Elektrodepolama ile Üretilen CoNi Alaşım İnce Film Kaplamaların Yapısal ve Manyetik Özellikleri Üzerine Ek Katkı Maddelerinin Etkisi

Year 2019, Volume: 7 Issue: 3, 661 - 675, 27.09.2019

Rasim Özdemir

https://doi.org/10.29109/gujsc.569110

Abstract

Metallerin ve alaşımların elektrodepolanması bir veya daha
fazla organik veya inorganik ek katkı maddeleri içerebilir. Ek katkılar; depolanan
ince film kaplamaların yüzey morfolojisine, tane büyüklüğüne ve kristal
yapısına etki etmektedir. Bu çalışmada CoNi alaşım ince film kaplamalar, katkı
madde olmadan ve ek katkı maddeleri (organik kumarin ve tiyoüre) kullanılarak
elektrodepolamayla üretildi. Ek katkısız depolanan CoNi alaşım ince film
kaplamanın; kristal yapısının yüzey merkezli kübik (fcc) ve kaplama
içeriğindeki kobalt miktarının % 67.94 olduğu bulundu. Banyo kompozisyonuna,
kumarin katıldığında film içeriğindeki kobaltın % 43.82’ye, tiyoüre
katıldığında %34.33’e düştüğü ve her iki filmin amorf özellik gösterdiği
belirlendi. Uygulanan manyetik alan, -75000 Oe ile +75000 Oe arasında değiştirilerek,
manyetizasyon değerleri ölçüldü ve histerezis eğrileri elde edildi. Katkı
maddelerinin alaşım film içerisindeki madde miktarına, kristal yapıya ve
manyetik özelliklere büyük etki ettiği görüldü.

Keywords

Ek katkılar, Kumarin ve tiyoüre, Kobalt-nikel, İnce film, Manyetizasyon

Supporting Institution

KİLİS 7 ARALIK ÜNİVERSİTESİ BİLİMSEL ARAŞTIRMALAR BİRİMİ

Project Number

BAP-2014/02/LTP/05

The Effect of Additives on Structural and Magnetic Properties of CoNi Alloy Thin Film Coatings Produced by Electrodeposition

Abstract

Electrodeposition
of metals and alloys may contain one or more organic or inorganic additives.
Additives it affects the surface morphology, grainsize and crystal structure of
the thin film coatings. In this study, CoNi alloy thin film coatings were
produced by electrodeposition without additives and using additional additives
(organic coumarin and thiourea). CoNi alloy thin film coating produced without
additional additive; It was found that the crystal structure was face centered
cubic (fcc) and the cobalt content of the coating was 67.94%. When coumarin was
added to the bath composition, cobalt in the film content decreased to 43.82%,
decreased to 34.33% when thiourea was added, and both films showed amorphous
properties. The magnetic field applied was changed between -75000 Oe to +75000
Oe, magnetization values were measured and hysteresis curves were obtained. It
was seen that the additives had a great effect on the amount of matter, crystal
structure and magnetic properties in the alloy film.

Keywords

Additives, Coumarin and thiourea, Cobalt-nickel, Thin film, Magnetization

Project Number

BAP-2014/02/LTP/05

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