Synthesis, Spectroscopic and Thermal Characterization of Non-Metal Cation NMC Pentaborates Salts Containing Cations Derived From Histidine and Arginine

Year 2012, Volume: 40 Issue: 3, 219 - 225, 01.08.2012

Dursun Ali Kose , Michael A. Beckett Naki Çolak

Abstract

The new non-metal cation NMC pentaborate structures of cationic histidine and arginine aminoacids were synthesized and characterized using spectroscopic 11B NMR and IR methods. Their thermal properties have been investigated by TG/DrTG-DTA. The histidine NMC pentaborate, [C6H10N3O2][B5O6 OH 4].4H2O and the arginine pentaborate, [C6H13N4O2][B5O6 OH 4]2.3H2O are formulated with 4 and 3 waters of crystallization, respectively. The histidine pentaborate is more stable than the arginine pentaborate to thermal decomposition, but both decompose thermally via initial dehydration followed by loss of amino acid fragments to afford glassy B2O3.

Keywords

Non-metal cation borate structure, Pentaborate, Thermal investigation, 11B NMR

Katyonik Histidine ve Arjinin Türevleri İçeren Metal Katyonsuz NMC Pentaborat Tuzlarının Sentezi, Spektroskopik ve Termal Karakterizasyonu

Abstract

K atyonik histidin ve arjinin aminoasitlerinin metal katyonu içermeyen NMC yeni pentaborat yapıları sentezlendi ve spektroskopik yöntemler 11B NMR and IR kullanılarak karakterize edildi. Termal özellikleri TG/DrTG-DTA ile araştırıldı. Histidine NMC pentaborat, [CHN[C6H13N4O2][B5O6 OH 42.3H2O yapılarının sırasıyla 4 ve 3 molekül Kristal suları içerdikleri tespit edilmiştir. Termal olarak histidine pentaborat arjinin pentaborat yapısına göre daha kararlıdır, fakat her iki NMC pentaborat yapısının bozunması dehidrasyonu izleyen aminoasit bölümlerinin uzaklaşması ve bozunma ürünü olarak camsı yapıda BO kalmasıyla gerçekleşir

Keywords

Metal katyonu içermeyen borat yapısı, Pentaborat, Termal inceleme, 11B NMR

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