Chiral Separations by Capillary Electrophoresis and related Techniques with Different Chiral Selectors: A Review

Abstract

Kiral bileşiklerin tanınma mekanizması ve enantiyomerik olarak ayrılması, hem analitik saflık hem de büyük ölçekli çalışmalar için çözüm bulmakla ilgilenen farmakoloji ve doğa bilimlerindeki araştırmacıların büyük ilgisini her zaman uyandıran konulardır. Kapiler Elektroforez, kiral selektörlerin yüksek çözünürlüğü ve yüksek verimliliği gibi üstün özellikleri nedeniyle enantiyomerik ayırımlar için en önemli analitik yaklaşımlardan biri haline gelmiştir. Araştırmacıların ilgi göstermeye devam ettiği bu alanda, teknolojinin ve farklı formdaki kiral selektörlerin gelişim sürecine paralel olarak Kapiler Elektroforez felsefesi temelinde geliştirilen yeni tekniklerin varlığıyla gün geçtikçe gelişmeler ilerlemektedir. Bu derlemede, kapiler elektroforez ve bununla ilişkili teknikler hakkında bazı tanımlayıcı teorik bilgilerin yanı sıra, moleküler baskılanmış polimerler, siklodekstrinler, metal-organik kafesler, iyonik sıvılar, monolitler ve nanopartiküller gibi farklı kiral selektörler kullanılarak kiral ayırmalar üzerine yaklaşık son 10 yıldaki (2010-2020) çalışmalar derlenmiştir.

Keywords

• Kapiler Elektroforez
• kiral selektörler
• kiral katkı maddeleri
• kiral ayırım

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