Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques

A. Solak; A. İsbir-turan; A. Natsagdorj; S. Koçak; Z. Kılıç

EN TR

Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques

Abstract

Electrochemical reduction mechanism of some salicylaldimine podands derived from salicylaldehyde and diamines having general formula of HO-C6H4-CH=N-R-N=CH-C6H4-OH [R = ‒, (CH2)6, (CH2CH2)2NH, (CH2CH2OCH2)2], namely N,N’-bis(salicylidene)-diamine (BSA), N,N’-bis(salicylidene)-1,6-hexanediamine (BSH), 1,7-bis(2-hydroxybenzyl)-1,4,7-triazaheptane (BST), 1,10-bis(2-hydroxybenzyl)-4,7-dioxa–1,10-diazadecane (BDD), respectively, were investigated by using various electrochemical techniques in 0.1 M tetrabutylammonium tetrafluoroborate (TBATFB) in acetonitrile (MeCN) at a glassy carbon (GC) electrode. Schiff base podand derivatives show cyclic voltammetric (CV) irreversible one-electron reduction peaks at about -1.82 V, -2.20 V, -2.14 V and -2.10 V at a scan rate of 0.1 V/s at GC electrode (vs. Ag/Ag ), respectively. The reaction mechanism was investigated by CV and decided to be electrochemical-chemical (EC) route and this mechanism was verified by digital simulation. The number of electrons transferred (n) and diffusion coefficients (D) of the compounds were determined using an ultramicroelectrode (UME) by CV, chronoamperometry (CA) and hydrodynamic voltammetry.

Keywords

Podand, digital simulation, EC mechanism, cyclic voltammetry, hydrodynamic voltammetry

Abstract

HO-C6H4-CH=N-R-N=CH-C6H4-OH [R = ‒, (CH2)6, (CH2CH2)2NH, (CH2CH2OCH2)2], adlandırması N,N’-bis(salisiliden)-diamin (BSA), N,N’-bis(salisiliden)-1,6-hekzandiamin (BSH), 1,7-bis(2-hidroksilbenzil)-1,4,7-triazaheptan (BST), 1,10-bis(2-hidroksibenzil)-4,7dioxa–1,10-diazadekan (BDD) olan salisilaldehit ve diaminlerden sentezlenen bazı salisilaldimin podandların bazı elektrokimyasal tekniklerle asetonitrilde hazırlanmış 0,1 M tetrabutilamonyum tetrafloroborat (TBATFB) ortamında ve camsı karbon elektrot kullanılarak elektrokimyasal indirgenme mekanizması araştırılmıştır. Dönüşümlü voltametri tekniği kullanılarak 0.1 V tarama hızında (Ag/Ag+ yardımcı elektrot kullanılarak) ve camsı karbon elektrotta Schiff baz türevlerine ait tersinmez bir elektronlu indirgenme pikleri sırasıyla, yaklaşık olarak -1.82 V, -2.20 V, -2.14 V ve -2.10 V olarak bulunmuştur. Reaksiyon mekanizmaları EC olduğuna karar verilmiş ve EC mekanizması dijital simülasyon ile kanıtlanmıştır. Bileşiklerin elektron aktarım sayısı (n) ve difüzyon katsayısı (D); ultramikroelektrot kullanılarak, dönüşümlü voltametri (CV), kronoamperometri (CA) ve hidrodinamik voltametri teknikleri ile elde edilmiştir. podand, dijital simülasyon, EC mekanizması, dönüşümlü voltametri, hidrodinamik voltametri

Keywords

podand, dijital simülasyon, EC mekanizması, dönüşümlü voltametri, hidrodinamik voltametri

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Primary Language

English

Subjects

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Journal Section

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Authors

A. Solak This is me

A. İsbir-turan This is me

A. Natsagdorj This is me

S. Koçak This is me

Z. Kılıç This is me

Publication Date

October 1, 2014

Submission Date

October 1, 2014

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Year 2014 Volume: 2 Number: 2

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https://izlik.org/JA86KR27LH

APA

Solak, A., İsbir-turan, A., Natsagdorj, A., Koçak, S., & Kılıç, Z. (2014). Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques. MANAS Journal of Engineering, 2(2), 46-58. https://izlik.org/JA86KR27LH

AMA

1.Solak A, İsbir-turan A, Natsagdorj A, Koçak S, Kılıç Z. Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques. MJEN. 2014;2(2):46-58. https://izlik.org/JA86KR27LH

Chicago

Solak, A., A. İsbir-turan, A. Natsagdorj, S. Koçak, and Z. Kılıç. 2014. “Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques”. MANAS Journal of Engineering 2 (2): 46-58. https://izlik.org/JA86KR27LH.

EndNote

Solak A, İsbir-turan A, Natsagdorj A, Koçak S, Kılıç Z (October 1, 2014) Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques. MANAS Journal of Engineering 2 2 46–58.

IEEE

[1]A. Solak, A. İsbir-turan, A. Natsagdorj, S. Koçak, and Z. Kılıç, “Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques”, MJEN, vol. 2, no. 2, pp. 46–58, Oct. 2014, [Online]. Available: https://izlik.org/JA86KR27LH

ISNAD

Solak, A. - İsbir-turan, A. - Natsagdorj, A. - Koçak, S. - Kılıç, Z. “Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques”. MANAS Journal of Engineering 2/2 (October 1, 2014): 46-58. https://izlik.org/JA86KR27LH.

JAMA

1.Solak A, İsbir-turan A, Natsagdorj A, Koçak S, Kılıç Z. Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques. MJEN. 2014;2:46–58.

MLA

Solak, A., et al. “Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques”. MANAS Journal of Engineering, vol. 2, no. 2, Oct. 2014, pp. 46-58, https://izlik.org/JA86KR27LH.

Vancouver

1.A. Solak, A. İsbir-turan, A. Natsagdorj, S. Koçak, Z. Kılıç. Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques. MJEN [Internet]. 2014 Oct. 1;2(2):46-58. Available from: https://izlik.org/JA86KR27LH

Manas Journal of Engineering

16155

Reduction Mechanism Investigation Of Some Schiff Base Podand Derivatives At Glassy Carbon Electrode By Using Electrochemical Techniques

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