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Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique

Year 2019, , 1377 - 1384, 01.09.2019
https://doi.org/10.21597/jist.513363

Abstract

In this study, two gold/palladium (Au/Pd) thin films having 20 nm and 80 nm thickness values were simultaneously deposited on glass substrates by adjusting target-substrate distance via radio frequency (RF) magnetron sputtering technique. The optical and surface properties of the produced thin films were investigated by using UV-VIS spectrophotometer, interferometer, tensiometer and atomic force microscope. The effects of film thickness on the investigated properties of the thin films were reported.

References

  • Bonet F, Delmas V, Grugeon S, Urbina RH, Silvert P, and Tekaia-Elhsissen, K, 1999. Synthesis of Monodisperse Au, Pt, Pd, Ru and Ir Nanoparticles in Ethylene Glycol. Nanostructured Materials, 11 (8): 1277-1284.
  • Chowdhury R, Mollick MMR, Biswas Y, Chattopadhyay D, and Rashid MH, 2018. Biogenic Synthesis of Shape-Tunable Au-Pd Alloy Nanoparticles with Enhanced Catalytic Activities. Journal of Alloys and Compounds, 763: 399-408.
  • Cybula A, Priebe JB, Pohl MM, Sobczak JW, Schneider M, Zielińska-Jurek A, Zaleska A, 2014. The Effect of Calcination Temperature on Structure and Photocatalytic Properties of Au/Pd Nanoparticles Supported On TiO2. Applied Catalysis B: Environmental, 152: 202-211.
  • de Yuso AM, Maetz A, Oumellal Y, Zlotea C, Le Meins JM and Ghimbeu CM, 2017. Optimization of The Synthesis of Pd-Au Nanoalloys Confined in Mesoporous Carbonaceous Materials. Journal of Colloid And Interface Science, 505: 410-420.
  • DeSantis CJ, and Skrabalak SE, 2012. Size-Controlled Synthesis of Au/Pd Octopods With High Refractive Index Sensitivity. Langmuir, 28(24): 9055-9062.
  • Fedrigo S, Harbich W and Buttet J, 1993. Collective Dipole Oscillations in Small Silver Clusters Embedded in Rare-Gas Matrices. Physical Review B, 47(16): 10706.
  • Ferrer D, Torres-Castro A, Gao X, Sepulveda-Guzman S, Ortiz-Mendez U, and Jose-Yacaman M, 2007. Three-Layer Core/Shell Structure In Au-Pd Bimetallic Nanoparticles. Nano Letters, 7(6): 1701-1705.
  • Henglein A, 2000. Colloidal Palladium Nanoparticles: Reduction of Pd (II) By H2; Pdcoreaushellagshell Particles. The Journal of Physical Chemistry B, 104(29): 6683-6685.
  • Hodak JH, Henglein A, Giersig M, and Hartland GV, 2000. Laser-Induced Inter-Diffusion in Auag Core-Shell Nanoparticles. The Journal of Physical Chemistry B, 104(49): 11708-11718.
  • Hodak JH, Henglein A and Hartland GV, 2000. Coherent Excitation of Acoustic Breathing Modes in Bimetallic Core-Shell Nanoparticles. The Journal of Physical Chemistry B, 104(21): 5053-5055.
  • Jerman I, Koželj M and Orel B, 2010. The Effect of Polyhedral Oligomeric Silsesquioxane Dispersant and Low Surface Energy Additives on Spectrally Selective Paint Coatings With Self-Cleaning Properties. Solar Energy Materials and Solar Cells, 94(2): 232-245.
  • Kan C, Cai W, Li C, Zhang L and Hofmeister H, 2003. Ultrasonic Synthesis And Optical Properties Of Au/Pd Bimetallic Nanoparticles In Ethylene Glycol. Journal of Physics D: Applied Physics, 36(13): 1609.
  • Kreibig U and Vollmer M (1995). Theoretical Considerations Optical Properties of Metal Clusters, pp. 13-201, Springer.
  • Li C, Cai W, Kan C, and Fu G, 2004. Synthesis and Optical Characterization Of Pd–Au Bimetallic Nanoparticles Dispersed Within Monolithic Mesoporous Silica. Scripta Materialia, 50(12): 1481-1486.
  • Mallikarjuna K, Bathula C, Reddy GD, Shrestha NK, Kim H And Noh YY, 2019. Au-Pd Bimetallic Nanoparticles Embedded Highly Porous Fenugreek Polysaccharide Based Micro Networks For Catalytic Applications. International Journal Of Biological Macromolecules, 126: 352-358.
  • Maye MM, Zheng W, Leibowitz FL, Ly NK and Zhong CJ, 2000. Heating-Induced Evolution of Thiolate-Encapsulated Gold Nanoparticles: A Strategy For Size and Shape Manipulations. Langmuir, 16(2): 490-497.
  • Mizukoshi Y, Fujimoto T, Nagata Y, Oshima R and Maeda Y, 2000. Characterization and Catalytic Activity of Core-Shell Structured Gold/Palladium Bimetallic Nanoparticles Synthesized by the Sonochemical Method. The Journal of Physical Chemistry B, 104(25): 6028-6032.
  • Nazarpour S, Cirera A and Varela M, 2010. Material properties of Au–Pd thin alloy films. Thin Solid Films, 518(20): 5715-5719.
  • Palpant B, Prével B, Lermé J, Cottancin E, Pellarin M, Treilleux M, Perez A, Vialle JL and Broyer M, 1998. Optical Properties of Gold Clusters in the Size Range 2–4 Nm. Physical Review B, 57(3): 1963.
  • Parajuli P, Mendoza-Cruz R, Velazquez-Salazar JJ, Yacaman MJ and Ponce A, 2019. Fivefold Annealing Twin in Nanocrystalline Au/Pd Film. Materials Letters, 244: 88-91.
  • Shao Gf, Tu Nn, Liu Td, Xu Ly, And Wen Yh, 2015. Structural Studies of Au–Pd Bimetallic Nanoparticles by a Genetic Algorithm Method. Physica E: Low-Dimensional Systems And Nanostructures, 70: 11-20.
  • Shishin B, Lee KR, Moon MW And Kim HY, 2012. Extreme Water Repellency of Nanostructured Low-Surface-Energy Non-Woven Fabrics. Soft Matter, 8(6): 1817-1823.
  • Smith AF, Harvey SM, Skrabalak SE and Weiner RG, 2016. Engineering High Refractive Index Sensitivity Through the Internal and External Composition of Bimetallic Nanocrystals. Nanoscale, 8(38): 16841-16845.
  • Szabo D and Vollath D, 1999. Nonocomposites from coated nanoparticles. Advanced Materials, 11(15): 1313-1316.
  • Toshima N, Harada M, Yamazaki Y and Asakura K, 1992. Catalytic Activity and Structural Analysis of Polymer-Protected Gold-Palladium Bimetallic Clusters Prepared by the Simultaneous Reduction of Hydrogen Tetrachloroaurate and Palladium Dichloride. The Journal of Physical Chemistry, 96(24): 9927-9933.
  • Toshima N and Yonezawa T, 1998. Bimetallic Nanoparticles-Novel Materials For Chemical and Physical Applications. New Journal of Chemistry, 22(11): 1179-1201.
  • Wu ML, Chen DH and Huang TC, 2001. Synthesis Of Au/Pd Bimetallic Nanoparticles In Reverse Micelles. Langmuir, 17(13): 3877-3883.
  • Xin Z, Xiao-Hui S and Dian-Lin Z, 2010. Thickness dependence of grain size and surface roughness for dc magnetron sputtered Au films. Chinese Physics B, 19(8): 086802.
  • Yi CW, Luo K, Wei T and Goodman D, 2005. The Composition and Structure Of Pd- Au Surfaces. The Journal of Physical Chemistry B, 109(39): 18535-18540.
  • Zhang QX and Yin LB, 2012. Electrochemical Performance f Heterostructured Au-Pd Bimetallic Nanoparticles Toward As (III) Aqueous Media. Electrochemistry Communications, 22: 57-60.

Radyo Frekans Magnetron Sıçratma Tekniği ile Altın/Paladyum (Au/Pd) Bimetalik İnce Film Biriktirme

Year 2019, , 1377 - 1384, 01.09.2019
https://doi.org/10.21597/jist.513363

Abstract

Bu çalışmada, 20 nm ve 80 nm kalınlığa sahip iki adet altın/paladyum (Au/Pd) ince film, eş zamanlı olarak radyo frekans (RF) magnetron sıçratma tekniği ile hedef-alttaş mesafesinin ayarlanmasıyla cam alttaşlar üzerinde biriktirilmiştir. Üretilen ince filmlerin optik ve yüzey özellikleri UV-VIS spektrofotometre, interferometre, tansiyometre ve atomik kuvvet mikroskobu kullanılarak incelenmiştir. Film kalınlığının, ince filmlerin incelenen özellikleri üzerindeki etkileri rapor edilmektedir.

References

  • Bonet F, Delmas V, Grugeon S, Urbina RH, Silvert P, and Tekaia-Elhsissen, K, 1999. Synthesis of Monodisperse Au, Pt, Pd, Ru and Ir Nanoparticles in Ethylene Glycol. Nanostructured Materials, 11 (8): 1277-1284.
  • Chowdhury R, Mollick MMR, Biswas Y, Chattopadhyay D, and Rashid MH, 2018. Biogenic Synthesis of Shape-Tunable Au-Pd Alloy Nanoparticles with Enhanced Catalytic Activities. Journal of Alloys and Compounds, 763: 399-408.
  • Cybula A, Priebe JB, Pohl MM, Sobczak JW, Schneider M, Zielińska-Jurek A, Zaleska A, 2014. The Effect of Calcination Temperature on Structure and Photocatalytic Properties of Au/Pd Nanoparticles Supported On TiO2. Applied Catalysis B: Environmental, 152: 202-211.
  • de Yuso AM, Maetz A, Oumellal Y, Zlotea C, Le Meins JM and Ghimbeu CM, 2017. Optimization of The Synthesis of Pd-Au Nanoalloys Confined in Mesoporous Carbonaceous Materials. Journal of Colloid And Interface Science, 505: 410-420.
  • DeSantis CJ, and Skrabalak SE, 2012. Size-Controlled Synthesis of Au/Pd Octopods With High Refractive Index Sensitivity. Langmuir, 28(24): 9055-9062.
  • Fedrigo S, Harbich W and Buttet J, 1993. Collective Dipole Oscillations in Small Silver Clusters Embedded in Rare-Gas Matrices. Physical Review B, 47(16): 10706.
  • Ferrer D, Torres-Castro A, Gao X, Sepulveda-Guzman S, Ortiz-Mendez U, and Jose-Yacaman M, 2007. Three-Layer Core/Shell Structure In Au-Pd Bimetallic Nanoparticles. Nano Letters, 7(6): 1701-1705.
  • Henglein A, 2000. Colloidal Palladium Nanoparticles: Reduction of Pd (II) By H2; Pdcoreaushellagshell Particles. The Journal of Physical Chemistry B, 104(29): 6683-6685.
  • Hodak JH, Henglein A, Giersig M, and Hartland GV, 2000. Laser-Induced Inter-Diffusion in Auag Core-Shell Nanoparticles. The Journal of Physical Chemistry B, 104(49): 11708-11718.
  • Hodak JH, Henglein A and Hartland GV, 2000. Coherent Excitation of Acoustic Breathing Modes in Bimetallic Core-Shell Nanoparticles. The Journal of Physical Chemistry B, 104(21): 5053-5055.
  • Jerman I, Koželj M and Orel B, 2010. The Effect of Polyhedral Oligomeric Silsesquioxane Dispersant and Low Surface Energy Additives on Spectrally Selective Paint Coatings With Self-Cleaning Properties. Solar Energy Materials and Solar Cells, 94(2): 232-245.
  • Kan C, Cai W, Li C, Zhang L and Hofmeister H, 2003. Ultrasonic Synthesis And Optical Properties Of Au/Pd Bimetallic Nanoparticles In Ethylene Glycol. Journal of Physics D: Applied Physics, 36(13): 1609.
  • Kreibig U and Vollmer M (1995). Theoretical Considerations Optical Properties of Metal Clusters, pp. 13-201, Springer.
  • Li C, Cai W, Kan C, and Fu G, 2004. Synthesis and Optical Characterization Of Pd–Au Bimetallic Nanoparticles Dispersed Within Monolithic Mesoporous Silica. Scripta Materialia, 50(12): 1481-1486.
  • Mallikarjuna K, Bathula C, Reddy GD, Shrestha NK, Kim H And Noh YY, 2019. Au-Pd Bimetallic Nanoparticles Embedded Highly Porous Fenugreek Polysaccharide Based Micro Networks For Catalytic Applications. International Journal Of Biological Macromolecules, 126: 352-358.
  • Maye MM, Zheng W, Leibowitz FL, Ly NK and Zhong CJ, 2000. Heating-Induced Evolution of Thiolate-Encapsulated Gold Nanoparticles: A Strategy For Size and Shape Manipulations. Langmuir, 16(2): 490-497.
  • Mizukoshi Y, Fujimoto T, Nagata Y, Oshima R and Maeda Y, 2000. Characterization and Catalytic Activity of Core-Shell Structured Gold/Palladium Bimetallic Nanoparticles Synthesized by the Sonochemical Method. The Journal of Physical Chemistry B, 104(25): 6028-6032.
  • Nazarpour S, Cirera A and Varela M, 2010. Material properties of Au–Pd thin alloy films. Thin Solid Films, 518(20): 5715-5719.
  • Palpant B, Prével B, Lermé J, Cottancin E, Pellarin M, Treilleux M, Perez A, Vialle JL and Broyer M, 1998. Optical Properties of Gold Clusters in the Size Range 2–4 Nm. Physical Review B, 57(3): 1963.
  • Parajuli P, Mendoza-Cruz R, Velazquez-Salazar JJ, Yacaman MJ and Ponce A, 2019. Fivefold Annealing Twin in Nanocrystalline Au/Pd Film. Materials Letters, 244: 88-91.
  • Shao Gf, Tu Nn, Liu Td, Xu Ly, And Wen Yh, 2015. Structural Studies of Au–Pd Bimetallic Nanoparticles by a Genetic Algorithm Method. Physica E: Low-Dimensional Systems And Nanostructures, 70: 11-20.
  • Shishin B, Lee KR, Moon MW And Kim HY, 2012. Extreme Water Repellency of Nanostructured Low-Surface-Energy Non-Woven Fabrics. Soft Matter, 8(6): 1817-1823.
  • Smith AF, Harvey SM, Skrabalak SE and Weiner RG, 2016. Engineering High Refractive Index Sensitivity Through the Internal and External Composition of Bimetallic Nanocrystals. Nanoscale, 8(38): 16841-16845.
  • Szabo D and Vollath D, 1999. Nonocomposites from coated nanoparticles. Advanced Materials, 11(15): 1313-1316.
  • Toshima N, Harada M, Yamazaki Y and Asakura K, 1992. Catalytic Activity and Structural Analysis of Polymer-Protected Gold-Palladium Bimetallic Clusters Prepared by the Simultaneous Reduction of Hydrogen Tetrachloroaurate and Palladium Dichloride. The Journal of Physical Chemistry, 96(24): 9927-9933.
  • Toshima N and Yonezawa T, 1998. Bimetallic Nanoparticles-Novel Materials For Chemical and Physical Applications. New Journal of Chemistry, 22(11): 1179-1201.
  • Wu ML, Chen DH and Huang TC, 2001. Synthesis Of Au/Pd Bimetallic Nanoparticles In Reverse Micelles. Langmuir, 17(13): 3877-3883.
  • Xin Z, Xiao-Hui S and Dian-Lin Z, 2010. Thickness dependence of grain size and surface roughness for dc magnetron sputtered Au films. Chinese Physics B, 19(8): 086802.
  • Yi CW, Luo K, Wei T and Goodman D, 2005. The Composition and Structure Of Pd- Au Surfaces. The Journal of Physical Chemistry B, 109(39): 18535-18540.
  • Zhang QX and Yin LB, 2012. Electrochemical Performance f Heterostructured Au-Pd Bimetallic Nanoparticles Toward As (III) Aqueous Media. Electrochemistry Communications, 22: 57-60.
There are 30 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Fizik / Physics
Authors

Volkan Şenay 0000-0002-6579-2737

Publication Date September 1, 2019
Submission Date January 16, 2019
Acceptance Date April 10, 2019
Published in Issue Year 2019

Cite

APA Şenay, V. (2019). Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique. Journal of the Institute of Science and Technology, 9(3), 1377-1384. https://doi.org/10.21597/jist.513363
AMA Şenay V. Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique. Iğdır Üniv. Fen Bil Enst. Der. September 2019;9(3):1377-1384. doi:10.21597/jist.513363
Chicago Şenay, Volkan. “Gold/Palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique”. Journal of the Institute of Science and Technology 9, no. 3 (September 2019): 1377-84. https://doi.org/10.21597/jist.513363.
EndNote Şenay V (September 1, 2019) Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique. Journal of the Institute of Science and Technology 9 3 1377–1384.
IEEE V. Şenay, “Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique”, Iğdır Üniv. Fen Bil Enst. Der., vol. 9, no. 3, pp. 1377–1384, 2019, doi: 10.21597/jist.513363.
ISNAD Şenay, Volkan. “Gold/Palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique”. Journal of the Institute of Science and Technology 9/3 (September 2019), 1377-1384. https://doi.org/10.21597/jist.513363.
JAMA Şenay V. Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique. Iğdır Üniv. Fen Bil Enst. Der. 2019;9:1377–1384.
MLA Şenay, Volkan. “Gold/Palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique”. Journal of the Institute of Science and Technology, vol. 9, no. 3, 2019, pp. 1377-84, doi:10.21597/jist.513363.
Vancouver Şenay V. Gold/palladium (Au/Pd) Bimetallic Thin Film Deposition by Radio Frequency Magnetron Sputtering Technique. Iğdır Üniv. Fen Bil Enst. Der. 2019;9(3):1377-84.