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Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells

Year 2023, Volume: 5 Issue: 1, 1 - 8, 30.06.2023

Abstract

To meet the increasing energy demands, studies are carried out to increase the efficiency of photovoltaic technologies, which are popular in renewable energy types. Since dye-sensitized solar cells do not require high infrastructure costs, studies to increase efficiency have focused on dye-sensitized solar cells (DSSC). In DSSC, the photosensitive dye is attached to the TiO2 layer. Endodontic files of endodontic NiTi alloy, which have completed their service life, were taken into solution over different acids and separated into their metallic values. Studies were carried out using TiO2, which was found to be in the anatase phase, which is one of these metallic values, in dye-sensitized solar cells. Within the scope of the study, the structure of contaminated TiO2 obtained from waste NiTi files was characterized, and its optical properties were investigated by attaching N719 dye solution to the surface. It has been revealed that the N719 dye solution used in dye-sensitized solar cells does not show significant activity in the visible region spectrum with the recovered anatase TiO2 treated surface.

Supporting Institution

Necmettin Erbakan Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

201224004

Thanks

The authors would like to thank Assoc. Prof. Dr. Seçkin Akın, Dr. Erdi Akman, and Muhittin Ünal for their technical support. The authors would like to thank EVONIK Corporation for providing the study's reference material (Aeroxide© TiO2 P25).

References

  • R.T. Chen, C.F. Liao, Evaluation and optimization to recycle used TiO2 photoelectrode for dye-sensitized solar cells, International Journal of Photoenergy. 2014 (2014). doi:10.1155/2014/650945.
  • S. Akin, E. Erol, S. Sonmezoglu, Enhancing the electron transfer and band potential tuning with long-term stability of ZnO based dye-sensitized solar cells by gallium and tellurium as dual-doping, Electrochimica Acta. 225 (2017) 243–254. doi:10.1016/j.electacta.2016.12.122.
  • T. Ozturk, B. Gulveren, M. Gulen, E. Akman, S. Sonmezoglu, An insight into titania nanopowders modifying with manganese ions: A promising route for highly efficient and stable photoelectrochemical solar cells, Solar Energy. 157 (2017) 47–57. doi:10.1016/j.solener.2017.08.010.
  • J. Wang, Comparison of development prospects between silicon solar cells and perovskite solar cells, Highlights in Science, Engineering and Technology. 27 (2022) 512–518.
  • D. Yang, R. Yang, S. Priya, S. Liu, Recent advances in flexible perovskite solar cells: fabrication and applications, Angewandte Chemie International Edition. 58 (2019) 4466–4483.
  • H. Tsuji, T. Sagimori, K. Kurita, Y. Gotoh, J. Ishikawa, Surface modification of TiO2 (rutile) by metal negative ion implantation for improving catalytic properties, Surface and Coatings Technology. 158 (2002) 208–213. doi:10.1016/S0257-8972(02)00209-8.
  • R. Sastrawan, Photovoltaic Modules of Dye Solar Cells, Albert-Ludwigs University of Freiburg, 2006.
  • L. Kavan, M. Grätzel, S.E. Gilbert, C. Klemenz, H.J. Scheel, Electrochemical and photoelectrochemical investigation of single-crystal anatase, Journal of the American Chemical Society. 118 (1996) 6716–6723. doi:10.1021/ja954172l.
  • T. Sumita, T. Yamaki, S. Yamamoto, A. Miyashita, Photo-induced surface charge separation of highly oriented TiO 2 anatase and rutile thin films, Applied Surface Science. 200 (2002) 21–26. doi:10.1016/S0169-4332(02)00614-1.
  • R.R. Guimarães, A.L.A. Parussulo, H.E. Toma, K. Araki, Enlightening the synergic effect of anatase/rutile mixtures in solar cells, Electrochimica Acta. 188 (2016) 523–528. doi:10.1016/j.electacta.2015.12.040.
  • M.İ. Özgün, A. Terlemez, M.E. Acma, Y.R. Eker, A.B. Batibay, Recovering of disposed nickel – Titanium rotary endodontic files via sulfuric acid leaching treatments, El-Cezeri Journal of Science and Engineering. 8 (2021) 1–10. doi:10.31202/ecjse.741512.
  • D. Tuschel, Raman spectroscopy and polymorphism, Spectroscopy. 34 (2019) 10–21.
  • J. Wang, J. Yu, X. Zhu, X.Z. Kong, Preparation of hollow TiO2 nanoparticles through TiO2 deposition on polystyrene latex particles and characterizations of their structure and photocatalytic activity, Nanoscale Research Letters. 7 (2012) 1–8. doi:10.1186/1556-276X-7-646.
  • T. MacÉ, S. Vaslin-Reimann, P. Ausset, M. Maillé, Characterization of manufactured TiO2 nanoparticles, Journal of Physics: Conference Series. 429 (2013). doi:10.1088/1742-6596/429/1/012012.
  • J. Jia, L. Mu, Y. Lin, X. Zhou, Electrochimica Acta Rutile versus anatase for quantum dot sensitized solar cell, Electrochimica Acta. 266 (2018) 103–109. doi:10.1016/j.electacta.2018.01.186.

Endodontik NiTi Eğelerden Elde Edilen TiO2' nin Boya Duyarlı Güneş Pillerinde Kullanımının Araştırılması

Year 2023, Volume: 5 Issue: 1, 1 - 8, 30.06.2023

Abstract

Artan enerji taleplerin karşılanmasında yenilenebilir enerji türleri açısından popüler olan fotovoltaik teknolojiler üzerine verim artırmaya yönelik çalışmalar yapılmaktadır. Boya duyarlı güneş pilleri yüksek altyapı maliyeti gerektirmeyen yapılar olduğundan verim artırmaya yönelik çalışmalar boya duyarlı güneş hücreleri (DSSC) üzerine yoğunlaşmıştır. DSSC’de ışığa duyarlı boya, TiO2 tabakasına tutundurulmaktadır. Kullanım ömrünü tamamlamış NiTi alaşımı endodontik eğeler, farklı asitler üzerinden çözeltiye alınıp metalik değerlerine ayrıştırılmış ve bu metalik değerlerden olan anataz fazında olduğu tespit edilen TiO2 ‘nin boya duyarlı güneş hücrelerinde kullanımına yönelik çalışmalar yapılmıştır. Çalışma kapsamında atık NiTi eğelerden elde edilen kontamine TiO2 ‘nin yapısı karakterize edilmiş ve N719 boya çözeltisinin yüzeye tutundurularak optik özellikleri araştırılmıştır. Boya duyarlı güneş hücrelerinde kullanılan N719 boya çözeltisi uygulanan geri kazanım anataz TiO2 tatbik edilmiş yüzeyle ile görünür bölge spektrumunda belirgin bir etkinlik göstermediği ortaya konulmuştur.

Project Number

201224004

References

  • R.T. Chen, C.F. Liao, Evaluation and optimization to recycle used TiO2 photoelectrode for dye-sensitized solar cells, International Journal of Photoenergy. 2014 (2014). doi:10.1155/2014/650945.
  • S. Akin, E. Erol, S. Sonmezoglu, Enhancing the electron transfer and band potential tuning with long-term stability of ZnO based dye-sensitized solar cells by gallium and tellurium as dual-doping, Electrochimica Acta. 225 (2017) 243–254. doi:10.1016/j.electacta.2016.12.122.
  • T. Ozturk, B. Gulveren, M. Gulen, E. Akman, S. Sonmezoglu, An insight into titania nanopowders modifying with manganese ions: A promising route for highly efficient and stable photoelectrochemical solar cells, Solar Energy. 157 (2017) 47–57. doi:10.1016/j.solener.2017.08.010.
  • J. Wang, Comparison of development prospects between silicon solar cells and perovskite solar cells, Highlights in Science, Engineering and Technology. 27 (2022) 512–518.
  • D. Yang, R. Yang, S. Priya, S. Liu, Recent advances in flexible perovskite solar cells: fabrication and applications, Angewandte Chemie International Edition. 58 (2019) 4466–4483.
  • H. Tsuji, T. Sagimori, K. Kurita, Y. Gotoh, J. Ishikawa, Surface modification of TiO2 (rutile) by metal negative ion implantation for improving catalytic properties, Surface and Coatings Technology. 158 (2002) 208–213. doi:10.1016/S0257-8972(02)00209-8.
  • R. Sastrawan, Photovoltaic Modules of Dye Solar Cells, Albert-Ludwigs University of Freiburg, 2006.
  • L. Kavan, M. Grätzel, S.E. Gilbert, C. Klemenz, H.J. Scheel, Electrochemical and photoelectrochemical investigation of single-crystal anatase, Journal of the American Chemical Society. 118 (1996) 6716–6723. doi:10.1021/ja954172l.
  • T. Sumita, T. Yamaki, S. Yamamoto, A. Miyashita, Photo-induced surface charge separation of highly oriented TiO 2 anatase and rutile thin films, Applied Surface Science. 200 (2002) 21–26. doi:10.1016/S0169-4332(02)00614-1.
  • R.R. Guimarães, A.L.A. Parussulo, H.E. Toma, K. Araki, Enlightening the synergic effect of anatase/rutile mixtures in solar cells, Electrochimica Acta. 188 (2016) 523–528. doi:10.1016/j.electacta.2015.12.040.
  • M.İ. Özgün, A. Terlemez, M.E. Acma, Y.R. Eker, A.B. Batibay, Recovering of disposed nickel – Titanium rotary endodontic files via sulfuric acid leaching treatments, El-Cezeri Journal of Science and Engineering. 8 (2021) 1–10. doi:10.31202/ecjse.741512.
  • D. Tuschel, Raman spectroscopy and polymorphism, Spectroscopy. 34 (2019) 10–21.
  • J. Wang, J. Yu, X. Zhu, X.Z. Kong, Preparation of hollow TiO2 nanoparticles through TiO2 deposition on polystyrene latex particles and characterizations of their structure and photocatalytic activity, Nanoscale Research Letters. 7 (2012) 1–8. doi:10.1186/1556-276X-7-646.
  • T. MacÉ, S. Vaslin-Reimann, P. Ausset, M. Maillé, Characterization of manufactured TiO2 nanoparticles, Journal of Physics: Conference Series. 429 (2013). doi:10.1088/1742-6596/429/1/012012.
  • J. Jia, L. Mu, Y. Lin, X. Zhou, Electrochimica Acta Rutile versus anatase for quantum dot sensitized solar cell, Electrochimica Acta. 266 (2018) 103–109. doi:10.1016/j.electacta.2018.01.186.
There are 15 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Muhammed İhsan Özgün 0000-0003-0048-3439

Ahmet Burçin Batıbay 0000-0002-2606-5115

Bayram Ünal 0000-0002-8699-2308

Yasin Ramazan Eker 0000-0001-7395-4364

Arslan Terlemez 0000-0002-6092-4817

Project Number 201224004
Publication Date June 30, 2023
Acceptance Date May 31, 2023
Published in Issue Year 2023 Volume: 5 Issue: 1

Cite

APA Özgün, M. İ., Batıbay, A. B., Ünal, B., Eker, Y. R., et al. (2023). Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells. Necmettin Erbakan Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 5(1), 1-8.
AMA Özgün Mİ, Batıbay AB, Ünal B, Eker YR, Terlemez A. Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells. NEJSE. June 2023;5(1):1-8.
Chicago Özgün, Muhammed İhsan, Ahmet Burçin Batıbay, Bayram Ünal, Yasin Ramazan Eker, and Arslan Terlemez. “Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells”. Necmettin Erbakan Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 5, no. 1 (June 2023): 1-8.
EndNote Özgün Mİ, Batıbay AB, Ünal B, Eker YR, Terlemez A (June 1, 2023) Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells. Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi 5 1 1–8.
IEEE M. İ. Özgün, A. B. Batıbay, B. Ünal, Y. R. Eker, and A. Terlemez, “Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells”, NEJSE, vol. 5, no. 1, pp. 1–8, 2023.
ISNAD Özgün, Muhammed İhsan et al. “Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells”. Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi 5/1 (June 2023), 1-8.
JAMA Özgün Mİ, Batıbay AB, Ünal B, Eker YR, Terlemez A. Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells. NEJSE. 2023;5:1–8.
MLA Özgün, Muhammed İhsan et al. “Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells”. Necmettin Erbakan Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 5, no. 1, 2023, pp. 1-8.
Vancouver Özgün Mİ, Batıbay AB, Ünal B, Eker YR, Terlemez A. Investigation of the Use of TiO2 Obtained from Endodontic NiTi Files in Dye-Sensitized Solar Cells. NEJSE. 2023;5(1):1-8.

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