Atık Maske Takviyeli Polyester Kompozit Üretimi ve Karakterizasyonu

Year 2022, , 41 - 49, 10.03.2022

Maruf Hurşit Demirel , Ercan Aydoğmuş

https://doi.org/10.33715/inonusaglik.1012426

Cited By: 10

Abstract

Bu araştırmada çevreyi kirleten atık maskeler (WM) polyester kompozit içerisinde değerlendirilmiştir. Elde edilen kompozitin bazı fiziksel ve kimyasal özellikleri karakterize edilmiştir. Özellikle yoğunluğu, Shore D sertliği, ısıl iletkenlik katsayısı, ısıl kararlılığı ve gözenekliliği karşılaştırılarak belirlenmiştir. Atık maskeleri toplanır, dezenfekte edilir, öğütülür, kurutulur ve dolgu maddesi olarak ağırlıkça % 0, % 2, % 5, % 7 ve % 10 oranlarında doymamış polyestere (UP) eklenir. Maske atıkları doymamış polyestere belirli oranlarda ilave edilerek 1000 rpm karıştırma hızında 10 dakika boyunca iyice homojenize edilir. Daha sonra metil etil keton peroksit (MEKP) ve kobalt oktoat (Co. Oc.) katalizörleri yardımıyla kimyasal reaksiyon gerçekleştirilmiştir. Üretilen polyester kompozitlerin kimyasal bağ yapısı Fourier dönüşümlü kızılötesi spektroskopisi (FTIR) ile belirlenir. Elde edilen sonuçlara göre kompozitlerdeki WM oranları arttıkça kompozitlerin hem yoğunluğu hem de Shore D sertliği azalmıştır. Artan WM oranı ile polyester kompozitin mekanik mukavemetinin ve gözenekliliğinin arttığı tespit edilmiştir. Polyester kompozitte kütlece WM'deki artış, termal iletkenlik katsayısını ve aktivasyon enerjisini arttırır.

Keywords

Aktivasyon enerjisi, Atık maske, Gözeneklilik, Polyester kompozit, Termal iletkenlik

Supporting Institution

Yok

Project Number

Yok

PRODUCTION AND CHARACTERIZATION OF WASTE MASK REINFORCED POLYESTER COMPOSITE

Abstract

In this research, waste masks (WM) that pollute the environment have been evaluated in the polyester composite. Some physical and chemical properties of the obtained composite have been characterized. In particular, its density, Shore D hardness, thermal conductivity, thermal stability, and porosity have been determined. Waste masks were collected, disinfect, ground, dried and added into unsaturated polyester (UP) at the rates of 0 %, 2 %, 5 %, 7 %, and 10 % by mass as a filler. Mask wastes were reinforced to the unsaturated polyester in certain proportions and were homogenized thoroughly for 10 minutes at a mixing speed of 1000 rpm. Then, the chemical reaction has been carried out with the help of methyl ethyl ketone peroxide (MEKP) and cobalt octoate (Co Oc) catalysts. The chemical bond structure of the produced polyester composites was determined by Fourier transform infrared spectrophotometer (FTIR). According to the results, both density and Shore D hardness of the composites decreased as the WM ratios in the composites increased. It has been evaluated that the mechanical strength of the polyester composite and porosity raises with increasing WM ratio. The increase in WM by mass in the polyester composite raises thermal conductivity and activation energy.

Keywords

Activation energy, Polyester composite, Porosity, Thermal conductivity, Waste mask

Project Number

Yok

References

• Abdullah, N. M., Ahmad, I. (2013). Potential of using polyester reinforced coconut fiber composites derived from recycling polyethylene terephthalate (PET) waste. Fibers and Polymers, 14(4), 584–590.
• Ahmad, T., Raza, S. S., Aleem, E., Kamran, M., Manzoor, U., Makhdoom, A., … Mukhtar, S. (2017). Improvement in mechanical and thermal properties of unsaturated polyester-based hybrid composites. Iranian Polymer Journal (English Edition), 26(4), 305–311.
• Aksoy, B., Paşahan, A., Güngör, Ö., Köytepe, S., Seçkin, T. (2017). A novel electrochemical biosensor based on polyimide-boron nitride composite membranes. International Journal of Polymeric Materials and Polymeric Biomaterials, 66(4), 203–212.
• Aragaw, T. A. (2020). Surgical face masks as a potential source for microplastic pollution in the COVID-19 scenario. Marine Pollution Bulletin, 159(June), 111517.
• Asim, N., Badiei, M., Sopian, K. (2021). Review of the valorization options for the proper disposal of face masks during the COVID-19 pandemic. Environmental Technology and Innovation, 23, 101797.
• Aydoğmuş, E., Arslanoğlu, H. (2021). Kinetics of thermal decomposition of the polyester nanocomposites. Petroleum Science and Technology, 39(13–14), 484–500.
• Aydoğmuş, E., Dağ, M. (2021). Characterization of Thermophysical of Biomass Reinforced Polyester Composite, 1st International Conference of Physics, Ankara.
• Aydoğmuş, E., Demirel, M. H. (2021). Waste Tire Rubber Reinforced Polyester Composite Production and Characterization, 8th International Conference on Materials Science and Nanotechnology for Next Generation, Elazığ.
• Aydoğmuş, E., Arslanoğlu, H., Dağ, M. (2021). Production of waste polyethylene terephthalate reinforced biocomposite with RSM design and evaluation of thermophysical properties by ANN. Journal of Building Engineering, 44(September), 103337.
• Battegazzore, D., Cravero, F., Frache, A. (2020). Is it possible to mechanical recycle the materials of the disposable filtering masks? Polymers, 12(11), 1–18.
• Crespo, C., Ibarz, G., Sáenz, C., Gonzalez, P., Roche, S. (2021). Study of Recycling Potential of FFP2 Face Masks and Characterization of the Plastic Mix-Material Obtained. A Way of Reducing Waste in Times of Covid-19. Waste and Biomass Valorization, 0123456789.
• Erzen, B., Aydoğmuş, E. (2021). Pumice Stone Reinforced Polyester Composite Production and Characterization, International Pumice and Perlite Symposium (PuPeS’21), Bitlis.
• Güngör, Ö., Paşahan, A., Aksoy, B., Köytepe, S., Seçkin, T. (2020). Voltammetric analysis of melatonin and dopamine by using graphene oxide/polyimide based biosensor. Journal of Inonu University Health Services Vocational School, 8(2), 367-382.
• Joseph, B., James, J., Kalarikkal, N., Thomas, S. (2021). Recycling of medical plastics. Advanced Industrial and Engineering Polymer Research, 4(3), 199–208.
• Meira Castro, A. C., Ribeiro, M. C. S., Santos, J., Meixedo, J. P., Silva, F. J. G., Fiúza, A., … Alvim, M. R. (2013). Sustainable waste recycling solution for the glass fibre reinforced polymer composite materials industry. Construction and Building Materials, 45, 87–94.
• Mellin, P., Jönsson, C., Åkermo, M., Fernberg, P., Nordenberg, E., Brodin, H., Strondl, A. (2016). Nano-sized by-products from metal 3D printing, composite manufacturing and fabric production. Journal of Cleaner Production, 139, 1224–1233.
• Mohan, H. T., Jayanarayanan, K., Mini, K. M. (2021). A sustainable approach for the utilization of PPE biomedical waste in the construction sector. Engineering Science and Technology, an International Journal, 1-9.
• Morganti, P., Yudin, V. E., Morganti, G., Coltelli, M. B. (2020). Trends in surgical and beauty masks for a cleaner environment. Cosmetics, 7, 68.
• Mosadeghzada, Z., Ahmada, I., Daika, R., Ramli, A., Jalaludin, Z. (2009). Preparation and properties of acacia sawdust/UPR composite based on recycled PET. Malaysian Polymer Journal, 4(1), 30–41.
• Nuzaimah, M., Sapuan, S. M., Nadlene, R., Jawaid, M. (2019). Microstructure and mechanical properties of unsaturated polyester composites filled with waste rubber glove crumbs. Fibers and Polymers, 20(6), 1290–1300.
• Orhan, R., Aydoğmuş, E., Topuz, S., Arslanoğlu, H. (2021). Investigation of thermo-mechanical characteristics of borax reinforced polyester composites. Journal of Building Engineering, 42(July), 103051. Paşahan, A. (2012). Sensor Applications of Polyimides. In High Performance Polymers - Polyimides Based - From Chemistry to Applications. InTech.
• Paşahan, A., Köytepe, S., Ekinci, E. (2011). Synthesis, characterization of a new organosoluble polyimide and its application in development of glucose biosensor. Polymer - Plastics Technology and Engineering, 50(12), 1239–1246. Reygrobellet, J. N., Cuesta, J. M. L., Crespy, A. (1999). Incorporation of Unsaturated Polyester Based Matrix Composites Into A PP-PE Copolymer for Recycling. Laboratoire Matrices, 1–7.
• Savan, E. K., Paşahan, A., Aksoy, B., Güngör, Ö., Köytepe, S., Seçkin, T. (2016). Preparation and properties of selective polyurethane films and their use for the development of biomedical dopamine sensor. International Journal of Polymeric Materials and Polymeric Biomaterials, 65(8), 402–408.
• Titretir Duran, S., Paşahan, A., Ayhan, N., Güngör, Ö., Cengiz, M. A., Köytepe, S. (2017). Synthesis, characterization of guar-containing polyurethane films and their non-enzymatic caffeic acid sensor applications. Polymer - Plastics Technology and Engineering, 56(16), 1741–1751.
• Xiang, M., Yang, Z., Zhou, S., Lu, T., Zhang, S., Sun, L., Dong, S. (2021). Polymer composites completely derived from waste: the crystalline structure and the mechanical enhancement effect. ACS Applied Polymer Materials, 3(7), 3679–3684. Yanen, C., Aydoğmuş, E. (2021). Characterization of thermo-physical properties of nanoparticle reinforced the polyester nanocomposite, Dicle University Journal of the Institute of Natural and Applied Science, 10(2), 121–132.
• Yıldız, S., Karaağaç, B., Güzeliş, S. G. (2021). Utilization of glass fiber reinforced polymer wastes. Polymer Composites, 42(1), 412–423.