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Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method

Year 2009, Volume: 22 Issue: 3, 157 - 167, 26.03.2010

Poonam Kaur Usha Gupta

Abstract

H-point standard addition method (HPSAM) was applied to kinetic data for simultaneous determination of Ni(II) and Mn(II). The method is based on the difference between rate of complexation of 1-(2-pyridylazo)-2- naphthol (PAN) with Ni(II) and Mn(II) at pH 7.5 in Triton X-100 micellar media. Ni(II) and Mn(II) can be determined simultaneously in the concentration range 0.084-0.734 and 0.055-0.366 8g mL-1, respectively. The proposed method has successfully been applied for simultaneous determination of Ni(II) and Mn(II) in synthetic samples, spiked water samples, alloys and food products.

 

Key Words: Nickel; Manganese; Kinetic; HPSAM; PAN.

Keywords

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References

  • Bosch-Reig, F., Campins-Falco, P., “H-point Standard Additions Method Application to Analytical Spectroscopy”, Analyst, 113: 1011-1016 (1988). Fundamentals and extensively method”, Fresenius J. Anal. Chem., 338: 16-21 (1990). or completely [4] Afkhami, A., Zarei, A.R., “Simultaneous Spectrophotometric Determination of Bi(III) and Sb(III) Based on Their Complexes with Iodide in Acidic Media Using the H-Point Standard Addition Method and First Derivative Spectrophotometry”,
  • Anal. Sci., 19: 917-921 (2003).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., “Evaluation and elimination of the “blank bias errror” using the H-point standard addition method: application to spectrophotometric determination on using absorbent blank”, Anal. Chim. Acta, 270 (1): 253-265 (1992).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., Molins-Legua, C., “Study of the behaviour of the absorbent blanks in analytical procedures by using the H-Point standard additions method (HPSAM)”, Talanta, 41 (1): 39-52 (1994).
  • Blasco-Gomez, F., Bosch-Reig, F., Campins-Falco, P., Molins-Legua, C., “H-point curve isolation method for coupled liquid chromatography and UV-Visible spectrophotometry”, Anal. Chem., 72: 2559-2565 (2000).
  • Zolgharnein, J., Abdollahi, H., Jafarifar, D., Azimi G.H., “Simultaneous determination of Fe (II) and Fe (III) by kinetic spectrophotometric H-point standard addition method”, Talanta, 57: 1067-1073 (2002).
  • Bosch-Reig, F., Campins-Falco, P., Sevillano-Cabez, A., “Development of the H-Point Standard-Additions Method for Ultraviolet-Visible Spectroscopic Kinetic Analysis of Two-Component Systems”, Anal. Chem., 63: 2424-2429 (1991). R., Molins-Legua, C., [10] Safavi, A., Abdollahi, H., Nezhad, M.R.H., “Simultaneous kinetic determination of Fe(III) and Fe(II) by H-point standard addition method”, Talanta, 56: 699-704 (2002).
  • Safavi, A., Abdollahi, H., Sedaghatpour, F., Zeinalli, S., “Kinetic spectrophotometric determination of V(IV) in the presence of V(V) by the H-point standard addition method”, Anal. Chim. Acta, 409: 275-282 (2000).
  • Nielsen, F.H., Nutrition in Health and Disease 9th ed., Baltimore: Williams & Wilkins, 283-303 (1999).
  • Andrews, R. K., Blakeley, R.L., Zerner, B., Lancaster, J.R., The Bioinorganic Chemistry of Nickel, VCH, New York, 141-165 (1988).
  • Teo, K.C., Chen, J., “Determination of manganese in water spectrometry after cloud point extraction”, Analyst, 126: 534-537 (2001). atomic absorption
  • Sirko, A., Brodzik, R., “Plant ureases: Roles and regulation”, Acta Biochim. Pol., 47 (4): 1189-1195 (2000).
  • Adriana, P.D.O., Mercedes, D. M., Anchieta, G.N.J., Claudio, L.E., “Simultaneous determination of Al, As, Cu, Fe, Mn, and Ni in fuel ethanol by GFAAS”, At. Spectrosc., 23(2): 39-43 (2002).
  • Ghoneim, M.M., Hassanein, A.M., Hammam, E., Beltagi, A.M., “Simultaneous determination of Cd, Pb, Cu, Sb, Bi, Se, Zn, Mn, Ni, Co and Fe in water samples by differential pulse stripping voltammetry at a hanging mercury drop electrode”, Fresenius, J. Anal. Chem., 367 (4): 378-383 (2000).
  • Fredrikson, M., Carlsson, N.G., Almgren, A., Sandberg, A.S., “Simultaneous and Sensitive Analysis of Cu, Ni, Zn, Co, Mn, and Fe in Food and Biological Samples by Ion Chromatography”, J. Agric. Food. Chem., 50: 59-65 (2002).
  • Mclntire, G.L., Dorsey, J.G., “Micelles in Analytical Chemistry”, Cri. Rev. Anal. Chem., 21(4): 257-278 (1990).
  • Singh, H.B., Agnihotri, N.K., Singh, V.K., “ Non- extractive determination of cobalt in micellar medium”, Talanta, 48: 623-631 (1999). Spectrophotometric
  • Second Annual Report on Carcinogens, Environmental Protection Agency, NTP, 81-43:73-75, 78-80(1981).

Year 2009, Volume: 22 Issue: 3, 157 - 167, 26.03.2010

Poonam Kaur Usha Gupta

Abstract

References

  • Bosch-Reig, F., Campins-Falco, P., “H-point Standard Additions Method Application to Analytical Spectroscopy”, Analyst, 113: 1011-1016 (1988). Fundamentals and extensively method”, Fresenius J. Anal. Chem., 338: 16-21 (1990). or completely [4] Afkhami, A., Zarei, A.R., “Simultaneous Spectrophotometric Determination of Bi(III) and Sb(III) Based on Their Complexes with Iodide in Acidic Media Using the H-Point Standard Addition Method and First Derivative Spectrophotometry”,
  • Anal. Sci., 19: 917-921 (2003).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., “Evaluation and elimination of the “blank bias errror” using the H-point standard addition method: application to spectrophotometric determination on using absorbent blank”, Anal. Chim. Acta, 270 (1): 253-265 (1992).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., Molins-Legua, C., “Study of the behaviour of the absorbent blanks in analytical procedures by using the H-Point standard additions method (HPSAM)”, Talanta, 41 (1): 39-52 (1994).
  • Blasco-Gomez, F., Bosch-Reig, F., Campins-Falco, P., Molins-Legua, C., “H-point curve isolation method for coupled liquid chromatography and UV-Visible spectrophotometry”, Anal. Chem., 72: 2559-2565 (2000).
  • Zolgharnein, J., Abdollahi, H., Jafarifar, D., Azimi G.H., “Simultaneous determination of Fe (II) and Fe (III) by kinetic spectrophotometric H-point standard addition method”, Talanta, 57: 1067-1073 (2002).
  • Bosch-Reig, F., Campins-Falco, P., Sevillano-Cabez, A., “Development of the H-Point Standard-Additions Method for Ultraviolet-Visible Spectroscopic Kinetic Analysis of Two-Component Systems”, Anal. Chem., 63: 2424-2429 (1991). R., Molins-Legua, C., [10] Safavi, A., Abdollahi, H., Nezhad, M.R.H., “Simultaneous kinetic determination of Fe(III) and Fe(II) by H-point standard addition method”, Talanta, 56: 699-704 (2002).
  • Safavi, A., Abdollahi, H., Sedaghatpour, F., Zeinalli, S., “Kinetic spectrophotometric determination of V(IV) in the presence of V(V) by the H-point standard addition method”, Anal. Chim. Acta, 409: 275-282 (2000).
  • Nielsen, F.H., Nutrition in Health and Disease 9th ed., Baltimore: Williams & Wilkins, 283-303 (1999).
  • Andrews, R. K., Blakeley, R.L., Zerner, B., Lancaster, J.R., The Bioinorganic Chemistry of Nickel, VCH, New York, 141-165 (1988).
  • Teo, K.C., Chen, J., “Determination of manganese in water spectrometry after cloud point extraction”, Analyst, 126: 534-537 (2001). atomic absorption
  • Sirko, A., Brodzik, R., “Plant ureases: Roles and regulation”, Acta Biochim. Pol., 47 (4): 1189-1195 (2000).
  • Adriana, P.D.O., Mercedes, D. M., Anchieta, G.N.J., Claudio, L.E., “Simultaneous determination of Al, As, Cu, Fe, Mn, and Ni in fuel ethanol by GFAAS”, At. Spectrosc., 23(2): 39-43 (2002).
  • Ghoneim, M.M., Hassanein, A.M., Hammam, E., Beltagi, A.M., “Simultaneous determination of Cd, Pb, Cu, Sb, Bi, Se, Zn, Mn, Ni, Co and Fe in water samples by differential pulse stripping voltammetry at a hanging mercury drop electrode”, Fresenius, J. Anal. Chem., 367 (4): 378-383 (2000).
  • Fredrikson, M., Carlsson, N.G., Almgren, A., Sandberg, A.S., “Simultaneous and Sensitive Analysis of Cu, Ni, Zn, Co, Mn, and Fe in Food and Biological Samples by Ion Chromatography”, J. Agric. Food. Chem., 50: 59-65 (2002).
  • Mclntire, G.L., Dorsey, J.G., “Micelles in Analytical Chemistry”, Cri. Rev. Anal. Chem., 21(4): 257-278 (1990).
  • Singh, H.B., Agnihotri, N.K., Singh, V.K., “ Non- extractive determination of cobalt in micellar medium”, Talanta, 48: 623-631 (1999). Spectrophotometric
  • Second Annual Report on Carcinogens, Environmental Protection Agency, NTP, 81-43:73-75, 78-80(1981).
There are 18 citations in total.

Details

Primary Language English
Journal Section Chemistry
Authors

Poonam Kaur This is me

Usha Gupta This is me

Publication Date March 26, 2010
Published in Issue Year 2009 Volume: 22 Issue: 3

Cite

APA Kaur, P., & Gupta, U. (2010). Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science, 22(3), 157-167.
AMA Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. March 2010;22(3):157-167.
Chicago Kaur, Poonam, and Usha Gupta. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science 22, no. 3 (March 2010): 157-67.
EndNote Kaur P, Gupta U (March 1, 2010) Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science 22 3 157–167.
IEEE P. Kaur and U. Gupta, “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”, Gazi University Journal of Science, vol. 22, no. 3, pp. 157–167, 2010.
ISNAD Kaur, Poonam - Gupta, Usha. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science 22/3 (March 2010), 157-167.
JAMA Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. 2010;22:157–167.
MLA Kaur, Poonam and Usha Gupta. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science, vol. 22, no. 3, 2010, pp. 157-6.
Vancouver Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. 2010;22(3):157-6.