Synthesis and Crystal Structure of New [HNC5H4B(OH)2–3]2[Pt(CN)4] Compound of Containing Pyridine-3-Boronic Acid and PtCN4

Abstract

In this work, the new compound [HNC5H4B(OH)2–3]2[Pt(CN)4] was synthesized and its crystal structure was characterized by the single crystal X-ray diffraction method. Crystal structure analysis showed in the orthorhombic crystal system of the compound, in the Cmca space group and a= 6.4372(13) Å, b = 14.769(3) Å, c = 19.045(4) Å, 𝛼 = β = γ = 90°, V = 1810.6(6) Å3, Z = 4 crystallization. In the crystalline structure of the compound, [Pt(CN)4]2– anion and [HNC5H4B(OH)2–3]22+ cation interact with N–H⋯NCPt– and strong B(OH)⋯NCPt– hydrogen bonds. Thus, the structure grows in a one-dimension chain structure. A two-dimensional network is formed in the bc plane with the cation molecules directed alternately above and below the glide plane. In addition, hydrogen bond interactions O–H⋯N, C–H⋯O, C–H⋯N and N–H⋯N also hold molecules together. Thus, a three-dimensional packed structure is formed. These hydrogen bond interactions provide the formation of a threedimensional crystal structure and the stability of the lattice structure.

Keywords

• Boroxine acid compound
• crystal structure
• hydrogen bond interactions

3-Piridin Boronik Asit ve PtCN4 İçeren Yeni [HNC5H4B(OH)2–3]2[Pt(CN)4] Bileşiğin Sentezi ve Kristal Yapısı

Abstract

Bu çalışmada, yeni bileşik [HNC5H4B(OH)2–3]2[Pt(CN)4] sentezlendi ve tek kristal X-ışını kırınımı metodu ile kristal yapısı karakterize edildi. Kristal yapı analizi bileşiğin ortorombik kristal sisteminde, Cmca uzay grubunda ve a=6.4372(13) Å, b=14.769(3) Å, c=19.045(4) Å, 𝛼 = β = γ = 90°, V=1810.6(6) Å3, Z=4 kristalleştiğini gösterdi. Bileşiğin kristal yapısında [Pt(CN)4]2– anyonu ve [HNC5H4B(OH)2–3]22+ katyonu N–H⋯NCPt– vegüçlü B(OH)⋯NCPt– hidrojen bağıile etkileşmektedir. Böylece, yapı bir boyutlu zincir bir yapıda büyümektedir. Kayma düzleminin üzerine ve altına dönüşümlü olarak yönlenen katyon molekülleri bc düzleminde iki boyutlu bir ağ oluşturmaktadır. Ayrıca, O–H⋯N, C–H⋯O, C–H⋯N ve N–H⋯N hidrojen bağ etkileşimleri de molekülleri bir arada tutmaktadır. Böylece üç boyutlu paketlenmiş bir yapı oluşmaktadır. Bu hidrojen bağ etkileşimleri üç boyutlu kristal yapının oluşmasını ve kafes yapının kararlılığını sağlamaktadır.

Keywords

• Boronik asit bileşiği
• kristal yapı
• hidrojen bağ etkileşimi

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