Synthesis of vic-Dioxime Derivatives with Semicarbazone Side Groups and Their Ni II Complexes

Year 2007, Volume: 35 Issue: 2, 117 - 121, 01.04.2007

İlknur Babahan Hüseyin Anıl Nursabah Sarıkavaklı

Abstract

In this work, two novel vic-dioxime L1H2, L2H2 compounds bearing semicarbazone side groups and their Ni II complexes were synthesized. The vic-dioxime ligands of bearing semicarbazone side groups were synthesized by reactinganti-chloroglyoxime with semicarbazidehydrochloride, 4-aminoacetophenenone semicarbazone, respectively. Ligands form mononuclear complexes [Ni LH 2] with a metal:ligand ratio of 1:2. The Ni II complexes are proposed tobe square planar. Structural assignments are supported by a combination of1H-NMR,13C-NMR, HMQC, FT-IR, UV,elemental analyses and magnetic susceptibility

Keywords

vic-Dioximes, Semicarbazones, Transition metal complexes

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