Year 2021, Volume 49 , Issue 1, Pages 57 - 68 2021-01-01

Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture

Özge YÜKSEL ORHAN [1]


The CO2 absorption-desorption performance of non-aqueous solutions comprising a sterically hindered amine system (2-amino-2-ethyl-1,3-propanediol (AEPD): 1-hexanol) was investigated in a gas-liquid stirred cell reactor under sequential absorption-desorption cycles. The absorption capacity and initial absorption rate were calculated for different concentrations of AEPD: 1-hexanol at 303 K and 2 bar absolute pressure. Increasing the amount of AEPD increased the CO2 absorption capacity. The biocatalytic effect of a constant amount of carbonic anhydrase (CA) on the CO2 absorption performance was also investigated, and the CA enzyme was found to increase the total amount of absorbed CO2. The CO2 loading of AEPD: 1-hexanol and CA activated AEPD: 1-hexanol were 0.88 and 0.97 mol CO2/mol AEPD, respectively. CO2 desorption experiments were performed in different sequences of the same experimental set-up at 363 K and 1.1 bar absolute N2 pressure. The effect of ultrasonic irradiation on the desorption performance of 0.1 g/L CA catalyzed AEPD: 1-hexanol system was also investigated. It was observed that ultrasonic assistance shortened the desorption time and enhanced the desorption rate. Furthermore, the effectiveness of regeneration, the reusability, and performance loss of AEPD: 1-hexanol, in the presence and absence of CA, were analyzed by Fourier transform infrared spectrometry.
CO2 capture, Carbonic anhydrase, FTIR, Sterically hindered amines
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Primary Language en
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0003-0135-0363
Author: Özge YÜKSEL ORHAN (Primary Author)
Institution: Hacettepe Üniversitesi
Country: Turkey


Thanks Authors gratefully acknowledge for valuable support of Hacettepe Technology Transfer Center (HT‐TTM).
Dates

Publication Date : January 1, 2021

Bibtex @research article { hjbc776359, journal = {Hacettepe Journal of Biology and Chemistry}, issn = {2687-475X}, eissn = {2687-475X}, address = {Hacettepe Üniversitesi Fen Fakültesi, 06532, Beytepe/ ANKARA/ TÜRKİYE}, publisher = {Hacettepe University}, year = {2021}, volume = {49}, pages = {57 - 68}, doi = {10.15671/hjbc.776359}, title = {Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture}, key = {cite}, author = {Yüksel Orhan, Özge} }
APA Yüksel Orhan, Ö . (2021). Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture . Hacettepe Journal of Biology and Chemistry , 49 (1) , 57-68 . DOI: 10.15671/hjbc.776359
MLA Yüksel Orhan, Ö . "Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture" . Hacettepe Journal of Biology and Chemistry 49 (2021 ): 57-68 <https://dergipark.org.tr/en/pub/hjbc/issue/58116/776359>
Chicago Yüksel Orhan, Ö . "Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture". Hacettepe Journal of Biology and Chemistry 49 (2021 ): 57-68
RIS TY - JOUR T1 - Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture AU - Özge Yüksel Orhan Y1 - 2021 PY - 2021 N1 - doi: 10.15671/hjbc.776359 DO - 10.15671/hjbc.776359 T2 - Hacettepe Journal of Biology and Chemistry JF - Journal JO - JOR SP - 57 EP - 68 VL - 49 IS - 1 SN - 2687-475X-2687-475X M3 - doi: 10.15671/hjbc.776359 UR - https://doi.org/10.15671/hjbc.776359 Y2 - 2020 ER -
EndNote %0 Hacettepe Journal of Biology and Chemistry Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture %A Özge Yüksel Orhan %T Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture %D 2021 %J Hacettepe Journal of Biology and Chemistry %P 2687-475X-2687-475X %V 49 %N 1 %R doi: 10.15671/hjbc.776359 %U 10.15671/hjbc.776359
ISNAD Yüksel Orhan, Özge . "Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture". Hacettepe Journal of Biology and Chemistry 49 / 1 (January 2021): 57-68 . https://doi.org/10.15671/hjbc.776359
AMA Yüksel Orhan Ö . Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture. HJBC. 2021; 49(1): 57-68.
Vancouver Yüksel Orhan Ö . Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture. Hacettepe Journal of Biology and Chemistry. 2021; 49(1): 57-68.
IEEE Ö. Yüksel Orhan , "Investigation of Biocatalytic Absorption and Ultrasound-Assisted Desorption Performance of CO2 Capture", Hacettepe Journal of Biology and Chemistry, vol. 49, no. 1, pp. 57-68, Jan. 2021, doi:10.15671/hjbc.776359