Year 2020, Volume 48 , Issue 1, Pages 75 - 82 2020-04-17

Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor

Monireh BAKHSHPOUR [1] , İlgım GÖKTÜRK [2] , Oğuz ÇAKIR [3] , Fatma YILMAZ [4] , Zübeyde BAYSAL [5] , Adil DENİZLİ [6]


In this study, Chlorpyrifos (Cps) imprinted nanoparticles based QCM sensor were prepared for detection of chlorpyrifos pesticide. Cps imprinted poly(ethylene glycol dimethacrylate- N-metacryloyl-(L)-tryptophan) (PEDMATrp) nanoparticles were prepared and then these nanoparticles were attached to the surface of QCM sensor chip. Also, non-imprinted PEDMATrp QCM sensor was prepared without using the Cps molecule to evaluate the imprinting efficiency. Cps imprinted and non-imprinted nanoparticles were characterized by zeta-sizer and Fourier transform infrared spectrophotometer-attenuated total reflection (FTIR-ATR) spectrophotometer. Cps imprinted and non-imprinted QCM sensors were also characterized by atomic force microscopy, ellipsometer, and contact angle measurements. The prepared sensors were applied for selective Cps detection in aqueous solution for the range of 0.015-2.9 nM. The selectivity studies of the prepared PEDMATrp quartz crystal microbalance sensor were examined by using competitive pesticide molecules such as Diazinon and Parathion (0.75 nM), which are similar to Cps in size and shape. The reusability studies of the prepared sensors were investigated by applying the same pesticide concentration (1.45 nM), four times consecutively.

Chlorpyrifos, Molecular imprinting, Nanoparticle, Quartz crystal microbalance
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Primary Language en
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0002-5737-720X
Author: Monireh BAKHSHPOUR

Orcid: 0000-0001-7292-7241
Author: İlgım GÖKTÜRK

Orcid: 0000-0002-8006-2054
Author: Oğuz ÇAKIR

Orcid: 0000-0003-3260-1639
Author: Fatma YILMAZ

Orcid: 0000-0001-7682-4469
Author: Zübeyde BAYSAL
Institution: DİCLE ÜNİVERSİTESİ
Country: Turkey


Orcid: 0000-0001-7548-5741
Author: Adil DENİZLİ (Primary Author)
Country: Turkey


Dates

Publication Date : April 17, 2020

Bibtex @research article { hjbc629138, journal = {Hacettepe Journal of Biology and Chemistry}, issn = {2687-475X}, eissn = {2687-475X}, address = {Hacettepe Üniversitesi Fen Fakültesi, 06532, Beytepe/ ANKARA/ TÜRKİYE}, publisher = {Hacettepe University}, year = {2020}, volume = {48}, pages = {75 - 82}, doi = {10.15671/hjbc.629138}, title = {Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor}, key = {cite}, author = {Bakhshpour, Monireh and Göktürk, İlgım and Çakır, Oğuz and Yılmaz, Fatma and Baysal, Zübeyde and Denizli, Adil} }
APA Bakhshpour, M , Göktürk, İ , Çakır, O , Yılmaz, F , Baysal, Z , Denizli, A . (2020). Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor . Hacettepe Journal of Biology and Chemistry , 48 (1) , 75-82 . DOI: 10.15671/hjbc.629138
MLA Bakhshpour, M , Göktürk, İ , Çakır, O , Yılmaz, F , Baysal, Z , Denizli, A . "Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor" . Hacettepe Journal of Biology and Chemistry 48 (2020 ): 75-82 <https://dergipark.org.tr/en/pub/hjbc/issue/53781/629138>
Chicago Bakhshpour, M , Göktürk, İ , Çakır, O , Yılmaz, F , Baysal, Z , Denizli, A . "Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor". Hacettepe Journal of Biology and Chemistry 48 (2020 ): 75-82
RIS TY - JOUR T1 - Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor AU - Monireh Bakhshpour , İlgım Göktürk , Oğuz Çakır , Fatma Yılmaz , Zübeyde Baysal , Adil Denizli Y1 - 2020 PY - 2020 N1 - doi: 10.15671/hjbc.629138 DO - 10.15671/hjbc.629138 T2 - Hacettepe Journal of Biology and Chemistry JF - Journal JO - JOR SP - 75 EP - 82 VL - 48 IS - 1 SN - 2687-475X-2687-475X M3 - doi: 10.15671/hjbc.629138 UR - https://doi.org/10.15671/hjbc.629138 Y2 - 2020 ER -
EndNote %0 Hacettepe Journal of Biology and Chemistry Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor %A Monireh Bakhshpour , İlgım Göktürk , Oğuz Çakır , Fatma Yılmaz , Zübeyde Baysal , Adil Denizli %T Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor %D 2020 %J Hacettepe Journal of Biology and Chemistry %P 2687-475X-2687-475X %V 48 %N 1 %R doi: 10.15671/hjbc.629138 %U 10.15671/hjbc.629138
ISNAD Bakhshpour, Monireh , Göktürk, İlgım , Çakır, Oğuz , Yılmaz, Fatma , Baysal, Zübeyde , Denizli, Adil . "Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor". Hacettepe Journal of Biology and Chemistry 48 / 1 (April 2020): 75-82 . https://doi.org/10.15671/hjbc.629138
AMA Bakhshpour M , Göktürk İ , Çakır O , Yılmaz F , Baysal Z , Denizli A . Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor. HJBC. 2020; 48(1): 75-82.
Vancouver Bakhshpour M , Göktürk İ , Çakır O , Yılmaz F , Baysal Z , Denizli A . Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor. Hacettepe Journal of Biology and Chemistry. 2020; 48(1): 75-82.
IEEE M. Bakhshpour , İ. Göktürk , O. Çakır , F. Yılmaz , Z. Baysal and A. Denizli , "Detection of Pesticide via Nanoparticle Based Quartz Crystal Microbalance Sensor", Hacettepe Journal of Biology and Chemistry, vol. 48, no. 1, pp. 75-82, Apr. 2020, doi:10.15671/hjbc.629138