Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi

Mukaddes Karataş; Nurhan Arslan

doi:10.35234/fumbd.1126606

Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi

Öz

Sabit sıcaklık ve bağıl nem ortamı sağlayan bir kamarada baklanın (Vicia faba L.), nem sorpsiyon özellikleri; üç farklı sıcaklıkta (25, 35 ve 45 °C) ve bağıl nemi atomizer nemlendirici ile ayarlanarak farklı su aktivitesi değerlerinde (0.1-0.9 aw) incelenmiştir. Elde edilen deneysel verilerden baklanın sorpsiyon izoterm eğrilerinin, BET su buharı sorpsiyon izotermleri sınıflandırmasına göre Tip III (J şekilli) özelliğe sahip olduğu bulunmuştur. Belirli bir su aktivitesinde sıcaklığın artması ile denge nem içeriği değerlerinde azalma gözlenmiştir. Baklanın sorpsiyon izotermleri tüm su aktivitesi aralığında histeresis etki göstermiştir. Sorpsiyon verilerinin matematik modellere uygunluklarının belirlenmesi amacıyla 12 farklı izoterm modeli (GAB, BET, Henderson, Oswin, Peleg, Smith, Caurie, Halsey, Ferro-Fontan, Kuhn, Chung-Pfost ve White-Eiring) kullanılmıştır. En iyi uyumu; adsorpsiyon izotermleri için Peleg modelinin, desorpsiyon izotermleri için ise Chung-Pfost modelinin gösterdiği belirlenmiştir. Sorpsiyon izosterik ısısı, sorpsiyon entropisi, yüzey potansiyeli, net integral entalpi ve net integral entropi gibi enerji gereksiniminin anlaşılmasını sağlayan termodinamik fonksiyonlar sorpsiyon izoterm verileri kullanılarak belirlenmiştir. Sorpsiyon izosterik ısısı ve net integral entalpi nem içeriğindeki artış ile azalmış ve saf suyun buharlaşma gizli ısısı değerine yaklaşmıştır.

Anahtar Kelimeler

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Mukaddes Karataş ^*
0000-0001-5803-6821
Türkiye

Nurhan Arslan
0000-0003-0051-0118
Türkiye

Yayımlanma Tarihi

30 Eylül 2022

Gönderilme Tarihi

6 Haziran 2022

Kabul Tarihi

2 Eylül 2022

Yayımlandığı Sayı

Yıl 2022 Cilt: 34 Sayı: 2

DOI

https://doi.org/10.35234/fumbd.1126606

IZ

https://izlik.org/JA56GN89FT

Kaynak Göster

RIS / Bibtex

APA

Karataş, M., & Arslan, N. (2022). Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, 34(2), 719-731. https://doi.org/10.35234/fumbd.1126606

AMA

1.Karataş M, Arslan N. Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi. 2022;34(2):719-731. doi:10.35234/fumbd.1126606

Chicago

Karataş, Mukaddes, ve Nurhan Arslan. 2022. “Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi”. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 34 (2): 719-31. https://doi.org/10.35234/fumbd.1126606.

EndNote

Karataş M, Arslan N (01 Eylül 2022) Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 34 2 719–731.

IEEE

[1]M. Karataş ve N. Arslan, “Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi”, Fırat Üniversitesi Mühendislik Bilimleri Dergisi, c. 34, sy 2, ss. 719–731, Eyl. 2022, doi: 10.35234/fumbd.1126606.

ISNAD

Karataş, Mukaddes - Arslan, Nurhan. “Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi”. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 34/2 (01 Eylül 2022): 719-731. https://doi.org/10.35234/fumbd.1126606.

JAMA

1.Karataş M, Arslan N. Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi. 2022;34:719–731.

MLA

Karataş, Mukaddes, ve Nurhan Arslan. “Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi”. Fırat Üniversitesi Mühendislik Bilimleri Dergisi, c. 34, sy 2, Eylül 2022, ss. 719-31, doi:10.35234/fumbd.1126606.

Vancouver

1.Mukaddes Karataş, Nurhan Arslan. Nem Kontrollü Bir Kamarada Depolanan Baklanın (Vicia faba L.) Sorpsiyon İzotermlerinin Modellenmesi ve Termodinamik Özelliklerinin Belirlenmesi. Fırat Üniversitesi Mühendislik Bilimleri Dergisi. 01 Eylül 2022;34(2):719-31. doi:10.35234/fumbd.1126606