Hydrothermal Synthesis of MIL-53 Catalyst for Liquid Phase Oxidation of Phenol Fenolün Sıvı Faz Oksidasyonu için Mil-53 Katalizörünün Hidrotermal Sentezi

Year 2019, Volume: 47 Issue: 2, 217 - 223, 18.09.2019

Okan İçten , Demet Özer

https://doi.org/10.15671/hjbc.623801

Abstract

For the removal of toxic organic phenol pollutants, to find a new alternative oxidation catalyst has been an important
topic for a long time. Iron terephthalate (MIL-53) is an efficient catalyst for oxidation processes with high porosity and
high surface area. In this study, MIL-53 was used for the oxidation of phenol. The catalyst was synthesized by hydrothermal
method at 150°C for 2 h. It was structurally characterized by FT-IR and p-XRD. Thermal properties were also examined. The
surface area was found as 152 m2
/g with micropore areas. The liquid phase oxidation of phenol by hydrogen peroxide was
performed on MIL-53. The reaction time, reaction temperature, catalyst amount and oxidant amount were also investigated.
The phenol was removed with 91% conversion for 3 hours at 80°C. MIL-53 was enhanced as an alternative catalyst for liquid
phase oxidation of phenol with high efficiency, selectivity, and conversion.

Keywords

Hydrothermal synthesis, MIL-53, phenol oxidation

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