Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi

Gülşah Başkan; Unsal Açıkel; Menderes Levent

doi:10.17341/gazimmfd.1008501

Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi

Öz

Antibiyotik kalıntılarının su kaynaklarındaki toksisitesi çevreyi olumsuz etkilemektedir. Son yıllarda yapılan çalışmalar antibiyotikler gibi organik kirleticilerin ucuz ve çevreye uyumlu adsorbentlerle sulu çözeltilerden giderimine odaklanmıştır. Bu çalışmada, doğal Manisa-Gördes klinoptiloliti oksitetrasiklin hidroklorür (OTC-HCL) adsorpsiyonu, kesikli sisteminde 298-323 K'de incelenmiştir. pH, başlangıç konsantrasyonu, adsorban dozu, temas süresi, karıştırma hızı ve sıcaklığın adsorpsiyon üzerindeki etkileri incelenmiş ve optimum parametreler belirlenmiştir. Adsorpsiyon izotermleri Langmuir, Freundlich, Dubinin-Radushkevich (D-R), Temkin modelleri kullanılarak analiz edilmiştir. Kinetik sabitler yalancı birinci derece, yalancı ikinci derece, inratapartikül difüzyon ve Elovich modelleriyle belirlenmiştir. Doğal zeolitin OTC-HCL adsorpsiyonu, en iyi Freundlich izotermine ve sözde ikinci dereceden kinetik modeline uymuştur. Doğal zeolitin maksimum adsorpsiyon kapasitesi 323 K'de 60,97 mg/g olarak belirlenmiştir. Termodinamik çalışmalar, OTC-HCL’nin doğal zeolit ile adsorpsiyonunun kendiliğinden ve endotermik olduğunu göstermiştir. Doğal zeolitin fizikokimyasal karakterizasyonu adsorpsiyondan önce ve sonra, N2 adsorpsiyon-desorpsiyon, XRD, FTIR, SEM-EDX analizleri ile gerçekleştirilmiştir. Doğal zeolitin BET spesfik yüzey alanı, adsorpsiyon sürecine bağlı olarak adsorpsiyon sonrasında azalmıştır. Karakterizasyon sonuçları, doğal zeolit yüzeyinde OTC-HCL moleküllerinin başarılı bir adsorbe olduğunu göstermiştir.

Anahtar Kelimeler

Destekleyen Kurum

Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Birimi

Proje Numarası

(BAP/M-764 kodlu proje)

Teşekkür

Bu çalışma Sivas Cumhuriyet Üniversitesi Bilimsel Araştırma Projeleri Birimi (BAP/M-764 kodlu proje) tarafından desteklenmektedir. Yazarlar, Deva Holding-İstanbul-Türkiye ve Gordes Zeolite-İzmir-Türkiye tarafından sağlanan antibiyotik ve zeolit için teşekkürlerini bildiriyorlar.

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Gülşah Başkan ^*
0000-0002-2852-6114
Türkiye

Unsal Açıkel
0000-0003-4969-8502
Türkiye

Menderes Levent
0000-0002-6363-1614
Türkiye

Yayımlanma Tarihi

6 Ocak 2023

Gönderilme Tarihi

12 Ekim 2021

Kabul Tarihi

16 Temmuz 2022

Yayımlandığı Sayı

Yıl 2023 Cilt: 38 Sayı: 3

DOI

https://doi.org/10.17341/gazimmfd.1008501

IZ

https://izlik.org/JA73TW47TP

Kaynak Göster

RIS / Bibtex

APA

Başkan, G., Açıkel, U., & Levent, M. (2023). Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38(3), 1505-1518. https://doi.org/10.17341/gazimmfd.1008501

AMA

1.Başkan G, Açıkel U, Levent M. Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. GUMMFD. 2023;38(3):1505-1518. doi:10.17341/gazimmfd.1008501

Chicago

Başkan, Gülşah, Unsal Açıkel, ve Menderes Levent. 2023. “Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38 (3): 1505-18. https://doi.org/10.17341/gazimmfd.1008501.

EndNote

Başkan G, Açıkel U, Levent M (01 Ocak 2023) Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38 3 1505–1518.

IEEE

[1]G. Başkan, U. Açıkel, ve M. Levent, “Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi”, GUMMFD, c. 38, sy 3, ss. 1505–1518, Oca. 2023, doi: 10.17341/gazimmfd.1008501.

ISNAD

Başkan, Gülşah - Açıkel, Unsal - Levent, Menderes. “Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38/3 (01 Ocak 2023): 1505-1518. https://doi.org/10.17341/gazimmfd.1008501.

JAMA

1.Başkan G, Açıkel U, Levent M. Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. GUMMFD. 2023;38:1505–1518.

MLA

Başkan, Gülşah, vd. “Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, c. 38, sy 3, Ocak 2023, ss. 1505-18, doi:10.17341/gazimmfd.1008501.

Vancouver

1.Gülşah Başkan, Unsal Açıkel, Menderes Levent. Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. GUMMFD. 01 Ocak 2023;38(3):1505-18. doi:10.17341/gazimmfd.1008501

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