TEKSTİL ATIKSUYUNDAN ASTRAZON BLACK BOYASININ GİDERİMİ: TAGUCHİ METODU İLE MODELLEME

Abstract

Bu çalışmada, adsorbent olarak kullanılan bahçe toprağı ile sentetik olarak hazırlanan Astrazon Black MBL (AB) boyası giderimi araştırılmıştır. Araştırmada sentetik boya çözeltisinde hem renk hem de organik madde içeriğinin giderimi, adsorpsiyon ve Fenton prosesleri ile farklı işletme şartları altında çalışılmıştır. Arıtma sonrası numunelerde oksidasyon-redüksiyon potansiyeli (ORP) ve FTIR analizleri gerçekleştirilmiştir. Fenton prosesinde oluşan çamur miktarı ölçülmüş, her iki sistem için renk giderimi, KOİ giderimi ve ORP değişimi istatistiksel analiz edilerek modeller önerilmiştir. Adsorpsiyon çalışmasında renk ve KOİ giderimi için işletme parametrelerinin farklı etkisi ve elde edilen optimum değerler farklı olmuştur. Fenton çalışmasında ise Fe+2 ve H2O2 miktarı hem renk hem de KOİ giderimine aynı etkiye sahip olmuştur. Aynı optimum değerler elde edilmiş ve her iki sistem ile optimum şartlarda rengin tamamı giderilebilmiştir. Her iki sistemde de KOİ giderimi %86’nın üzerinde gerçekleşmiştir. Kullanılan toprak ile yüksek oranlarda renk giderilebileceği ve organik maddelerin yüzeyde tutunabileceği sonucuna varılmıştır.

Keywords

• Adsorpsiyon
• Fenton
• Toprak
• Tekstil Atıksuyu
• Taguchi Metodu

REMOVAL OF ASTRAZON BLACK DYE FROM TEXTILE WASTEWATER: MODELLING BY TAGUCHI METHOD

Abstract

In this study, both color and organic matter removal in Astrazon Black MBL (AB) dye wastewater were studied under different operation conditions by adsorption and Fenton processes. Moreover, oxidation-reduction potential (ORP) and FTIR analysis were performed on the samples after treatment. The amount of sludge generated in the Fenton process was measured. Color removal, chemical oxygen demand (COD) removal and ORP change for both systems were statistically analyzed and models were proposed using Taguchi method. As a result of the study, effects of operation parameters and optimum values obtained for color and COD removals in the adsorption study were different. In the Fenton study, the amount of Fe+2 and H2O2 had the same effect on both color and COD removals, and the same optimum values were obtained. With both systems, the color could completely be removed under optimum conditions. COD removal determined also over 86% for both systems. If the removal of both parameters is to be considered, the operation conditions of the process should be determined according to COD removal, since color removal is much easier than mineralization. The soil used as an adsorbent has shown that high levels of color and organic matters may be adsorbed.

Keywords

• Adsorption
• Fenton
• Soil
• Textile Wastewater
• Taguchi Method

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