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Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi

Year 2018, Volume: 33 Issue: 4, 1603 - 1610, 19.12.2018
https://doi.org/10.17341/gazimmfd.416455

Abstract

Demir esaslı toz metal (TM) kompaktların sertlik, sürtünme, aşınma ve korozyon dayanımına akımsız Ni-B kaplamanın etkisi incelendi. Bu amaçla, toz metalürjisi yöntemiyle üretilen demir esaslı TM kompaktlar çok ince akımsız Ni-P kaplandıktan sonra akımsız Ni-B kaplama işlemi uygulandı. Akımsız Ni-B kaplanmış ve kaplanmamış TM kompaktlar taramalı elektron mikroskobu (SEM), X-ışını kırınım analizi (XRD), enerji dağılımlı X-ışını spektroskopisi (EDX) ve mikrosertlik ölçümleri ile karaktereze edildi. Tribolojik özellikler pin-on-disk tipi aşınma cihazı kullanılarak 10, 20 ve 30 N’luk yükler altında, 1 ms-1 sürtünme hızında ve 1000 m sürtünme mesafesinde belirlendi. Korozyon dayanımları potansiyodinamik polarizasyon ölçümleri ile tespit edildi. Sonuçlar, akımsız Ni-B kaplamanın amorfsu yapıda ve sütunsu bir büyüme morfolojisine sahip olduğunu göstermiştir.  Mikrosertlik ve tribolojik testler Ni-B kaplamanın sahip olduğu yüksek sertlik ve morfolojik özellikleri ile TM kompaktların aşınma ve sürtünme özelliklerini iyileştirdiğini göstermiştir. Akımsız Ni-B kaplama TM kompaktların korozyon direncinde kayda değer bir artış meydana getirmiştir. 

References

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  • Danninger, H., Gierl-Mayer, C., Advanced powder metallurgy steel alloys, Advances in powder metallurgy: properties, processing and applications, Woodhead Publishing, 149–201, 2013.
  • De Mello, J. D. B., Binder, C., Binder, R., Klein, A. N., Effect of nature of nitride phases on microabrasion of plasma nitrided sintered iron, Tribology - Materials, Surfaces, Interfaces, 4, 191–196, 2010.
  • Steimbreger, C., Vuorinea, E., Johansson, P., Wear Analysis of PM compacts with bainitic microstructures, under unlubricated sliding conditions, Procedia Materials Science, 9, 578–589, 2015.
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  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni-B-Si3N4 composite coating: deposition and evaluation of its characteristic properties, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 42, 920–927, 2012.
  • Narayanan, T. S. N. S., Krishnaveni, K., Seshadri, S. K., Electroless Ni–P/Ni–B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance, Materials Chemistry and Physics, 82, 771–779, 2003.
  • Vitry, V., Kanta, A.-F., Delaunois, F., Mechanical and wear characterization of electroless nickel-boron coatings. Surface and Coatings Technology, 206, 1879–1885, 2011.
  • Vitry, V., Sens, A., Kanta, a. F., Delaunois, F., Wear and corrosion resistance of heat treated and as-plated Duplex NiP/NiB coatings on 2024 aluminum alloys, Surface and Coatings Technology, 206, 3421–3427, 2012.
  • ASTM G102., Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements, Annual book of ASTM standards, 03.02, 416–422, 1994.
  • Srinivasan, K. N., Meenakshi, R., Santhi, A., Thangavelu, P. R., S. John, S., Studies on development of electroless Ni–B bath for corrosion resistance and wear resistance applications, Surface Engineering, 26(3), 153-158, 2017.
  • Delaunois, F., Lienard, P., Heat treatments for electroless nickel – boron plating on aluminium alloys, Surface and Coatings Technology, 160, 239–248, 2002.
  • Niksefat, V., Ghorbani, M., Mechanical and electrochemical properties of ultrasonic-assisted electroless deposition of Ni-B-TiO2 composite coatings, Journal of Alloys and Compounds, 633, 127–136, 2015.
  • Vitry, V., Delaunois, F., Nanostructured electroless nickel-boron coatings for wear resistance, Anti-Abrasive Nanocoatings, Elsevier, 157–199, 2015.
  • Vitry, V., Kanta, A. F., Delaunois, F., Initiation and formation of electroless nickel–boron coatings on mild steel: Effect of substrate roughness, Materials Science and Engineering: B, 175, 266–273, 2010.
  • Krishnaveni, K., Seshadri, S. K., Electroless Ni-B and Ni-B-Si3N4 composite Coatings - their role in surface engineering, International Symposium of Research Students on Materials Science and Engineering, India, 1–9, 2004.
  • Madah, F., Amadeh, A. A., Dehghanian, C., Investigation on the phase transformation of electroless Ni-B coating after dry sliding against alumina ball, Journal of Alloys and Compounds, 658, 272–279, 2016.
  • Madah, F., Dehghanian, C., Amadeh, A. A., Investigations on the wear mechanisms of electroless Ni-B coating during dry sliding and endurance life of the worn surfaces, Surface and Coatings Technology, 282, 6–15, 2015.
  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni–B coatings: preparation and evaluation of hardness and wear resistance, Surface and Coatings Technology, 190, 115–121, 2005.
  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni-B-Si3N4 Composite Coating: Deposition and Evaluation of Its Characteristic Properties. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 42, 920–927, 2012.
  • Bülbül, F., Çelik, İ., Effect of heat treatment on structure of electroless Ni-B coated pure titanium, Journal of the Faculty of Engineering and Architecture of Gazi University, 29, 89–94, 2014.
  • Gilley, K. L., Nino, J. C., Riddle, Y. W., Hahn, D. W., Perry, S. S., Heat treatments modify the tribological properties of nickel boron coatings, ACS Applied Materials and Interfaces, 4, 3069–3076, 2012.
Year 2018, Volume: 33 Issue: 4, 1603 - 1610, 19.12.2018
https://doi.org/10.17341/gazimmfd.416455

Abstract

References

  • Etaat, M., Emamy, M., Ghambari, M., Fadaei, E., Surface treatment and nickel plating of iron powder metallurgy parts for corrosion protection, Materials and Design, 30, 3560–3565, 2009.
  • Danninger, H., Gierl-Mayer, C., Advanced powder metallurgy steel alloys, Advances in powder metallurgy: properties, processing and applications, Woodhead Publishing, 149–201, 2013.
  • De Mello, J. D. B., Binder, C., Binder, R., Klein, A. N., Effect of nature of nitride phases on microabrasion of plasma nitrided sintered iron, Tribology - Materials, Surfaces, Interfaces, 4, 191–196, 2010.
  • Steimbreger, C., Vuorinea, E., Johansson, P., Wear Analysis of PM compacts with bainitic microstructures, under unlubricated sliding conditions, Procedia Materials Science, 9, 578–589, 2015.
  • Matik, U., Çıtak, R., Influence of the heat treatment on hardness and adhesive wear performance of Ni-P deposit with low phosphorus content, Materials Testing, 57, 431–436, 2015.
  • Matik, U., Structural and wear properties of heat-treated electroless Ni-P alloy and Ni-P-Si3N4 composite coatings on iron based PM compacts, Surface and Coatings Technology, 302, 528–534, 2016.
  • Sudagar, J., Lian, J., Sha, W., Electroless nickel, alloy, composite and nano coatings - A critical review, Journal of Alloys and Compounds, 571, 183–204, 2013.
  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni-B-Si3N4 composite coating: deposition and evaluation of its characteristic properties, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 42, 920–927, 2012.
  • Narayanan, T. S. N. S., Krishnaveni, K., Seshadri, S. K., Electroless Ni–P/Ni–B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance, Materials Chemistry and Physics, 82, 771–779, 2003.
  • Vitry, V., Kanta, A.-F., Delaunois, F., Mechanical and wear characterization of electroless nickel-boron coatings. Surface and Coatings Technology, 206, 1879–1885, 2011.
  • Vitry, V., Sens, A., Kanta, a. F., Delaunois, F., Wear and corrosion resistance of heat treated and as-plated Duplex NiP/NiB coatings on 2024 aluminum alloys, Surface and Coatings Technology, 206, 3421–3427, 2012.
  • ASTM G102., Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements, Annual book of ASTM standards, 03.02, 416–422, 1994.
  • Srinivasan, K. N., Meenakshi, R., Santhi, A., Thangavelu, P. R., S. John, S., Studies on development of electroless Ni–B bath for corrosion resistance and wear resistance applications, Surface Engineering, 26(3), 153-158, 2017.
  • Delaunois, F., Lienard, P., Heat treatments for electroless nickel – boron plating on aluminium alloys, Surface and Coatings Technology, 160, 239–248, 2002.
  • Niksefat, V., Ghorbani, M., Mechanical and electrochemical properties of ultrasonic-assisted electroless deposition of Ni-B-TiO2 composite coatings, Journal of Alloys and Compounds, 633, 127–136, 2015.
  • Vitry, V., Delaunois, F., Nanostructured electroless nickel-boron coatings for wear resistance, Anti-Abrasive Nanocoatings, Elsevier, 157–199, 2015.
  • Vitry, V., Kanta, A. F., Delaunois, F., Initiation and formation of electroless nickel–boron coatings on mild steel: Effect of substrate roughness, Materials Science and Engineering: B, 175, 266–273, 2010.
  • Krishnaveni, K., Seshadri, S. K., Electroless Ni-B and Ni-B-Si3N4 composite Coatings - their role in surface engineering, International Symposium of Research Students on Materials Science and Engineering, India, 1–9, 2004.
  • Madah, F., Amadeh, A. A., Dehghanian, C., Investigation on the phase transformation of electroless Ni-B coating after dry sliding against alumina ball, Journal of Alloys and Compounds, 658, 272–279, 2016.
  • Madah, F., Dehghanian, C., Amadeh, A. A., Investigations on the wear mechanisms of electroless Ni-B coating during dry sliding and endurance life of the worn surfaces, Surface and Coatings Technology, 282, 6–15, 2015.
  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni–B coatings: preparation and evaluation of hardness and wear resistance, Surface and Coatings Technology, 190, 115–121, 2005.
  • Krishnaveni, K., Sankara Narayanan, T. S. N., Seshadri, S. K., Electroless Ni-B-Si3N4 Composite Coating: Deposition and Evaluation of Its Characteristic Properties. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 42, 920–927, 2012.
  • Bülbül, F., Çelik, İ., Effect of heat treatment on structure of electroless Ni-B coated pure titanium, Journal of the Faculty of Engineering and Architecture of Gazi University, 29, 89–94, 2014.
  • Gilley, K. L., Nino, J. C., Riddle, Y. W., Hahn, D. W., Perry, S. S., Heat treatments modify the tribological properties of nickel boron coatings, ACS Applied Materials and Interfaces, 4, 3069–3076, 2012.
There are 24 citations in total.

Details

Journal Section Makaleler
Authors

Ulaş Matik

Publication Date December 19, 2018
Submission Date April 24, 2017
Published in Issue Year 2018 Volume: 33 Issue: 4

Cite

APA Matik, U. (2018). Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 33(4), 1603-1610. https://doi.org/10.17341/gazimmfd.416455
AMA Matik U. Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi. GUMMFD. December 2018;33(4):1603-1610. doi:10.17341/gazimmfd.416455
Chicago Matik, Ulaş. “Akımsız Ni-B Kaplama Ile Demir Esaslı Toz Metal kompaktların yüzey özelliklerinin geliştirilmesi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 33, no. 4 (December 2018): 1603-10. https://doi.org/10.17341/gazimmfd.416455.
EndNote Matik U (December 1, 2018) Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 33 4 1603–1610.
IEEE U. Matik, “Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi”, GUMMFD, vol. 33, no. 4, pp. 1603–1610, 2018, doi: 10.17341/gazimmfd.416455.
ISNAD Matik, Ulaş. “Akımsız Ni-B Kaplama Ile Demir Esaslı Toz Metal kompaktların yüzey özelliklerinin geliştirilmesi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 33/4 (December 2018), 1603-1610. https://doi.org/10.17341/gazimmfd.416455.
JAMA Matik U. Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi. GUMMFD. 2018;33:1603–1610.
MLA Matik, Ulaş. “Akımsız Ni-B Kaplama Ile Demir Esaslı Toz Metal kompaktların yüzey özelliklerinin geliştirilmesi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol. 33, no. 4, 2018, pp. 1603-10, doi:10.17341/gazimmfd.416455.
Vancouver Matik U. Akımsız Ni-B kaplama ile demir esaslı toz metal kompaktların yüzey özelliklerinin geliştirilmesi. GUMMFD. 2018;33(4):1603-10.