Ammonium Removal in Aquatic Conditions Using Different Levels of Calcium Bentonite
Abstract
Ammonia, necessary for life cycles is a natural substance that is available in all forms of life from plants to animals and human beings. Ammonia is toxic at high levels, however low concentrates can be tolerated by the living forms. Especially in mass production of fish under intensive culture conditions, significant amount of ammonia excretion deteriorates the water environment. Hence, removal of ammonia from water environment may support the re-use of freshwater in aquaculture facilities, and benefit for sustainable utilization of water resources. Compared to clay minerals, bentonite has a high usability due to its high adsorption capacity and low cost. In this study, it was aimed to determine the effects of two different concentrations of calcium bentonite on ammonium adsorption in a freshwater environment at constant temperature (17°C). Two different concentrations of calcium bentonite (7g/l B7 and 14g/l B14) were tested in triplicate and experiments were performed in chambers with 2 liter water and NH4Cl incorporated to obtain 10 mg/l NH4+ in each of the water chamber. Water quality parameters such as temperature, pH, dissolved oxygen (DO) and total ammonium nitrogen (TAN) were determined during the course of the experiment. Ammonia adsorption effects of calcium bentonite were tested and at the end of the trial, NH3 values were recorded as 0.461±0.01mg/l and 0.463±0.01 mg/l for the B7 and B14 groups, respectively. There were difference in TAN values between the experimental groups (P<0.05). As a result, it has been concluded that bentonite of 14 g/l might be ideal for ammonium removal under aquatic conditions applied.is
Keywords
References
- Abdelaal, A.M., 2004. Using a natural coagulant for treating wastewater. Eighth International Water Technology Conference, IWTC8, Alexandria, Egypt.
- Alshameri, A., He, H., Zhu, J., Xi, Y., Zhu, R., Ma, L., Tao, Q., 2017. Adsorption of ammonium by different natural clay minerals: Characterization, kinetics and adsorption isotherms. Applied Clay Science (2017), http://dx.doi.org/10.1016/j.clay.2017.11.007
- Angar, Y., Djelali, N-E., Kebbouche-Gana, S., 2017. Investigation of ammonium adsorption on Algerian natural bentonite. Environ Sci Pollut Res, 24:11078–11089.
- Asselin, E., Alfantazi, A., Rogak, S., 2008. Thermodynamics of the Corrosion of Alloy 625 Supercritical Water Oxidation Reactor Tubing in Ammoniacal Sulfate Solution. Corrosion, 64 (4): 301-314.
- Babel, S. and Kurniawan, T.A., 2003. Low-cost adsorbent for heavy metals uptake from contaminated water: a review. Journal of Hazardous Materials, B97, pp 219-243.
- Booth, D.J. 1999. Effects of Dietary and Free Bentonite On Ammonia Build up in Aquarium Fis. Austrasian Journal of Exotoxicology, 5:149-152.
- Boyd, C.E., 1990. Water quality in ponds for aquaculture, Auburn, AL: Auburn University, Alabama Agricultural Experiment Station, Pres. 482 (It was taken: Boyd, C. E., Practical aspects of chemistry in pond aquaculture, The Progressive Fish Culturist, 59 (1997) 85-93).
- De Luna, M.D.G., Futalan, C.M., Jurado, C.A., Colades, J.I., Wan, M.W., 2018. Removal of ammonium-nitrogen from aqueous solution using chitosan-coated bentonite: Mechanism and effect of operating parameters. Journal Of Applied Polymer Science, 135 (9), Article Number: 45924, DOI: 10.1002/APP.45924
Details
Primary Language
English
Subjects
-
Journal Section
Research Article
Authors
Dilek Şahin
0000-0003-4454-9030
Türkiye
Eda Sertaşı
*
0000-0001-8565-0130
Türkiye
Meryem Öz
0000-0002-7803-8207
Türkiye
Ünal Öz
0000-0003-1918-3284
Türkiye
Orhan Aral
0000-0001-8550-9970
Türkiye
Publication Date
December 15, 2018
Submission Date
April 6, 2018
Acceptance Date
November 9, 2018
Published in Issue
Year 2018 Volume: 7 Number: 3