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Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites

Year 2008, Volume: 21 Issue: 3, 105 - 112, 01.04.2010

Abstract

The present work describes preparation of acid resistant composites from porphyrite and wollastonite by adding wastes of furfurol (PA1) and furfuryl alcohol (PA2) production as the polymer additives. The effects of waste polymer additives on the compressive strength, chemical resistance and adhesive ability of the composites were examined. The mechanism of the hydration process and phase evaluation of the composites were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), differential thermal analysis (DTA) and IR spectroscopy. The results indicated that hardening of the composites promoted formation of chemical bond between constituents and calcium fluoride compounds. Comparative study showed that the porphyrite composite (Sample P-2) with 1% PA1 additive and porphyrite – wollastonite composite (Sample PW-9) with 2% PA2 additive have optimal parameters among the samples. Acid resistance and compressive strength of prepared composites applied to surfaces of metal and ceramic materials were determined and enhanced properties of porphyrite – wollastonite composite with additive PA2 were found to be in metal (2.4 ĞœPĞ°). The reason for the improvement of the chemical resistance and compressive strength of the composites may be attributed to the formation of the amorphous silicon phase.

 Key Words: Porphyrite, Wollastonite, Industrial wastes, Polymer additives, Acid resistant composite.

 

References

  • Dan, E., Janotka, I., “Chemical resistance of Portland cement, blast - furnace slag Portland cement and sulphoaluminate-belite cement in acid, chloride and sulphate solution: Some preliminary results”, Ceramics – Silikaty, 47: 14-18 (2003). medium Ceramic 1.40 1.08 P-2 Metal 1.93 1.14 Ceramic 2.10 1.90 PW-9 Metal 2.40 2.00
  • Gonzalez, M.A., “Effect of limestone filler on the sulfate resistance of low C3A Portland cement”, Cement and Concrete Research, 28: 1655-1667 (1998).
  • Puertas, F., Blanco-Valera, M.T., Palomo, A., Vazquez, T., “Behaviour of a new white cement fabricated with raw materials containing CaF2 and CaSO4·2H2O Part 2: Durability and chemical resistance”, ZKG International, 51: 94-100 (1998).
  • Kerr, M.L., Pitt, J.M., “Resistance of high alumina and portland cement to H2SO4”, Trenchless Pipeline Projects, Practical Applications, Boston, USA, 251-257 (1997).
  • Xiong, G., Chen, X., Li, G., Chen, L., “Sulphuric acid resistance of soluble soda glass-polyvinyl acetate latex-modified cement mortar”, Cement and Concrete Research, 31: 83-86 (2001).
  • Bright, R.P., Wise, S., Mackenzie, M.L., “Polymer impregnation of an impervious cementitious composite material”, Materials Research Society Symposium, Boston, USA, 287-294 (1985).
  • Gebauer, J., Coughlin, R.W., “Preparation, properties and corrosion resistance of composites of cement mortar and organic polymers”, Cement and Concrete Research, 1: 187-210 (1971).
  • Figovsky, O., Beilin, D., Blank, N., Potapov, J., Chernyshev, V., “Development of polymer concrete with polybutadiene matrix”, Cement and Concrete Composites, 18: 437-444 (1996).
  • Weber, H.H., McBee, W.C., Krabbe, E.A., “Sulfur concrete composite materials for construction and maintenance”, Materials Performance, 29: 73-77 (1990).
  • Leitheiser, R.H., Londrigan, M.E., Rude, C.A., “Furan resinous cements”, American Chemical Society Symposium, Washington, USA, 7-26 (1979).
  • Seymour, R.B., “Plastic Mortars, Sealants, and Caulking Compounds”, American Chemical Society Symposium, Washington, USA, 184 (1979).
  • Sugama, T., Kukacka, L.E., Horn, W., “Properties of water-compatible furfuryl alcohol polymer concrete”, Cement and Concrete Research, 11: 497-506 (1981).
  • Semler, C., Hawisher, T., Pieterse, H., Williams, R., “Acid resistant cement composition”, US Patent, 5: 989, 330 (1999).
  • Subbotkin, M.I., Kuritsina, Y.S., “Acid-proof concrete and mortar on the basis of water glass”, Stroyizdat, Moscow, Russia (1967).
  • Moskvin, V.I., “Physicochemical investigation of concrete and its components”, Stroyizdat, Moscow, Russia (1976).
  • Sychev, D.I., “Adhesive on the basis of silicate alkaline metals”, Nauka, Moscow, Russia (1986).
  • Babushkin, V.I., Plugin, A.A., “Acid-proof binding composites and concretes for protection of building from corrosion”, Chemistry and Technology of Cement, Moscow, Russia, 144-150 (2000).
  • Xiong, G.J., Chen, X.H., Chen, L.Q., Yang, J.Z., Li, G.Y., “Hybrid modified ferrocement under sustained load in flowing sulphuric acid solution”, Cement and Concrete Composites, 26: 8-86 (2004).
  • Traulsen, C., Nielsen, N.J.R., Nielsen, T.S., “Tests validate fiber glass cement to protect subsea FBE coating”, Oil and Gas Journal, 88: 72-76 (1990).
  • Zivica, V., “Experimental principles in the
  • research of chemical resistance of cement based materials”, Construction and Building Materials, 12: 365-371 (1998).
  • Butt, J.M., Sychev, M.M., Timashev, V.V.,
  • “Chemical technology of binding materials”, Stroyizdat, Moscow, Russia (1980).
  • Moskvin, V.M., “Durability of concrete and corrosion theory”, Hydrotechnical Construction, 19: 379-385 (1985).
Year 2008, Volume: 21 Issue: 3, 105 - 112, 01.04.2010

Abstract

References

  • Dan, E., Janotka, I., “Chemical resistance of Portland cement, blast - furnace slag Portland cement and sulphoaluminate-belite cement in acid, chloride and sulphate solution: Some preliminary results”, Ceramics – Silikaty, 47: 14-18 (2003). medium Ceramic 1.40 1.08 P-2 Metal 1.93 1.14 Ceramic 2.10 1.90 PW-9 Metal 2.40 2.00
  • Gonzalez, M.A., “Effect of limestone filler on the sulfate resistance of low C3A Portland cement”, Cement and Concrete Research, 28: 1655-1667 (1998).
  • Puertas, F., Blanco-Valera, M.T., Palomo, A., Vazquez, T., “Behaviour of a new white cement fabricated with raw materials containing CaF2 and CaSO4·2H2O Part 2: Durability and chemical resistance”, ZKG International, 51: 94-100 (1998).
  • Kerr, M.L., Pitt, J.M., “Resistance of high alumina and portland cement to H2SO4”, Trenchless Pipeline Projects, Practical Applications, Boston, USA, 251-257 (1997).
  • Xiong, G., Chen, X., Li, G., Chen, L., “Sulphuric acid resistance of soluble soda glass-polyvinyl acetate latex-modified cement mortar”, Cement and Concrete Research, 31: 83-86 (2001).
  • Bright, R.P., Wise, S., Mackenzie, M.L., “Polymer impregnation of an impervious cementitious composite material”, Materials Research Society Symposium, Boston, USA, 287-294 (1985).
  • Gebauer, J., Coughlin, R.W., “Preparation, properties and corrosion resistance of composites of cement mortar and organic polymers”, Cement and Concrete Research, 1: 187-210 (1971).
  • Figovsky, O., Beilin, D., Blank, N., Potapov, J., Chernyshev, V., “Development of polymer concrete with polybutadiene matrix”, Cement and Concrete Composites, 18: 437-444 (1996).
  • Weber, H.H., McBee, W.C., Krabbe, E.A., “Sulfur concrete composite materials for construction and maintenance”, Materials Performance, 29: 73-77 (1990).
  • Leitheiser, R.H., Londrigan, M.E., Rude, C.A., “Furan resinous cements”, American Chemical Society Symposium, Washington, USA, 7-26 (1979).
  • Seymour, R.B., “Plastic Mortars, Sealants, and Caulking Compounds”, American Chemical Society Symposium, Washington, USA, 184 (1979).
  • Sugama, T., Kukacka, L.E., Horn, W., “Properties of water-compatible furfuryl alcohol polymer concrete”, Cement and Concrete Research, 11: 497-506 (1981).
  • Semler, C., Hawisher, T., Pieterse, H., Williams, R., “Acid resistant cement composition”, US Patent, 5: 989, 330 (1999).
  • Subbotkin, M.I., Kuritsina, Y.S., “Acid-proof concrete and mortar on the basis of water glass”, Stroyizdat, Moscow, Russia (1967).
  • Moskvin, V.I., “Physicochemical investigation of concrete and its components”, Stroyizdat, Moscow, Russia (1976).
  • Sychev, D.I., “Adhesive on the basis of silicate alkaline metals”, Nauka, Moscow, Russia (1986).
  • Babushkin, V.I., Plugin, A.A., “Acid-proof binding composites and concretes for protection of building from corrosion”, Chemistry and Technology of Cement, Moscow, Russia, 144-150 (2000).
  • Xiong, G.J., Chen, X.H., Chen, L.Q., Yang, J.Z., Li, G.Y., “Hybrid modified ferrocement under sustained load in flowing sulphuric acid solution”, Cement and Concrete Composites, 26: 8-86 (2004).
  • Traulsen, C., Nielsen, N.J.R., Nielsen, T.S., “Tests validate fiber glass cement to protect subsea FBE coating”, Oil and Gas Journal, 88: 72-76 (1990).
  • Zivica, V., “Experimental principles in the
  • research of chemical resistance of cement based materials”, Construction and Building Materials, 12: 365-371 (1998).
  • Butt, J.M., Sychev, M.M., Timashev, V.V.,
  • “Chemical technology of binding materials”, Stroyizdat, Moscow, Russia (1980).
  • Moskvin, V.M., “Durability of concrete and corrosion theory”, Hydrotechnical Construction, 19: 379-385 (1985).
There are 24 citations in total.

Details

Primary Language English
Journal Section Chemistry
Authors

Mirabbos Hojamberdıev This is me

Zamira Muhamedbaeva This is me

Yunhua Xu This is me

Fazhan Wang This is me

Surayo Julchıeva This is me

Publication Date April 1, 2010
Published in Issue Year 2008 Volume: 21 Issue: 3

Cite

APA Hojamberdıev, M., Muhamedbaeva, Z., Xu, Y., Wang, F., et al. (2010). Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites. Gazi University Journal of Science, 21(3), 105-112.
AMA Hojamberdıev M, Muhamedbaeva Z, Xu Y, Wang F, Julchıeva S. Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites. Gazi University Journal of Science. March 2010;21(3):105-112.
Chicago Hojamberdıev, Mirabbos, Zamira Muhamedbaeva, Yunhua Xu, Fazhan Wang, and Surayo Julchıeva. “Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites”. Gazi University Journal of Science 21, no. 3 (March 2010): 105-12.
EndNote Hojamberdıev M, Muhamedbaeva Z, Xu Y, Wang F, Julchıeva S (March 1, 2010) Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites. Gazi University Journal of Science 21 3 105–112.
IEEE M. Hojamberdıev, Z. Muhamedbaeva, Y. Xu, F. Wang, and S. Julchıeva, “Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites”, Gazi University Journal of Science, vol. 21, no. 3, pp. 105–112, 2010.
ISNAD Hojamberdıev, Mirabbos et al. “Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites”. Gazi University Journal of Science 21/3 (March 2010), 105-112.
JAMA Hojamberdıev M, Muhamedbaeva Z, Xu Y, Wang F, Julchıeva S. Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites. Gazi University Journal of Science. 2010;21:105–112.
MLA Hojamberdıev, Mirabbos et al. “Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites”. Gazi University Journal of Science, vol. 21, no. 3, 2010, pp. 105-12.
Vancouver Hojamberdıev M, Muhamedbaeva Z, Xu Y, Wang F, Julchıeva S. Effect of Waste Polymer Additives on the Properties of Acid Resistant Composites. Gazi University Journal of Science. 2010;21(3):105-12.