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Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles

Year 2022, Volume: 8 Issue: 1, 24 - 30, 30.06.2022
https://doi.org/10.29132/ijpas.993988

Abstract

Composites were prepared using polyvinyl chloride (PVC) and different percentages of Fe2O3 nanoparticles. All composites were characterized by FT-IR spectroscopy. Then, the thermal properties of the composites prepared in 1% and 10% ratios were examined. It was observed that the initial decomposition temperature (Ti) values of PVC composites prepared with Fe2O3 nanoparticles addition were lower than pure PVC. Magnetic properties of composites were examined with a vibrating sample magnetometer (VSM). The saturation magnetization values of PVC composites prepared by using 1% and 10% Fe2O3 were 2.77 and 7.06 emu / g, respectively.

References

  • Adem, A., 2019. Akış Enjeksiyon Analiz Yönteminde Dedektör Olarak Potansiyometrik Sensör Kullanarak Çevre Numunelerinde Kalsiyum İyonu Tayini. International Journal of Pure and Applied Sciences, 5 (1): 37-45.
  • Al-Ramadhan, Z., Hashim, A., Ali, M., Jewad, A., 2012. Synthesis and study the electrical properties of carbon nanotubes-polyvinylchloride composites. Iraqi Journal of Physics, 10 (18): 147-150.
  • Balazs, A.C., Emrick, T., Russell, T.P., 2006. Nanoparticle polymer composites: where two small worlds meet. science, 314 (5802): 1107-1110.
  • Berry, C.C., Curtis, A.S., 2003. Functionalisation of magnetic nanoparticles for applications in biomedicine. Journal of physics D: Applied physics, 36 (13): R198.
  • Byrne, M.T., Gun'ko, Y.K., 2010. Recent advances in research on carbon nanotube–polymer composites. Advanced materials, 22 (15): 1672-1688.
  • Caizer, C., 2003. Saturation magnetization of γ-Fe2O3 nanoparticles dispersed in a silica matrix. Physica B: Condensed Matter, 327 (1): 27-33.
  • Chen, C., Wesson, R., Collier, J., Lo, Y., 1995. Studies of rigid poly (vinyl chloride)(PVC) compounds. I. Morphological characteristics of poly (vinyl chloride)/chlorinated polyethylene (PVC/CPE) blends. Journal of applied polymer science, 58 (7): 1087-1091.
  • Chouly, C., Pouliquen, D., Lucet, I., Jeune, J., Jallet, P., 1996. Development of superparamagnetic nanoparticles for MRI: effect of particle size, charge and surface nature on biodistribution. Journal of microencapsulation, 13 (3): 245-255.
  • Conn, C., Booth, N., Unsworth, J., 1995. Preparation of a flexible polyaniline‐pvc composite. Advanced materials, 7 (9): 790-792.
  • Djidjelli, H., Martinez‐Vega, J.J., Farenc, J., Benachour, D., 2002. Effect of wood flour content on the thermal, mechanical and dielectric properties of poly (vinyl chloride). Macromolecular Materials and Engineering, 287 (9): 611-618.
  • Gossuin, Y., Gillis, P., Hocq, A., Vuong, Q.L., Roch, A., 2009. Magnetic resonance relaxation properties of superparamagnetic particles. Wiley Interdisciplinary Reviews: Nanomedicine and Nanobiotechnology, 1 (3): 299-310.
  • Haruna, H., Pekdemir, M.E., Tukur, A., Coşkun, M., 2020. Characterization, thermal and electrical properties of aminated PVC/oxidized MWCNT composites doped with nanographite. Journal of Thermal Analysis and Calorimetry1-9.
  • Hassan Haruna, M.E.P., Mehmet Coşkun, 2019. A study on aminated PVC/oxidized MWCNT composites. Academia Journal of Scientific Research, 7 (2): 86-94.
  • Klarić, I., Vrandečić, N.S., Roje, U., 2000. Effect of poly (vinyl chloride)/chlorinated polyethylene blend composition on thermal stability. Journal of applied polymer science, 78 (1): 166-172.
  • Kommareddi, N.S., Tata, M., John, V.T., McPherson, G.L., Herman, M.F., Lee, Y.-S. ve Kaplan, D.L., 1996. Synthesis of superparamagnetic polymer− ferrite composites using surfactant microstructures. Chemistry of materials, 8 (3): 801-809.
  • Lee, J.-H., Huh, Y.-M., Jun, Y.-w., Seo, J.-w., Jang, J.-t., Song, H.-T. ve Suh, J.-S., 2007. Artificially engineered magnetic nanoparticles for ultra-sensitive molecular imaging. Nature medicine, 13 (1): 95-99. Lu, A.H., Salabas, E.e.L., Schüth, F., 2007. Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angewandte Chemie International Edition, 46 (8): 1222-1244.
  • Ma, P.-C., Siddiqui, N.A., Marom, G., Kim, J.-K., 2010. Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Composites Part A: Applied Science and Manufacturing, 41 (10): 1345-1367.
  • Matuana, L.M., Park, C.B., Balatinecz, J.J., 1998. Cell morphology and property relationships of microcellular foamed pvc/wood‐fiber composites. Polymer Engineering & Science, 38 (11): 1862-1872.
  • Moniruzzaman, M., Winey, K.I., 2006. Polymer nanocomposites containing carbon nanotubes. Macromolecules, 39 (16): 5194-5205.
  • Ouyang, M., Chan, C.M., 1996. Electrical and mechanical properties of pre‐localized polypyrrole/poly (vinyl chloride) conductive composites. Polymer Engineering & Science, 36 (21): 2676-2682.
  • Pekdemir, M.E., Pekdemir, S., İnci, Ş., Kırbağ, S., Çiftci, M., 2021. Thermal, Magnetic Properties and Antimicrobial Effects of Magnetic Iron Oxide Nanoparticles Treated with Polygonum cognatum. Iranian Journal of Science and Technology, Transactions A: Science, 45 1579-1586.
  • Shafi, K.V., Ulman, A., Yan, X., Yang, N.-L., Estournes, C., White, H., Rafailovich, M., 2001. Sonochemical synthesis of functionalized amorphous iron oxide nanoparticles. Langmuir, 17 (16): 5093-5097.
  • Sun, S., Li, C., Zhang, L., Du, H., Burnell‐Gray, J., 2006. Interfacial structures and mechanical properties of PVC composites reinforced by CaCO3 with different particle sizes and surface treatments. Polymer international, 55 (2): 158-164.
  • Sun, S., Murray, C.B., Weller, D., Folks, L., Moser, A., 2000. Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science, 287 (5460): 1989-1992.
  • Tanaydın, M.K., 2021. Hidrometalurjik Yöntemlerle Nadir Toprak Elementlerinin Kazanılması. International Journal of Pure and Applied Sciences, 7 (2): 288-304.
  • Thostenson, E.T., Ren, Z., Chou, T.-W., 2001. Advances in the science and technology of carbon nanotubes and their composites: a review. Composites science and technology, 61 (13): 1899-1912.
  • TUKUR, A., PEKDEMİR, M.E., COŞKUN, M., 2020. Investigation of structural, thermal and dielectric properties of PVC/modified magnetic nanoparticle composites. Cumhuriyet Science Journal, 41 (2): 377-385.
  • Vadukumpully, S., Paul, J., Mahanta, N., Valiyaveettil, S., 2011. Flexible conductive graphene/poly (vinyl chloride) composite thin films with high mechanical strength and thermal stability. Carbon, 49 (1): 198-205.
  • Weissleder, R., Moore, A., Mahmood, U., Bhorade, R., Benveniste, H., Chiocca, E.A., Basilion, J.P., 2000. In vivo magnetic resonance imaging of transgene expression. Nature medicine, 6 (3): 351-354.
  • Wilson, J., Poddar, P., Frey, N., Srikanth, H., Mohomed, K., Harmon, J. ve Wachsmuth, J., 2004. Synthesis and magnetic properties of polymer nanocomposites with embedded iron nanoparticles. Journal of Applied Physics, 95 (3): 1439-1443. Yaacob, I.I., Nunes, A.C., Bose, A., 1995. Magnetic nanoparticles produced in spontaneous cationic-anionic vesicles: room temperature synthesis and characterization. Journal of colloid and interface science, 171 (1): 73-84.
  • Zhang, Y., Kohler, N., Zhang, M., 2002. Surface modification of superparamagnetic magnetite nanoparticles and their intracellular uptake. Biomaterials, 23 (7): 1553-1561.

Farklı Oranlarda Fe2O3 (Maghemit) Nanopartikülleri Kullanılarak Hazırlanan Poli Vinil Klorür Kompozitlerinin Manyetik Özelliklerinin İncelenmesi

Year 2022, Volume: 8 Issue: 1, 24 - 30, 30.06.2022
https://doi.org/10.29132/ijpas.993988

Abstract

Polivinil klorür (PVC) ve farklı oranlarda Fe2O3 nanoparçacıkları kullanılarak kompozitler hazırlandı. Tüm kompozitler FT-IR spektroskopisi ile karakterize edildi. Ardından, %1 ve %10 oranlarında hazırlanan kompozitlerin termal özellikleri incelendi. Fe2O3 nanopartikül ilavesi ile hazırlanan PVC kompozitlerin başlangıç bozunma sıcaklığı (Ti) değerlerinin saf PVC'ye göre daha düşük olduğu görüldü. Titreşimli numune manyetometresi (VSM) ile kompozitlerin manyetik özellikleri incelendi. %1 ve %10 Fe2O3 kullanılarak hazırlanan PVC kompozitlerin doygunluk manyetizasyon değerleri sırasıyla 2,77 ve 7,06 emu/g bulundu.

References

  • Adem, A., 2019. Akış Enjeksiyon Analiz Yönteminde Dedektör Olarak Potansiyometrik Sensör Kullanarak Çevre Numunelerinde Kalsiyum İyonu Tayini. International Journal of Pure and Applied Sciences, 5 (1): 37-45.
  • Al-Ramadhan, Z., Hashim, A., Ali, M., Jewad, A., 2012. Synthesis and study the electrical properties of carbon nanotubes-polyvinylchloride composites. Iraqi Journal of Physics, 10 (18): 147-150.
  • Balazs, A.C., Emrick, T., Russell, T.P., 2006. Nanoparticle polymer composites: where two small worlds meet. science, 314 (5802): 1107-1110.
  • Berry, C.C., Curtis, A.S., 2003. Functionalisation of magnetic nanoparticles for applications in biomedicine. Journal of physics D: Applied physics, 36 (13): R198.
  • Byrne, M.T., Gun'ko, Y.K., 2010. Recent advances in research on carbon nanotube–polymer composites. Advanced materials, 22 (15): 1672-1688.
  • Caizer, C., 2003. Saturation magnetization of γ-Fe2O3 nanoparticles dispersed in a silica matrix. Physica B: Condensed Matter, 327 (1): 27-33.
  • Chen, C., Wesson, R., Collier, J., Lo, Y., 1995. Studies of rigid poly (vinyl chloride)(PVC) compounds. I. Morphological characteristics of poly (vinyl chloride)/chlorinated polyethylene (PVC/CPE) blends. Journal of applied polymer science, 58 (7): 1087-1091.
  • Chouly, C., Pouliquen, D., Lucet, I., Jeune, J., Jallet, P., 1996. Development of superparamagnetic nanoparticles for MRI: effect of particle size, charge and surface nature on biodistribution. Journal of microencapsulation, 13 (3): 245-255.
  • Conn, C., Booth, N., Unsworth, J., 1995. Preparation of a flexible polyaniline‐pvc composite. Advanced materials, 7 (9): 790-792.
  • Djidjelli, H., Martinez‐Vega, J.J., Farenc, J., Benachour, D., 2002. Effect of wood flour content on the thermal, mechanical and dielectric properties of poly (vinyl chloride). Macromolecular Materials and Engineering, 287 (9): 611-618.
  • Gossuin, Y., Gillis, P., Hocq, A., Vuong, Q.L., Roch, A., 2009. Magnetic resonance relaxation properties of superparamagnetic particles. Wiley Interdisciplinary Reviews: Nanomedicine and Nanobiotechnology, 1 (3): 299-310.
  • Haruna, H., Pekdemir, M.E., Tukur, A., Coşkun, M., 2020. Characterization, thermal and electrical properties of aminated PVC/oxidized MWCNT composites doped with nanographite. Journal of Thermal Analysis and Calorimetry1-9.
  • Hassan Haruna, M.E.P., Mehmet Coşkun, 2019. A study on aminated PVC/oxidized MWCNT composites. Academia Journal of Scientific Research, 7 (2): 86-94.
  • Klarić, I., Vrandečić, N.S., Roje, U., 2000. Effect of poly (vinyl chloride)/chlorinated polyethylene blend composition on thermal stability. Journal of applied polymer science, 78 (1): 166-172.
  • Kommareddi, N.S., Tata, M., John, V.T., McPherson, G.L., Herman, M.F., Lee, Y.-S. ve Kaplan, D.L., 1996. Synthesis of superparamagnetic polymer− ferrite composites using surfactant microstructures. Chemistry of materials, 8 (3): 801-809.
  • Lee, J.-H., Huh, Y.-M., Jun, Y.-w., Seo, J.-w., Jang, J.-t., Song, H.-T. ve Suh, J.-S., 2007. Artificially engineered magnetic nanoparticles for ultra-sensitive molecular imaging. Nature medicine, 13 (1): 95-99. Lu, A.H., Salabas, E.e.L., Schüth, F., 2007. Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angewandte Chemie International Edition, 46 (8): 1222-1244.
  • Ma, P.-C., Siddiqui, N.A., Marom, G., Kim, J.-K., 2010. Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Composites Part A: Applied Science and Manufacturing, 41 (10): 1345-1367.
  • Matuana, L.M., Park, C.B., Balatinecz, J.J., 1998. Cell morphology and property relationships of microcellular foamed pvc/wood‐fiber composites. Polymer Engineering & Science, 38 (11): 1862-1872.
  • Moniruzzaman, M., Winey, K.I., 2006. Polymer nanocomposites containing carbon nanotubes. Macromolecules, 39 (16): 5194-5205.
  • Ouyang, M., Chan, C.M., 1996. Electrical and mechanical properties of pre‐localized polypyrrole/poly (vinyl chloride) conductive composites. Polymer Engineering & Science, 36 (21): 2676-2682.
  • Pekdemir, M.E., Pekdemir, S., İnci, Ş., Kırbağ, S., Çiftci, M., 2021. Thermal, Magnetic Properties and Antimicrobial Effects of Magnetic Iron Oxide Nanoparticles Treated with Polygonum cognatum. Iranian Journal of Science and Technology, Transactions A: Science, 45 1579-1586.
  • Shafi, K.V., Ulman, A., Yan, X., Yang, N.-L., Estournes, C., White, H., Rafailovich, M., 2001. Sonochemical synthesis of functionalized amorphous iron oxide nanoparticles. Langmuir, 17 (16): 5093-5097.
  • Sun, S., Li, C., Zhang, L., Du, H., Burnell‐Gray, J., 2006. Interfacial structures and mechanical properties of PVC composites reinforced by CaCO3 with different particle sizes and surface treatments. Polymer international, 55 (2): 158-164.
  • Sun, S., Murray, C.B., Weller, D., Folks, L., Moser, A., 2000. Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science, 287 (5460): 1989-1992.
  • Tanaydın, M.K., 2021. Hidrometalurjik Yöntemlerle Nadir Toprak Elementlerinin Kazanılması. International Journal of Pure and Applied Sciences, 7 (2): 288-304.
  • Thostenson, E.T., Ren, Z., Chou, T.-W., 2001. Advances in the science and technology of carbon nanotubes and their composites: a review. Composites science and technology, 61 (13): 1899-1912.
  • TUKUR, A., PEKDEMİR, M.E., COŞKUN, M., 2020. Investigation of structural, thermal and dielectric properties of PVC/modified magnetic nanoparticle composites. Cumhuriyet Science Journal, 41 (2): 377-385.
  • Vadukumpully, S., Paul, J., Mahanta, N., Valiyaveettil, S., 2011. Flexible conductive graphene/poly (vinyl chloride) composite thin films with high mechanical strength and thermal stability. Carbon, 49 (1): 198-205.
  • Weissleder, R., Moore, A., Mahmood, U., Bhorade, R., Benveniste, H., Chiocca, E.A., Basilion, J.P., 2000. In vivo magnetic resonance imaging of transgene expression. Nature medicine, 6 (3): 351-354.
  • Wilson, J., Poddar, P., Frey, N., Srikanth, H., Mohomed, K., Harmon, J. ve Wachsmuth, J., 2004. Synthesis and magnetic properties of polymer nanocomposites with embedded iron nanoparticles. Journal of Applied Physics, 95 (3): 1439-1443. Yaacob, I.I., Nunes, A.C., Bose, A., 1995. Magnetic nanoparticles produced in spontaneous cationic-anionic vesicles: room temperature synthesis and characterization. Journal of colloid and interface science, 171 (1): 73-84.
  • Zhang, Y., Kohler, N., Zhang, M., 2002. Surface modification of superparamagnetic magnetite nanoparticles and their intracellular uptake. Biomaterials, 23 (7): 1553-1561.
There are 31 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Mustafa Ersin Pekdemir 0000-0002-4979-1777

Mehmet Fatih Coşkun 0000-0002-4322-7200

Demet Coşkun 0000-0001-7141-6909

Publication Date June 30, 2022
Submission Date September 11, 2021
Acceptance Date December 22, 2021
Published in Issue Year 2022 Volume: 8 Issue: 1

Cite

APA Pekdemir, M. E., Coşkun, M. F., & Coşkun, D. (2022). Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles. International Journal of Pure and Applied Sciences, 8(1), 24-30. https://doi.org/10.29132/ijpas.993988
AMA Pekdemir ME, Coşkun MF, Coşkun D. Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles. International Journal of Pure and Applied Sciences. June 2022;8(1):24-30. doi:10.29132/ijpas.993988
Chicago Pekdemir, Mustafa Ersin, Mehmet Fatih Coşkun, and Demet Coşkun. “Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles”. International Journal of Pure and Applied Sciences 8, no. 1 (June 2022): 24-30. https://doi.org/10.29132/ijpas.993988.
EndNote Pekdemir ME, Coşkun MF, Coşkun D (June 1, 2022) Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles. International Journal of Pure and Applied Sciences 8 1 24–30.
IEEE M. E. Pekdemir, M. F. Coşkun, and D. Coşkun, “Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles”, International Journal of Pure and Applied Sciences, vol. 8, no. 1, pp. 24–30, 2022, doi: 10.29132/ijpas.993988.
ISNAD Pekdemir, Mustafa Ersin et al. “Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles”. International Journal of Pure and Applied Sciences 8/1 (June 2022), 24-30. https://doi.org/10.29132/ijpas.993988.
JAMA Pekdemir ME, Coşkun MF, Coşkun D. Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles. International Journal of Pure and Applied Sciences. 2022;8:24–30.
MLA Pekdemir, Mustafa Ersin et al. “Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles”. International Journal of Pure and Applied Sciences, vol. 8, no. 1, 2022, pp. 24-30, doi:10.29132/ijpas.993988.
Vancouver Pekdemir ME, Coşkun MF, Coşkun D. Investigation of Magnetic Properties of Poly Vinyl Chloride Composites Prepared Using Different Ratios of Fe2O3 (Maghemite) Nanoparticles. International Journal of Pure and Applied Sciences. 2022;8(1):24-30.

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