TiO2 Nanopartikülü İle Fonksiyonelleştirilmiş Çok Duvarlı Karbon Nanotüpün Su Bazlı Sondaj Çamuruna Etkisinin Belirlenmesi: Deneysel Çalışma

Abstract

Bu çalışmada, su bazlı sondaj çamuruna (Na-Bentonit bazlı) fonksiyonelleştirilmiş karbon nanotüpün etkisinin tespiti amaçlanmıştır. Bu kapsamda su bazlı sondaj çamurları hazırlanmış ve kimyasal buhar biriktirme (CVD) yöntemi ile üretilen TiO2 nanopartikülü ile fonksiyonelleştirilmiş çok duvarlı karbon nanotüp (TiO2NP/ÇDKNT) farklı oranlarda (0.001 – 0.01 % k/h) eklenmiştir. Hazırlanan sondaj çamurlarının plastik viskozitesi (PV), görünür viskozitesi (AV), kopma noktası (YP), jel mukavemeti değerleri (10 saniye ve 10 dakika) gibi reolojik özellikleri FANN viskozimetresi ile ayrıca su (filtrasyon) kaybı ve sondaj çamuru kek kalınlığı Amerikan Petrol Enstitüsü (API) sıvı kaybı test ekipmanları ile API standartlarına uygun olacak şekilde detaylı analiz edilmiştir. TiO2NP/ÇDKNT’ün eklenmesi ile hazırlanan sondaj çamurlarının reolojik ve filtrasyon özellikleri kendi içlerinde, daha sonra da katkısız sondaj çamuru ile karşılaştırılmıştır. Elde edilen sonuçlara göre; TiO2NP/ÇDKNT’ün su bazlı sondaj çamuruna eklenmesiyle; PV değerinin % 71.4; AV değerinin % 41.8; YP değerinin % 28; 10 saniye değerinin % 8.3; 10 dakika değerinin % 5.6 arttığı; filtrasyon kaybının % 8.6 azaldığı; aynı zamanda da kek kalınlığı değerinin de % 11 oranında arttığı görülmüştür. Yapılan bu çalışmayla; TiO2NP/ÇDKNT’ün sondaj çamurunun reolojik özellikleri ile filtrasyon kaybı değerlerine olumlu yönde katkı sağladığı tespit edilmiştir.

Keywords

• Su bazlı sondaj çamuru,nanopartikül madde,fonksiyonelleştirilmiş çok katmanlı karbon nanotüp,kimyasal buhar biriktirme yöntemi

Effect of TiO2 Nanoparticle Functionalized Multi-Walled Carbon Nanotubes on the Water Based Drilling Fluid: Experimental Study

Abstract

In this study, it is aimed to determine the effect of functionalized carbon nanotube on water-based drilling mud (Na-Bentonite based). In this context, water based drilling muds were prepared and multi-walled carbon nanotube (TiO2NP/MWCNTs) functionalized with TiO2 nanoparticle produced by chemical vapor deposition (CVD) method was added in different ratios (0.001 - 0.01% w/v). The rheological properties of the prepared drilling muds such as plastic viscosity (PV), apparent viscosity (AV), yield point (YP), gel strength values (10 seconds and 10 minutes) were determined with a FANN viscometer, as well as water (filtration) loss and drilling mud cake thickness have been analyzed using American Petroleum Institute liquid loss test equipment accordance API standards in detail. The rheological and filtration properties of the drilling muds prepared by adding TiO2NP/MWCNTs were compared with each other and then with pure drilling mud. According to the results obtained; 71.4% of PV, 41.8% of AV value, 28% of the YP value, 8.3% of 10 seconds, 5.6% of 10 minutes increased and 8.6% of the loss of filtration decreased by adding TiO2NP/MWCNTs to water based drilling mud. At the same time, cake thickness value increased by 11%. With this study; it was found that TiO2NP/MWCNTs contributed positively to the rheological properties and filtration loss values of the drilling mud.

Keywords

• Water based drilling mud,nanoparticle substance,functionalized multi-walled carbon nanotube,chemical vapor deposition method

References

1. Abbasi S, Zebarjad SM, Baghban SHN, Youssefi A, Ekrami-Kakhki MS, 2016. Experimental investigation of the rheological behavior and viscosity of decorated multi-walled carbon nanotubes with TiO2 nanoparticles/water nanofluids. Journal of Thermal Analysis and Calorimetry, 123(1), 81-89.API 13B-1, 2009.
2. Aftab A, Ismail AR, Khokhar S, Ibupoto ZH. 2016. Novel zinc oxide nanoparticles deposited acrylamide composite used for enhancing the performance of water-based drilling fluids at elevated temperature conditions. Journal of Petroleum Science and Engineering, 146, 1142-1157.
3. API RP 13B-1, 2009. Recommended Practice for Field Testing Water-based Drilling Fluids. 4th Edition: API.
4. Asker NH, Özkan V, Özkan A. Su Bazlı Sondaj Çamurunun Reolojik ve Filtrasyon Özelliklerine ZnO Nanopartikülü ile Fonksiyonelleştirilmiş Çok Duvarlı Karbon Nanotüpün Etkisinin Araştırılması. Euro Asia 5th. International Congress on Applied Sciences,15-17 Novamber, 2019, p139-147, Adana, Turkey.
5. Bayat AE, Shams R. 2019. Appraising the impacts of SiO2, ZnO and TiO2 nanoparticles on rheological properties and shale inhibition of water-based drilling muds. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 581, 123792.
6. Bég OA, Espinoza DS, Kadir A, Shamshuddin MD, Sohail A, 2018. Experimental study of improved rheology and lubricity of drilling fluids enhanced with nano-particles. Applied Nanoscience, 8(5), 1069-1090.
7. Bicerano J, 2009. U.S. Patent Application No. 12/178, 785.
8. Bybee K, 2001. Water-Based Drilling-Fluid Systems for Deepwater Norway. Journal of Petroleum Technology, 53(11), 36-36.

9. Cueto LF, Hirata GA, Sánchez EM. 2006. Thin-film TiO2 electrode surface characterization upon CO2 reduction processes. Journal of Sol-Gel Science and Technology, 37(2), 105-109.
10. Dahman Y, 2017. Nanotechnology and Functional Materials for Engineers. Elsevier.
11. Elward-Berry J, Thomas EW, 1994, January. Rheologically Stable Deepwater Drilling Fluid Development and Application. In SPE/IADC Drilling Conference. Society of Petroleum Engineers.
12. Ersoy A, 2008. Sondaj Teknikleri ve Uygulamaları. Nobel Kitabevi, Adana.
13. Evdokimov IN, Eliseev NY, Losev AP, Novikov MA, 2006, January. Emerging petroleum-oriented nanotechnologies for reservoir engineering. In SPE Russian Oil and Gas Technical Conference and Exhibition. Society of Petroleum Engineers.
14. Fakoya MF, Shah SN, 2017. Emergence of nanotechnology in the oil and gas industry: Emphasis on the application of silica nanoparticles. Petroleum, 3(4), 391-405.
15. Gel Strength Definition, 2007. Retrieved on December 18, 2011 from Oil & Gas Field Technical Terms Glossary: http://oilgasglossary.com/gel-strength.html
16. In JB, Cho KR, Tran TX, Kim SM, Wang Y, Grigoropoulos CP, ... Fornasiero F, 2018. Effect of Enhanced Thermal Stability of Alumina Support Layer on Growth of Vertically Aligned Single-Walled Carbon Nanotubes and Their Application in Nanofiltration Membranes. Nanoscale research letters, 13(1), 173.
17. Ismail AR, Aftab A, Ibupoto ZH, Zolkifile N. 2016. The novel approach for the enhancement of rheological properties of water-based drilling fluids by using multi-walled carbon nanotube, nanosilica and glass beads. Journal of Petroleum Science and Engineering, 139, 264-275.
18. Javeri SM, Haindade ZMW, Jere CB, 2011, January. Mitigating loss circulation and differential sticking problems using silicon nanoparticles. In SPE/IADC Middle East Drilling Technology Conference and Exhibition. Society of Petroleum Engineers.
19. Kang Y, She J, Zhang H, You L, Song M, 2016. Strengthening shale wellbore with silica nanoparticles drilling fluid. Petroleum, 2(2), 189-195.
20. Kazemi-Beydokhti A, Hajiabadi SH, 2018. Rheological investigation of smart polymer/carbon nanotube complex on properties of water-based drilling fluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 556, 23-29.
21. Mao H, Qiu Z, Shen Z, Huang W, 2015a. Hydrophobic associated polymer based silica nanoparticles composite with core–shell structure as a filtrate reducer for drilling fluid at utra-high temperature. Journal of Petroleum Science and Engineering, 129, 1-14.
22. Mao H, Qiu Z, Shen Z, Huang W, Zhong H, Dai W, 2015b. Novel hydrophobic associated polymer based nano-silica composite with core–shell structure for intelligent drilling fluid under ultra-high temperature and ultra-high pressure. Progress in Natural Science: Materials International, 25(1), 90-93.
23. Mohideen AAM, Saheed MSM, Mohamed NM. 2019. Multiwalled carbon nanotubes and graphene oxide as nano-additives in water-based drilling fluid for enhanced fluid-loss-control & gel strength”. In AIP Conference Proceedings, Vol. 2151, No. 1, p. 020001. AIP Publishing.
24. Moulder JF, Stickle WF, Sobol PE, Bomben KD. 1992. Handbook of X-ray Photoelectron Spectroscopy. Chastain, J. Perkin-Elmer Corp., Eden Prairie, MN.
25. Özkan A, 2018, Effect of Multi-Walled Carbon Nanotubes on the Water-Based Drilling Muds. Mus Alparslan University Journal of Science, 6(2), 591-594.
26. Özkan A, Kaplan B.M, 2019. Investigation of the Effects on Rheological and Filtration Properties of Water-Based Drilling Mud of Boron Minerals: An Experimental Study. Pamukkale University Journal of Engineering Sciences. DOI: 10.5505/pajes.2019.89990.
27. Özkan A, Kaplan BM, Özkan V, Turan S.E, 2018b. Effect of Micro-Sized Colemanite on the Rheological Properties of the Water Based Drilling Fluid. Çukurova University Journal of the Faculty of Engineering and Architecture, 33(4), 83-88.
28. Özkan A, Özkan V, 2019. Effect of Clinoptilolite-Rich Zeolite on the Properties of Water Based Drilling Fluid, Fresenius Environmental Bulletin, 28(3), 2232-2237.
29. Özkan A, Turan SE, Kaplan BM, 2018a. Investigation of Fly Ash Effect on Rheological and Filtration Properties of Drilling Muds. Fresenius Environmental Bulletin, 27(12A), 9189-9194.
30. Özkan, A. 2020. Effect of Gold Nanoparticle Functionalized Multi-Walled Carbon Nanotubes on the Properties of Na-Bentonite Water Based Drilling Fluid. Fresenius Environmental Bulletin, 29(1), 143-151.
31. Rafati R, Haddad AS, Hamidi H, 2016. Experimental study on stability and rheological properties of aqueous foam in the presence of reservoir natural solid particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 509, 19-31.
32. Shah KA, Najar FA, Sharda T, Sreenivas K, 2018. Synthesis of multi-walled carbon nanotubes by thermal CVD technique on Pt–W–MgO catalyst. Journal of Taibah University for Science, 12(2), 230-234.
33. Singh SK, Ahmed RM, Growcock F, 2010, January. Vital role of nanopolymers in drilling and stimulations fluid applications. In SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
34. Specifications, A. P. I, 2010. 13A, 2010. Specification for Drilling Fluid Materials.
35. Yola ML, Eren T, Atar N, 2014. A novel efficient photocatalyst based on TiO2 nanoparticles involved boron enrichment waste for photocatalytic degradation of atrazine. Chemical Engineering Journal, 250, 288-294.