Synthesis and Crystal Structure of New [HNC5H4B(OH)2–3]2[Pt(CN)4] Compound of Containing Pyridine-3-Boronic Acid and PtCN4

Öz

In this work, the new compound [HNC5H4B(OH)2–3]2[Pt(CN)4] was synthesized and its crystal structure was characterized by the single crystal X-ray diffraction method. Crystal structure analysis showed in the orthorhombic crystal system of the compound, in the Cmca space group and a= 6.4372(13) Å, b = 14.769(3) Å, c = 19.045(4) Å, 𝛼 = β = γ = 90°, V = 1810.6(6) Å3, Z = 4 crystallization. In the crystalline structure of the compound, [Pt(CN)4]2– anion and [HNC5H4B(OH)2–3]22+ cation interact with N–H⋯NCPt– and strong B(OH)⋯NCPt– hydrogen bonds. Thus, the structure grows in a one-dimension chain structure. A two-dimensional network is formed in the bc plane with the cation molecules directed alternately above and below the glide plane. In addition, hydrogen bond interactions O–H⋯N, C–H⋯O, C–H⋯N and N–H⋯N also hold molecules together. Thus, a three-dimensional packed structure is formed. These hydrogen bond interactions provide the formation of a threedimensional crystal structure and the stability of the lattice structure.

Anahtar Kelimeler

• Boroxine acid compound
• crystal structure
• hydrogen bond interactions

3-Piridin Boronik Asit ve PtCN4 İçeren Yeni [HNC5H4B(OH)2–3]2[Pt(CN)4] Bileşiğin Sentezi ve Kristal Yapısı

Öz

Bu çalışmada, yeni bileşik [HNC5H4B(OH)2–3]2[Pt(CN)4] sentezlendi ve tek kristal X-ışını kırınımı metodu ile kristal yapısı karakterize edildi. Kristal yapı analizi bileşiğin ortorombik kristal sisteminde, Cmca uzay grubunda ve a=6.4372(13) Å, b=14.769(3) Å, c=19.045(4) Å, 𝛼 = β = γ = 90°, V=1810.6(6) Å3, Z=4 kristalleştiğini gösterdi. Bileşiğin kristal yapısında [Pt(CN)4]2– anyonu ve [HNC5H4B(OH)2–3]22+ katyonu N–H⋯NCPt– vegüçlü B(OH)⋯NCPt– hidrojen bağıile etkileşmektedir. Böylece, yapı bir boyutlu zincir bir yapıda büyümektedir. Kayma düzleminin üzerine ve altına dönüşümlü olarak yönlenen katyon molekülleri bc düzleminde iki boyutlu bir ağ oluşturmaktadır. Ayrıca, O–H⋯N, C–H⋯O, C–H⋯N ve N–H⋯N hidrojen bağ etkileşimleri de molekülleri bir arada tutmaktadır. Böylece üç boyutlu paketlenmiş bir yapı oluşmaktadır. Bu hidrojen bağ etkileşimleri üç boyutlu kristal yapının oluşmasını ve kafes yapının kararlılığını sağlamaktadır.

Anahtar Kelimeler

• Boronik asit bileşiği
• kristal yapı
• hidrojen bağ etkileşimi

Kaynakça

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