Research Article
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Investigation of The Effect of Ground Colemanite Additive on Hydraulic Lime-Based Mortars

Year 2025, Volume: 10 Issue: 1, 116 - 125, 28.07.2025
https://doi.org/10.30785/mbud.1636026

Abstract

Boron is a rare metalloid found in borate minerals like borax, kernite, colemanite, and ulexite. In the construction sector, it is used to protect wood from fungi, insects, and decay, as well as to enhance fire resistance in building materials. Additionally, it serves as an additive in cement and concrete to improve structural properties. This study investigated the effects of ground colemanite (45 µm and 75 µm) as a partial substitute (0-3%) for natural hydraulic lime (NHL 3.5) in mortar. The 28-day mechanical strength and physical properties of the samples were analyzed. Results showed that colemanite improved compressive strength but had little impact on other characteristics, including water absorption. This indicates that at low concentrations, colemanite does not significantly affect the mortar's water permeability.

References

  • Ahmad, J., Zhou, Z. & Deifalla, A. F. (2023). Self-compacting concrete with partially substitution of waste marble: a review. International Journal of Concrete Structures and Materials, 17(1), 25.
  • Akgül, Ö. (2010). Zinc borate production from different boron minerals. M.Sc. Thesis. Yıldız Technical University. Graduate School of Applied and Natural Sciences, İstanbul. Access Address (29.05.2010): https://tez.yok.gov.tr/UlusalTezMerkezi/tezSorguSonucYeni.jsp
  • Baştürk, T. B., Yılmaz, A. & Aygörmez, Y. (2025). Sulfate attack, freeze-thaw and high-temperature performances by evaluation of colemanite waste as binding material and aggregate in green geopolymer production. Sustainable Chemistry and Pharmacy, 43, 101872.
  • BS EN 1936. (2006). Natural stone test methods. Determination of real density and apparent density, and of total and open porosity. United Kingdom: British Standards.
  • BS EN 196-1. (2016). Methods of testing cement. Determination of strength. United Kingdom: British Standards.
  • Çelik, A., Yilmaz, K., Canpolat, O., Al-Mashhadani, M. M., Aygörmez, Y. & Uysal, M. (2018). High-temperature behavior and mechanical characteristics of boron waste additive metakaolin based geopolymer composites reinforced with synthetic fibers. Construction and Building Materials, 187, 1190-1203.
  • Çiğdem, M. (2020). Statistical evaluation of the thermal determination process of p-PVC boron composites. M.Sc. Thesis. Uşak University. Graduate School of Applied and Natural Sciences, Uşak.
  • Ediz, N. & Özdağ, H. (2001). Boron minerals and economy, Dumlupınar University. Journal of the Graduate School of Natural and Applied Sciences, 2, 133-151.
  • Eti Maden Operations General Directorate. (2024). 2023 Boron Sector Report. Access Adress (29.05.2024):https://www.etimaden.gov.tr/storage/2023%20YILI %20BOR%20SEKT%C3%96R%20RAPORU.pdf
  • Glinicki, M. A., Antolik, A. & Gawlicki, M. (2018). Evaluation of compatibility of neutron-shielding boron aggregates with Portland cement in mortar. Construction and Building Materials, 164, 731-738.
  • Güner, S. B. (2020). Effects of Silver Doping on Magnetic Levitation Performance of MgB2 Superconductors. Cryogenics, 108, 1-7.
  • Güner, N. U., Kütük, S. & Kütük-Sert, T. (2025). Role of calcination process of natural colemanite powder on compressive strength property of concrete. Heliyon, 11(1).
  • Kara, C., Kütük Sert, T. & Kütük, S. (2020). Öğütülmüş kolemanit içeren betonlarda sodyum klorür etkisi. Duzce University Journal of Science and Technology, 8(1), 499-510. doi: https://doi.org/10.29130/dubited.553523
  • Kara, C., Kütük, S. & Kütük Sert, T. (2023). Improvement of the durability of concrete by substitution of raw ground colemanite. Case Studies in Construction Materials, 19, e02393.
  • Kochkodan, V., Darwish, N. B. & Hilal, N. (2015). The chemistry of boron in water. Elsevier e-Books, 35–63. doi: https://doi.org/10.1016/b978-0-444-63454-2.00002-2.
  • Kula, I., Olgun, A. S. İ. M., Erdogan, Y. & Sevinc, V. (2001). Effects of colemanite waste, cool bottom ash, and fly ash on the properties of cement. Cement and concrete research, 31(3), 491-494.
  • Kurt, Ü., Can, M., Yahşi, M., Adıgüzel, N., Özkul, H., Turhan, A., …, Üzer, S. (2023). Bor madenleri nedir? Nerelerde kullanılır? Türkiye ekonomisine etkileri ve Dünyadaki yeri. International Journal of Social and Humanities Sciences Research (JSHSR), 10(94), 937- 946.
  • Kütük Sert, T. (2016). Stability analyses of submicron-boron mineral prepared by mechanical milling process in concrete roads. Construction and Building Materials, 121, 255-264.
  • Meydan, E. (2019). Boron compounds with magnetic properties and their application areas in industry. Journal of Scientific Perspectives, 3(1),11–20. doi: https://doi.org/10.26900/jsp.3.002.
  • PRT SBD (Presidency of the Republic of Turkey, Strategy and Budget Directorate). (2019). Eleventh Five-Year Development Plan. Access Address (18.07.2019): https://www.sbb.gov.tr/wp- content/uploads/2022/07/On_Birinci_Kalkinma_Plani-2019- 2023.pdf
  • Refsan Industrial Furnace And Machinery Industry Trade Incorporated Company. (n.d.). Kolemanit. Access Address (29.05.2024): https://www.refsan.com.tr/kolemanit-5304
  • Şahin, F. İ. & Acaralı, N. (2023). A survey on application areas and advanced materials for Boron minerals. Current Research in Engineering, 29.
  • Sökmen, N. & Büyükakinci, B. Y. (2018). The use of Boron / Boron compounds in the text industry and their use in Turkey, Cbu International Innovation Conference Science And Education, March 21-23, Prague, Czech Republic.
  • TS EN 459-2. (2021). Yapı kireci- Bölüm 2: Deney yöntemleri. Ankara: Türk Standartları Enstitüsü.
  • Ün, S. (2019). Boron and arsenic removal from Emet boron operations directorate boric acid plant espey area spring water with pilot scale membrane systems. M.Sc. Thesis. Eskişehir Osmangazi University. Graduate School of Applied and Natural Sciences, Eskişehir.
  • Yakıncı, Z. D. & Kök, M. (2016). Use of boron in healthcare. Journal of İnönü University Vocational School of Health Services, 4(1), 36–44.
  • Yenmez, N. (2011). The importance of boron minerals in Turkey as a strategic mine. Journal of Geography, 19, 59–94.
  • Zengi̇n, A., Aka, B., Gençay, S. & Uzun, M. (2021). Boron and Industrial Applications. Europan Journal of Science and Technology, (46), 161-178. doi: https://doi.org/10.31590/ejosat.919451

Hidrolik Kireç Esaslı Harçlarda Öğütülmüş Kolemanit Katkı Maddesinin Etkisinin Araştırılması

Year 2025, Volume: 10 Issue: 1, 116 - 125, 28.07.2025
https://doi.org/10.30785/mbud.1636026

Abstract

Bor, boraks, kernit, kolemanit ve uleksit gibi borat minerallerinde bulunan nadir bir metalloiddir. Yapı sektöründe ahşabı mantar, böcek ve çürümeye karşı korumak için kullanılır. Ayrıca, yapı malzemelerinde yangına dayanıklılığı artıran bir katkı maddesi olarak da yer alır. Çimento ve beton katkısı olarak ise yapısal özellikleri iyileştirmeye yardımcı olur.Bu çalışmada, öğütülmüş kolemanit (45 µm ve 75 µm), doğal hidrolik kireç (NHL 3.5) yerine %0-3 oranında kullanılarak hazırlanan harçların 28 günlük mekanik dayanımı ve fiziksel özellikleri incelenmiştir. Sonuçlar, kolemanit eklemenin basınç dayanımını artırdığını ancak diğer özellikler üzerinde belirgin bir etkisi olmadığını göstermiştir. Özellikle, kolemanit katkısı su emme oranlarını değiştirmemiştir. Bu durum, düşük oranlarda kolemanit katkısının harç matrisinin su geçirgenliği üzerinde sınırlı bir etkisi olduğunu göstermektedir.

References

  • Ahmad, J., Zhou, Z. & Deifalla, A. F. (2023). Self-compacting concrete with partially substitution of waste marble: a review. International Journal of Concrete Structures and Materials, 17(1), 25.
  • Akgül, Ö. (2010). Zinc borate production from different boron minerals. M.Sc. Thesis. Yıldız Technical University. Graduate School of Applied and Natural Sciences, İstanbul. Access Address (29.05.2010): https://tez.yok.gov.tr/UlusalTezMerkezi/tezSorguSonucYeni.jsp
  • Baştürk, T. B., Yılmaz, A. & Aygörmez, Y. (2025). Sulfate attack, freeze-thaw and high-temperature performances by evaluation of colemanite waste as binding material and aggregate in green geopolymer production. Sustainable Chemistry and Pharmacy, 43, 101872.
  • BS EN 1936. (2006). Natural stone test methods. Determination of real density and apparent density, and of total and open porosity. United Kingdom: British Standards.
  • BS EN 196-1. (2016). Methods of testing cement. Determination of strength. United Kingdom: British Standards.
  • Çelik, A., Yilmaz, K., Canpolat, O., Al-Mashhadani, M. M., Aygörmez, Y. & Uysal, M. (2018). High-temperature behavior and mechanical characteristics of boron waste additive metakaolin based geopolymer composites reinforced with synthetic fibers. Construction and Building Materials, 187, 1190-1203.
  • Çiğdem, M. (2020). Statistical evaluation of the thermal determination process of p-PVC boron composites. M.Sc. Thesis. Uşak University. Graduate School of Applied and Natural Sciences, Uşak.
  • Ediz, N. & Özdağ, H. (2001). Boron minerals and economy, Dumlupınar University. Journal of the Graduate School of Natural and Applied Sciences, 2, 133-151.
  • Eti Maden Operations General Directorate. (2024). 2023 Boron Sector Report. Access Adress (29.05.2024):https://www.etimaden.gov.tr/storage/2023%20YILI %20BOR%20SEKT%C3%96R%20RAPORU.pdf
  • Glinicki, M. A., Antolik, A. & Gawlicki, M. (2018). Evaluation of compatibility of neutron-shielding boron aggregates with Portland cement in mortar. Construction and Building Materials, 164, 731-738.
  • Güner, S. B. (2020). Effects of Silver Doping on Magnetic Levitation Performance of MgB2 Superconductors. Cryogenics, 108, 1-7.
  • Güner, N. U., Kütük, S. & Kütük-Sert, T. (2025). Role of calcination process of natural colemanite powder on compressive strength property of concrete. Heliyon, 11(1).
  • Kara, C., Kütük Sert, T. & Kütük, S. (2020). Öğütülmüş kolemanit içeren betonlarda sodyum klorür etkisi. Duzce University Journal of Science and Technology, 8(1), 499-510. doi: https://doi.org/10.29130/dubited.553523
  • Kara, C., Kütük, S. & Kütük Sert, T. (2023). Improvement of the durability of concrete by substitution of raw ground colemanite. Case Studies in Construction Materials, 19, e02393.
  • Kochkodan, V., Darwish, N. B. & Hilal, N. (2015). The chemistry of boron in water. Elsevier e-Books, 35–63. doi: https://doi.org/10.1016/b978-0-444-63454-2.00002-2.
  • Kula, I., Olgun, A. S. İ. M., Erdogan, Y. & Sevinc, V. (2001). Effects of colemanite waste, cool bottom ash, and fly ash on the properties of cement. Cement and concrete research, 31(3), 491-494.
  • Kurt, Ü., Can, M., Yahşi, M., Adıgüzel, N., Özkul, H., Turhan, A., …, Üzer, S. (2023). Bor madenleri nedir? Nerelerde kullanılır? Türkiye ekonomisine etkileri ve Dünyadaki yeri. International Journal of Social and Humanities Sciences Research (JSHSR), 10(94), 937- 946.
  • Kütük Sert, T. (2016). Stability analyses of submicron-boron mineral prepared by mechanical milling process in concrete roads. Construction and Building Materials, 121, 255-264.
  • Meydan, E. (2019). Boron compounds with magnetic properties and their application areas in industry. Journal of Scientific Perspectives, 3(1),11–20. doi: https://doi.org/10.26900/jsp.3.002.
  • PRT SBD (Presidency of the Republic of Turkey, Strategy and Budget Directorate). (2019). Eleventh Five-Year Development Plan. Access Address (18.07.2019): https://www.sbb.gov.tr/wp- content/uploads/2022/07/On_Birinci_Kalkinma_Plani-2019- 2023.pdf
  • Refsan Industrial Furnace And Machinery Industry Trade Incorporated Company. (n.d.). Kolemanit. Access Address (29.05.2024): https://www.refsan.com.tr/kolemanit-5304
  • Şahin, F. İ. & Acaralı, N. (2023). A survey on application areas and advanced materials for Boron minerals. Current Research in Engineering, 29.
  • Sökmen, N. & Büyükakinci, B. Y. (2018). The use of Boron / Boron compounds in the text industry and their use in Turkey, Cbu International Innovation Conference Science And Education, March 21-23, Prague, Czech Republic.
  • TS EN 459-2. (2021). Yapı kireci- Bölüm 2: Deney yöntemleri. Ankara: Türk Standartları Enstitüsü.
  • Ün, S. (2019). Boron and arsenic removal from Emet boron operations directorate boric acid plant espey area spring water with pilot scale membrane systems. M.Sc. Thesis. Eskişehir Osmangazi University. Graduate School of Applied and Natural Sciences, Eskişehir.
  • Yakıncı, Z. D. & Kök, M. (2016). Use of boron in healthcare. Journal of İnönü University Vocational School of Health Services, 4(1), 36–44.
  • Yenmez, N. (2011). The importance of boron minerals in Turkey as a strategic mine. Journal of Geography, 19, 59–94.
  • Zengi̇n, A., Aka, B., Gençay, S. & Uzun, M. (2021). Boron and Industrial Applications. Europan Journal of Science and Technology, (46), 161-178. doi: https://doi.org/10.31590/ejosat.919451
There are 28 citations in total.

Details

Primary Language English
Subjects Materials and Technology in Architecture
Journal Section Research Articles
Authors

Sebahat Sevde Sağlam 0000-0002-4186-4759

Nazife Özer 0000-0003-1072-0493

Seden Acun Özgünler 0000-0001-5975-5115

Publication Date July 28, 2025
Submission Date February 8, 2025
Acceptance Date March 25, 2025
Published in Issue Year 2025 Volume: 10 Issue: 1

Cite

APA Sağlam, S. S., Özer, N., & Acun Özgünler, S. (2025). Investigation of The Effect of Ground Colemanite Additive on Hydraulic Lime-Based Mortars. Journal of Architectural Sciences and Applications, 10(1), 116-125. https://doi.org/10.30785/mbud.1636026