Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS

Muharrem Karabörk; Arzu Ersöz; Ebru Birlik; Rıdvan Say

Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS

Abstract

Novel Fe III -imprinted beads were prepared by molecular imprinting technique for selective solid-phase extraction SPE of Fe III ions prior to its determination by flame atomic absorption spectrometry FAAS . The functional metalcomplexing monomer and crosslinking monomer used were methacrylamidoantipyrine MAAP and ethyleneglycoldimethacrylate EGDMA , respectively. MAAP was synthesized using methacryloylchloride, 4-aminoantipyrine andpyridine. Fe III ions were complexed with MAAP and the Fe III -imprinted poly MAAP-EGDMA beads were synthesized by suspension polymerization. After that, the template ions i.e., Fe III ions were removed using 4.0 M HNO3solution. The specific surface area of the Fe III -imprinted and non-imprinted poly MAAP-EGDMA beads was foundto be 1181.45 m2/g and 437.94 m2/g, respectively. The swelling ratio was 60% and 47% for imprinted and non-imprintedbeads, respectively. According to the elemental analysis results, the beads contained 119.0 µmol MAAP/g polymer.The maximum adsorption capacity, optimum pH and equilibrium binding time were 29.32 mg/g, 4.0 and 80 min, respectively. Selectivity coefficients for Al III , Cu II , Zn II and Co II ions were compared with Fe III ion. Fe III -imprinted beads showed the following order of metal ion affinity: Fe III >Zn II >Cu II >Co II >Al III . The Fe III -imprintedpoly MAAP-EGDMA beads could be used many times without decreasing their adsorption capacities significantly

Keywords

Ion imprinting IIP,FAAS,Fe III ion,Preconcentration,solid phase extraction.

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Details

Primary Language

English

Subjects

-

Journal Section

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Authors

Muharrem Karabörk This is me

Arzu Ersöz This is me

Ebru Birlik This is me

Rıdvan Say This is me

Publication Date

April 1, 2007

Submission Date

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Acceptance Date

-

Published in Issue

Year 2007 Volume: 35 Number: 2

IZ

https://izlik.org/JA59KD33XW

Cite

RIS / Bibtex

APA

Karabörk, M., Ersöz, A., Birlik, E., & Say, R. (2007). Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. Hacettepe Journal of Biology and Chemistry, 35(2), 135-142. https://izlik.org/JA59KD33XW

AMA

1.Karabörk M, Ersöz A, Birlik E, Say R. Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. HJBC. 2007;35(2):135-142. https://izlik.org/JA59KD33XW

Chicago

Karabörk, Muharrem, Arzu Ersöz, Ebru Birlik, and Rıdvan Say. 2007. “Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS”. Hacettepe Journal of Biology and Chemistry 35 (2): 135-42. https://izlik.org/JA59KD33XW.

EndNote

Karabörk M, Ersöz A, Birlik E, Say R (April 1, 2007) Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. Hacettepe Journal of Biology and Chemistry 35 2 135–142.

IEEE

[1]M. Karabörk, A. Ersöz, E. Birlik, and R. Say, “Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS”, HJBC, vol. 35, no. 2, pp. 135–142, Apr. 2007, [Online]. Available: https://izlik.org/JA59KD33XW

ISNAD

Karabörk, Muharrem - Ersöz, Arzu - Birlik, Ebru - Say, Rıdvan. “Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS”. Hacettepe Journal of Biology and Chemistry 35/2 (April 1, 2007): 135-142. https://izlik.org/JA59KD33XW.

JAMA

1.Karabörk M, Ersöz A, Birlik E, Say R. Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. HJBC. 2007;35:135–142.

MLA

Karabörk, Muharrem, et al. “Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS”. Hacettepe Journal of Biology and Chemistry, vol. 35, no. 2, Apr. 2007, pp. 135-42, https://izlik.org/JA59KD33XW.

Vancouver

1.Muharrem Karabörk, Arzu Ersöz, Ebru Birlik, Rıdvan Say. Preconcentration of Fe III Using Fe III -Ion Imprinted Polymeric Traps and Its Analytical Performance for FAAS. HJBC [Internet]. 2007 Apr. 1;35(2):135-42. Available from: https://izlik.org/JA59KD33XW