. Goldsmith, and B. Z. Weiss: 'Multicomponent Ti-Zr-N and Ti-Nb-N coatings deposited by vacuum arc', Surf. Coat. Technol., 1998, 108(1-3), 154-159.9. V. Y. Fominski, S. N. Grigoriev, J. P. Celis, R. I. Romanov, and V. B. Oshurko: 'Structure and mechanical properties of W-Se-C/diamond-like carbon and W-Se/diamond-like carbon bi-layer coatings prepared by pulsed laser deposition', Thin Solid Films, 2012, 520(21), 6476-6483.10. Y. Alajlani, F. Placido, D. Gibson, H. O. Chu, S. G. Song, L. Porteous, and S. Moh: 'Nanostructured ZnO films prepared by hydro-thermal chemical deposition and microwave-activated reactive sputtering', Surf. Coat. Technol., 2016, 290, 16-20.11. F. Movassagh-Alanagh, A. Abdollah-Zadeh, M. Aliofkhazraei, and M. Abedi: 'Improving the wear and corrosion resistance of Ti-6Al-4V alloy by deposition of TiSiN nanocomposite coating with pulsed-DC PACVD', Wear, 2017, 390-391, 93-103.12. F. X. Ye and X. Sun: 'Nanoindentation response analysis of TiN-Cu coating deposited by magnetron sputtering', Progress in Natural Science-Materials International, 2018, 28(1), 40-44.13. P. J. Kelly and R. D. Arnell: 'Magnetron sputtering: a review of recent developments and applications', Vacuum, 2000, 56(3), 159-172.14. L. Kara, T. Kucukomeroglu, O. Baran, I. Efeoglu, and K. Yamamoto: 'Microstructure, Mechanical, and Scratch Resistance Properties of TiAlCrNbN-Graded Composite Coating Deposited on AISI H13 Steel Substrate with Pulsed DC Closed Field Unbalanced Magnetron Sputtering Method', Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science, 2014, 45A(4), 2123-2131.15. S. Gangopadhyay, R. Acharya, A. K. Chattopadhyay, and S. Paul: 'Effect of substrate bias voltage on structural and mechanical properties of pulsed DC magnetron sputtered TiN-MoSx composite coatings', Vacuum, 2010, 84(6), 843-850.16. A. D. Pogrebnjak, A. A. Bagdasaryan, V. M. Beresnev, U. S. Nyemchenko, V. I. Ivashchenko, Y. O. Kravchenko, Z. K. Shaimardanov, S. V. Plotnikov, and O. Maksakova: 'The effects of Cr and Si additions and deposition conditions on the structure and properties of the (Zr-Ti-Nb)N coatings', Ceramics International, 2017, 43(1), 771-782.17. L. Sadowski, J. Hola, S. Czarnecki, and D. H. Wang: 'Pull-off adhesion prediction of variable thick overlay to the substrate', Automation in Construction, 2018, 85, 10-23.18. Q. W. Qiu and D. V. Lau: 'A novel approach for near-surface defect detection in FRP-bonded concrete systems using laser reflection and acoustic-laser techniques', Construction and Building Materials, 2017, 141, 553-564.19. J. K. Du, B. R. Tittmann, and H. S. Ju: 'Evaluation of film adhesion to substrates by means of surface acoustic wave dispersion', Thin Solid Films, 2010, 518(20), 5786-5795.20. Y. Fizi, Y. Mebdoua, H. Lahmar, S. Djeraf, and S. Benbahouche: 'Adhesion of FeCrNiBSi-(W-Ti)C wire-arc deposited coatings onto carbon steel substrates determined by indentation measurements and modeling', Surf. Coat. Technol., 2015, 268, 310-316.21. O. S. Heavens: 'Some factors influencing the adhesion of films produced by vacuum evaporation', Journal de Physique et le Radium, , 1950, 11, 355-360.22. S. J. Bull and D. S. Rickerby: 'MULTI-PASS SCRATCH TESTING AS A MODEL FOR ABRASIVE WEAR', Thin Solid Films, 1989, 181, 545-553.23. F. Yildiz and A. Alsaran: 'Multi-pass scratch test behavior of modified layer formed during plasma nitriding', Tribol. Int., 2010, 43(8), 1472-1478.24. J. von Stebut: 'Multi-mode scratch testing - a European standards, measurements and testing study', Surf. Coat. Technol., 2005, 200(1-4), 346-350.25. G. A. Rodriguez-Castro, R. C. Vega-Moron, A. Meneses-Amador, H. W. Jimenez-Diaz, J. A. Andraca-Adame, I. E. Campos-Silva, and M. E. P. Pardave: 'Multi-pass scratch test behavior of AISI 316L borided steel', Surf. Coat. Technol., 2016, 307, 491-499.26. I. Efeoglu and R. D. Arnell: 'Multi-pass sub-critical load testing of titanium nitride coatings', Thin Solid Films, 2000, 377, 346-353.27. K. V. Ezirmik and S. Rouhi: 'Influence of Cu additions on the mechanical and wear properties of NbN coatings', Surf. Coat. Technol., 2014, 260, 179-185.28. J. Musil: 'Hard and superhard nanocomposite coatings', Surf. Coat. Technol., 2000, 125(1-3), 322-330.29. S. Veprek and S. Reiprich: 'A concept for the design of novel superhard coatings', Thin Solid Films, 1995, 268(1-2), 64-71.30. R. Jacobs, J. Meneve, G. Dyson, D. G. Teer, N. M. Jennett, P. Harris, J. von Stebut, C. Comte, P. Feuchter, A. Cavaleiro, H. Ronkainen, K. Holmberg, U. Beck, G. Reiners, and C. D. Ingelbrecht: 'A certified reference material for the scratch test', Surf. Coat. Technol., 2003, 174, 1008-1013.31. G. A. Gogotsi: 'Criteria of ceramics fracture (edge chipping and fracture toughness tests)', Ceramics International, 2013, 39(3), 3293-3300.32. A. C. FischerCripps and B. R. Lawn: 'Stress analysis of contact deformation in quasi-plastic ceramics', Journal of the American Ceramic Society, 1996, 79(10), 2609-2618.33. S. Kataria, N. Kumar, S. Dash, R. Ramaseshan, and A. K. Tyagi: 'Evolution of deformation and friction during multimode scratch test on TiN coated D9 steel', Surf. Coat. Technol., 2010, 205(3), 922-927.
Cu ilavesinin TiZrNbN Kaplamaların Yorulma Özelliklerine Etkisi
Year 2020,
Volume: 13 Issue: 1, 181 - 189, 20.03.2020
Hossein Ahmad Aghdam
Ayşenur Keleş
,
Ozlem Baran
,
Yaşar Totik
,
İhsan Efeoglu
Abstract
Yorulma
özellikleri, kullanım ömrü nedeniyle kesme aletleri için çok önemlidir. Kesici
takımların yorulma özelliklerini iyileştirmek için kesici takım malzemeleri
üzerine yumuşak metalle (Cu, Ni vb.) Geçiş metali nitrürleri kaplanmıştır.
Yorulma özellikleri üzerindeki Cu etkisini araştırmak için, TiZrNbN ve Cu
katkılı TiZrNbN kaplamalar, -80V'luk ön gerilim voltajında, 0.33 Pa'lık kaplama
basıncı ve Cu hedef akımında 0.6 A değerinde reaktif kapalı alan dengesiz manyetik
alanda sıçratma (CFUBMS) kullanılarak M2 yüksek hızlı çelik üzerinde
biriktirildi. Kaplamaların mikro yapı özellikleri X-Ray Difraktometri (XRD),
Taramalı Elektron Mikroskop (SEM) ve Enerji Dağıtıcı Spektroskopi (EDS) ile
belirlenmiştir. Kaplamaların mekanik özellikleri microhardness test cihazı ve çizik
test cihazı ile incelenmiştir. Kaplamaların yorulma özellikleri çok geçişli
çizik test cihazı kullanılarak incelenmiştir. Sonuçlara göre, Cu katkılı
TiZrNbN'nin mikro sertliği TiZrNbN'den daha iyidir. Öte yandan, TiZrNbN'nin
yapışma ve yorulma özellikleri en yüksektir
References
- 1. O. Baran, A. Keles, H. Cicek, Y. Totik, and I. Efeoglu: 'The mechanical and tribological properties of Ti Nb, V N films on the Al-2024 alloy', Surf. Coat. Technol., 2017, 332, 312-318.2. J. Stallard, S. Poulat, and D. G. Teer: 'The study of the adhesion of a TiN coating on steel and titanium alloy substrates using a multi-mode scratch tester', Tribol. Int., 2006, 39(2), 159-166.3. A. Bloyce, P. Y. Qi, H. Dong, and T. Bell: 'Surface modification of titanium alloys for combined improvements in corrosion and wear resistance', Surf. Coat. Technol., 1998, 107(2-3), 125-132.4. F. Bidev, O. Baran, E. Arslan, Y. Totik, and I. Efeoglu: 'Adhesion and fatigue properties of Ti/TiB2/MoS2 graded-composite coatings deposited by closed-field unbalanced magnetron sputtering', Surf. Coat. Technol., 2013, 215, 266-271.5. C. Montero-Ocampo, E. A. Ramirez-Ceja, and J. A. Hidalgo-Badillo: 'Effect of codeposition parameters on the hardness and adhesion of TiVN coatings', Ceramics International, 2015, 41(9), 11013-11023.6. B. A. Latella, B. K. Gan, K. E. Daviesb, D. R. McKenzie, and D. G. McCulloch: 'Titanium nitride/vanadium nitride alloy coatings: mechanical properties and adhesion characteristics', Surf. Coat. Technol., 2006, 200(11), 3605-3611.7. A. Keles, H. Cicek, O. Baran, Y. Totik, and I. Efeoglu: 'Determining the critical loads of V and Nb doped ternary TiN-based coatings deposited using CFUBMS on steels', Surf. Coat. Technol., 2017, 332, 168-173.8. I. Grimberg, V. N. Zhitomirsky, R. L. Boxman, S. Goldsmith, and B. Z. Weiss: 'Multicomponent Ti-Zr-N and Ti-Nb-N coatings deposited by vacuum arc', Surf. Coat. Technol., 1998, 108(1-3), 154-159.9. V. Y. Fominski, S. N. Grigoriev, J. P. Celis, R. I. Romanov, and V. B. Oshurko: 'Structure and mechanical properties of W-Se-C/diamond-like carbon and W-Se/diamond-like carbon bi-layer coatings prepared by pulsed laser deposition', Thin Solid Films, 2012, 520(21), 6476-6483.10. Y. Alajlani, F. Placido, D. Gibson, H. O. Chu, S. G. Song, L. Porteous, and S. Moh: 'Nanostructured ZnO films prepared by hydro-thermal chemical deposition and microwave-activated reactive sputtering', Surf. Coat. Technol., 2016, 290, 16-20.11. F. Movassagh-Alanagh, A. Abdollah-Zadeh, M. Aliofkhazraei, and M. Abedi: 'Improving the wear and corrosion resistance of Ti-6Al-4V alloy by deposition of TiSiN nanocomposite coating with pulsed-DC PACVD', Wear, 2017, 390-391, 93-103.12. F. X. Ye and X. Sun: 'Nanoindentation response analysis of TiN-Cu coating deposited by magnetron sputtering', Progress in Natural Science-Materials International, 2018, 28(1), 40-44.13. P. J. Kelly and R. D. Arnell: 'Magnetron sputtering: a review of recent developments and applications', Vacuum, 2000, 56(3), 159-172.14. L. Kara, T. Kucukomeroglu, O. Baran, I. Efeoglu, and K. Yamamoto: 'Microstructure, Mechanical, and Scratch Resistance Properties of TiAlCrNbN-Graded Composite Coating Deposited on AISI H13 Steel Substrate with Pulsed DC Closed Field Unbalanced Magnetron Sputtering Method', Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science, 2014, 45A(4), 2123-2131.15. S. Gangopadhyay, R. Acharya, A. K. Chattopadhyay, and S. Paul: 'Effect of substrate bias voltage on structural and mechanical properties of pulsed DC magnetron sputtered TiN-MoSx composite coatings', Vacuum, 2010, 84(6), 843-850.16. A. D. Pogrebnjak, A. A. Bagdasaryan, V. M. Beresnev, U. S. Nyemchenko, V. I. Ivashchenko, Y. O. Kravchenko, Z. K. Shaimardanov, S. V. Plotnikov, and O. Maksakova: 'The effects of Cr and Si additions and deposition conditions on the structure and properties of the (Zr-Ti-Nb)N coatings', Ceramics International, 2017, 43(1), 771-782.17. L. Sadowski, J. Hola, S. Czarnecki, and D. H. Wang: 'Pull-off adhesion prediction of variable thick overlay to the substrate', Automation in Construction, 2018, 85, 10-23.18. Q. W. Qiu and D. V. Lau: 'A novel approach for near-surface defect detection in FRP-bonded concrete systems using laser reflection and acoustic-laser techniques', Construction and Building Materials, 2017, 141, 553-564.19. J. K. Du, B. R. Tittmann, and H. S. Ju: 'Evaluation of film adhesion to substrates by means of surface acoustic wave dispersion', Thin Solid Films, 2010, 518(20), 5786-5795.20. Y. Fizi, Y. Mebdoua, H. Lahmar, S. Djeraf, and S. Benbahouche: 'Adhesion of FeCrNiBSi-(W-Ti)C wire-arc deposited coatings onto carbon steel substrates determined by indentation measurements and modeling', Surf. Coat. Technol., 2015, 268, 310-316.21. O. S. Heavens: 'Some factors influencing the adhesion of films produced by vacuum evaporation', Journal de Physique et le Radium, , 1950, 11, 355-360.22. S. J. Bull and D. S. Rickerby: 'MULTI-PASS SCRATCH TESTING AS A MODEL FOR ABRASIVE WEAR', Thin Solid Films, 1989, 181, 545-553.23. F. Yildiz and A. Alsaran: 'Multi-pass scratch test behavior of modified layer formed during plasma nitriding', Tribol. Int., 2010, 43(8), 1472-1478.24. J. von Stebut: 'Multi-mode scratch testing - a European standards, measurements and testing study', Surf. Coat. Technol., 2005, 200(1-4), 346-350.25. G. A. Rodriguez-Castro, R. C. Vega-Moron, A. Meneses-Amador, H. W. Jimenez-Diaz, J. A. Andraca-Adame, I. E. Campos-Silva, and M. E. P. Pardave: 'Multi-pass scratch test behavior of AISI 316L borided steel', Surf. Coat. Technol., 2016, 307, 491-499.26. I. Efeoglu and R. D. Arnell: 'Multi-pass sub-critical load testing of titanium nitride coatings', Thin Solid Films, 2000, 377, 346-353.27. K. V. Ezirmik and S. Rouhi: 'Influence of Cu additions on the mechanical and wear properties of NbN coatings', Surf. Coat. Technol., 2014, 260, 179-185.28. J. Musil: 'Hard and superhard nanocomposite coatings', Surf. Coat. Technol., 2000, 125(1-3), 322-330.29. S. Veprek and S. Reiprich: 'A concept for the design of novel superhard coatings', Thin Solid Films, 1995, 268(1-2), 64-71.30. R. Jacobs, J. Meneve, G. Dyson, D. G. Teer, N. M. Jennett, P. Harris, J. von Stebut, C. Comte, P. Feuchter, A. Cavaleiro, H. Ronkainen, K. Holmberg, U. Beck, G. Reiners, and C. D. Ingelbrecht: 'A certified reference material for the scratch test', Surf. Coat. Technol., 2003, 174, 1008-1013.31. G. A. Gogotsi: 'Criteria of ceramics fracture (edge chipping and fracture toughness tests)', Ceramics International, 2013, 39(3), 3293-3300.32. A. C. FischerCripps and B. R. Lawn: 'Stress analysis of contact deformation in quasi-plastic ceramics', Journal of the American Ceramic Society, 1996, 79(10), 2609-2618.33. S. Kataria, N. Kumar, S. Dash, R. Ramaseshan, and A. K. Tyagi: 'Evolution of deformation and friction during multimode scratch test on TiN coated D9 steel', Surf. Coat. Technol., 2010, 205(3), 922-927.