Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II

Dursun Ali Kose; Hasan Icbudak; Hacali Necefoglu

Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II

Abstract

Nicotinamide-acetylsalicylato complexes of Co II , Ni II , Cu II , and Zn II were synthesised and their structural properties were investigated by employing elemental analysis, magnetic susceptibilitiy, solid state UV-vis, direct injectionprobe mass, FTIR and thermoanalytic TG-DTG methods. It was found that ratio of metal:ligand:ligand is 1:2:2 and thedecomposition of each complex starts with dehydration and follows by decomposition of the nicotinamide and acetylsalicylato, respectively. The thermal dehydration of the complexes takes place in steps from one to two. The decomposition mechanism and thermal stability of the investigated complexes are interpreted in terms of their structures. Thefinal decomposition products are found to be the respective metal oxides

Keywords

Nicotinamide,N,N-diethylnicotinamide,acetylsalicylato,Thermal decomposition,metal complexes

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Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Dursun Ali Kose This is me

Hasan Icbudak This is me

Hacali Necefoglu This is me

Publication Date

April 1, 2007

Submission Date

-

Acceptance Date

-

Published in Issue

Year 2007 Volume: 35 Number: 2

IZ

https://izlik.org/JA94PU46CX

Cite

RIS / Bibtex

APA

Kose, D. A., Icbudak, H., & Necefoglu, H. (2007). Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. Hacettepe Journal of Biology and Chemistry, 35(2), 123-128. https://izlik.org/JA94PU46CX

AMA

1.Kose DA, Icbudak H, Necefoglu H. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC. 2007;35(2):123-128. https://izlik.org/JA94PU46CX

Chicago

Kose, Dursun Ali, Hasan Icbudak, and Hacali Necefoglu. 2007. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry 35 (2): 123-28. https://izlik.org/JA94PU46CX.

EndNote

Kose DA, Icbudak H, Necefoglu H (April 1, 2007) Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. Hacettepe Journal of Biology and Chemistry 35 2 123–128.

IEEE

[1]D. A. Kose, H. Icbudak, and H. Necefoglu, “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”, HJBC, vol. 35, no. 2, pp. 123–128, Apr. 2007, [Online]. Available: https://izlik.org/JA94PU46CX

ISNAD

Kose, Dursun Ali - Icbudak, Hasan - Necefoglu, Hacali. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry 35/2 (April 1, 2007): 123-128. https://izlik.org/JA94PU46CX.

JAMA

1.Kose DA, Icbudak H, Necefoglu H. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC. 2007;35:123–128.

MLA

Kose, Dursun Ali, et al. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry, vol. 35, no. 2, Apr. 2007, pp. 123-8, https://izlik.org/JA94PU46CX.

Vancouver

1.Dursun Ali Kose, Hasan Icbudak, Hacali Necefoglu. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC [Internet]. 2007 Apr. 1;35(2):123-8. Available from: https://izlik.org/JA94PU46CX