Atık Madeni Yağlar ve Yağlı Atıksu Arıtma Yöntemlerine Dair Bir Araştırma
Yıl 2021,
, 73 - 84, 16.12.2021
Ezgi Güneş Gürdal
Öz
Endüstriyelleşme ile birlikte dünyadaki madeni yağ talebi her geçen gün büyük artış göstermektedir. Bu artış çeşitli kaynaklara göre ortalama olarak yaklaşık 36 milyon ton/yıldır. Artan talep atık yağın artışına sebep olmaktadır ve insan sağlığı ile çevre için önemli bir tehdit oluşturmaktadır. Bu tehdidi önlemek için yağ atıklarının bertarafının kontrollü bir şekilde yapılması gerekmektedir.
Bu çalışmada madeni yağ üretimi, çeşitleri ve yağ içeren atıksuların bertaraf yöntemleri araştırılmıştır. Elde edilen literatür sonuçlarına göre atık yağ ile kirlenmiş suların arıtımında kullanılan en etkili yöntemler elektrokoagülasyon ve membran filtrasyonudur. Membran filtrasyonunda ise membran gözenek çapı azaldıkça arıtım verimi artış göstermiştir. Uygun koagülant seçimi yapılan elektrokoagülasyon yöntemi ve membran filtrasyonunda nanofiltrasyon yada hibrit sistemler kullanıldığında yüzde yüze varan giderim verimleri tespit edilmiştir. Bununla birlikte tek başına uygulanan konvansiyonel yöntemlerin giderim verimleri düşük olarak tespit edilmiştir.
Kaynakça
- [1]. Tetteh, E. K., Rathilal, S., “Effects of a polymeric organic coagulant for industrial mineral oil wastewater treatment using response surface methodology (RSM),” Water SA, 44(2), 155–161, 2018.
- [2]. Gosalia, A., “Sustainability and the Global Lubricants Industry,” The European Lubricants Industry Magazine, 109, 2012.
- [3]. Tetteh, E. K., Rathilal, S., Chollom, M. N., “Treatment of Industrial Mineral Oil Wastewater-Optimisation of Coagulation Flotation process using Response Surface Methodology (RSM),” International Journal of Applied Engineering Research, 12(23), 13084–13091, 2017.Retrieved from http://www.ripublication.com.
- [4]. Özbey, A., Metin, E., (n.d.) “Atık Yağların Yönetimi,” PETDER, Retrieved November 12, 2021, from https://www.petder.org.tr/Uploads/Document/02cfc115-a858-49ad-98b0-0c1a0f4c1a8e.pdf?v-636450635310213718.
- [5]. Neftçi, A., “Petrol Rafineri Tipleri”, 2015. Retrieved October 1, 2021, from http://docplayer.biz.tr/6268450-Petrol-rafineri-tipleri.html.
- [6]. Rac, A., Vencl, A., “Ecological and Technical Aspects of the waste Oils Influence on the Environment,” Tribology, 18(1), 2012.
- [7]. Mordor Intelligence, “Lubricants Market | Growth, Trends, COVID-19 Impact, and Forecasts (2021- 2026), 2020.Retrieved October 1, 2021, from https://www.mordorintelligence.com/industry-reports/lubricants-market.
- [8]. Hirani, H., Fundamentals of Engineering Tribology with Applications. Delhi: Cambridge University Press, 2016.
- [9]. Çevre ve Şehircilik Bakanlığı, December 21 “Atık Yağların Yönetimi Yönetmeliği,” Resmi Gazete, 2019.Retrieved September 28, 2021, from https://webdosya.csb.gov.tr/db/cygm/icerikler/yon-30985at-kyagyonynt-20201224171101.pdf.
- [10]. O, A. A., Jameel, A. T., Muyubi, S. A., Karim, M. I. A., Alam, and Md. Z., “Removal of Oil and Grease as Emerging Pollutants of Concern (EPC) in Wastewater Stream,” IIUM Engineering Journal, 12(4), 2011.
- [11]. Aljuboury, D. A. D. A., Palaniandy, P., Abdul Aziz, H. B., Feroz, S., “Treatment of petroleum wastewater by conventional and new technologies - A review,” Global Nest Journal, 19(3), 439–452, 2017.
- [12]. Emam, E. A., Shoaib, A. M., “Re-refining of Used Lube Oil, II-by Solvent/Clay and Acid/Clay-Percolation Processes,” ARPN Journal of Science and Technology, 2(11), 2012. Retrieved from http://www.ejournalofscience.org.
- [13]. Abu-Elella, R., Ossman, M. E., Farouq, R. M., Abd-Elfatah, M., “Used Motor Oil Treatment: Turning Waste Oil Into Valuable Products,” International Journal of Chemical and Biochemical Sciences, 7(2015), 57–67, 2015.Retrieved from https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.714.8676&rep=rep1&type=pdf
- [14]. Rincón, J., Cañizares, P., García, M. T., Gracia, I., “Regeneration of Used Lubricant Oil by Propane Extraction,” Industrial and Engineering Chemistry Research, 42(20), 4867–4873, 2003.
- [15]. Vural, U. S., “Waste Mineral Oils Re-Refınıng with Physicochemical Methods,” Turkey Turkish Journal of Engineering (TUJE), 4(2), 62–69, 2020.
- [16]. Kumar, S., Bajwa, N. S., Rana, B. S., Nanoti, S. M., Garg, M. O., “Desulfurization of gas oil using a distillation, extraction and hydrotreating-based integrated process,” Fuel, 220, 754–762, 2018.
- [17]. Betton, C. I., “Lubricants and Their Environmental Impact,” In R. Mortier, M. F. Fox, & S. T. Orszulik (Eds.), Chemistry and Tech of Lubricants (3rd ed., pp. 435–457). London: Springer Science and Business Media B.V., 2010.
- [18]. Jamaly, S., Giwa, A., Hasan, S. W., “Recent improvements in oily wastewater treatment: Progress, challenges, and future opportunities,” Journal of Environmental Sciences, 37, 15–30, 2015.
- [19]. Erol Nalbur, B., Karaelli̇, E., “Petrol İçeren Atıksuların Arıtılabilirliği ve Arıtım Sisteminin Tasarlanması,” Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt, 24(1), 231–242, 2019.
- [20]. Wang, T., “Improve the efficiency of the sewage settling tank degreasing with flotation,” Oil-Gasfield Surface Engineering, 26(7), 26–27, 2007. Retrieved from https://www.scopus.com/record/display.uri?eid=2-s2.0-85006561078&origin=inward&txGid=b99ec0606118e5822166ec9311914c42.
- [21]. Zhu, D. H., Zheng, Z. H., “Application of MAF Air Flotation Technology in Refinery Wastewater Treatment,” Environment Protection in Petrochemical Industry, 25(3), 16–18, 2002. Retrieved from https://www.scopus.com/record/display.uri?eid=2-s2.0-85006575501&origin=inward&txGid=d01d192f641769264835456a2a95560e.
- [22]. Al-Shamrani, A. A., James, A., Xiao, H., “Separation of oil from water by dissolved air flotation,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 209(1), 15–26, 2002.
- [23]. Yu, L., Han, M., He, F., “A review of treating oily wastewater,” Arabian Journal of Chemistry, 10, S1913–S1922, 2017.
- [24]. Lin, Z. S., Wen, W., “Study on Oily Wastewater Treatment with CAX Composite Coagulator,” Mar. Environ. Sci., 22, 15–19, 2003. Retrieved from https://www.scopus.com/record/display.uri?eid=2-s2.0-84958168708&origin=inward&txGid=9d3e30509bad1485de31db773650a5b0.
- [25]. Cong, L. N., Liu, Y. J., Hao, B., “Synthesis and application of PAZSC in oily wastewater treatment,” Chem. Eng., 1(1), 5–9, 2011. Retrieved from https://www.scopus.com/record/display.uri?eid=2-s2.0-85006629907&origin=inward&txGid=cf2e17382f90cadede3f5c33731ac9ed.
- [26]. Körbahti, B. K., Artut, K., “Electrochemical oil/water demulsification and purification of bilge water using Pt/Ir electrodes,” Desalination, 258(1–3), 219–228, 2010.
- [27]. Ngamlerdpokin, K., Kumjadpai, S., Chatanon, P., Tungmanee, U., Chuenchuanchom, S., Jaruwat, P., … Hunsom, M., “Remediation of biodiesel wastewater by chemical- and electro-coagulation: A comparative study,” Journal of Environmental Management, 92(10), 2454–2460, 2011.
- [28]. Jaruwat, P., Kongjao, S., Hunsom, M., “Management of biodiesel wastewater by the combined processes of chemical recovery and electrochemical treatment,” Energy Conversion and Management, 51(3), 531–537, 2010.
- [29]. Sekman, E., Top, S., Uslu, E., Varank, G., Bilgili, M. S., “Treatment of Oily Wastewater From Port Waste Reception Facilities by Electrocoagulation,” International Journal of Environmental Research, 5(4), 1079–1086, 2011.
- [30]. Ahmadi, S., Sardari, E., Javadian, H. R., Katal, R., Sefti, M. V., “Removal of oil from biodiesel wastewater by electrocoagulation method,” Korean Journal of Chemical Engineering 2012 30:3, 30(3), 634–641, 2012.
- [31]. Xu, X., Zhu, X., “Treatment of refectory oily wastewater by electro-coagulation process,” Chemosphere, 56(10), 889–894, 2004.
- [32]. Sun, C., Leiknes, T. O., Weitzenböck, J., Thorstensen, B., “Development of a biofilm-MBR for shipboard wastewater treatment: The effect of process configuration,” Desalination, 250(2), 745–750, 2010.
- [33]. Soltani, S., Mowla, D., Vossoughi, M., Hesampour, M., “Experimental investigation of oily water treatment by membrane bioreactor,” Desalination, 250(2), 598–600, 2010.
- [34]. Salahi, A., Gheshlaghi, A., Mohammadi, T., Madaeni, S. S., “Experimental performance evaluation of polymeric membranes for treatment of an industrial oily wastewater,” Desalination, 262(1–3), 235–242, 2010.
- [35]. Nandi, B. K., Moparthi, A., Uppaluri, R., Purkait, M. K., “Treatment of oily wastewater using low cost ceramic membrane: Comparative assessment of pore blocking and artificial neural network models,” Chemical Engineering Research and Design, 88(7), 881–892, 2010.
- [36]. Yang, T., Ma, Z. F., Yang, Q. Y., “Formation and performance of Kaolin/MnO2 bi-layer composite dynamic membrane for oily wastewater treatment: Effect of solution conditions,” Desalination, 270(1–3), 50–56, 2011.
- [37]. Abadi, S. R. H., Sebzari, M. R., Hemati, M., Rekabdar, F., Mohammadi, T., “Ceramic membrane performance in microfiltration of oily wastewater,” Desalination, 265(1–3), 222–228, 2011.
- [38]. Mittal, P., Jana, S., Mohanty, K., “Synthesis of low-cost hydrophilic ceramic–polymeric composite membrane for treatment of oily wastewater,” Desalination, 282, 54–62, 2011.
- [39]. Pendashteh, A. R., Abdullah, L. C., Fakhru’L-Razi, A., Madaeni, S. S., Zainal Abidin, Z., Awang Biak, D. R., “Evaluation of membrane bioreactor for hypersaline oily wastewater treatment,” Process Safety and Environmental Protection, 90(1), 45–55, 2012.
- [40]. Madaeni, S. S., Gheshlaghi, A., Rekabdar, F., “Membrane treatment of oily wastewater from refinery processes,” Asia-Pacific Journal of Chemical Engineering, 8(1), 45–53, 2013.
- [41]. Noshadi, I., Salahi, A., Hemmati, M., Rekabdar, F., Mohammadi, T., “Experimental and ANFIS modeling for fouling analysis of oily wastewater treatment using ultrafiltration,” Asia-Pacific Journal of Chemical Engineering, 8(4), 527–538, 2013.
- [42]. Karakulski, K., Morawski A. W., “Recovery of process water from spent emulsions generated in copper cable factory,” Journal of Hazardous Materials, 186(2–3), 1667–1671, 2011. Retrieved from https://www.sciencedirect.com/science/article/pii/S0304389410016213.
- [43]. Song, C., Wang, T., Pan, Y., Qiu, J., “Preparation of coal-based microfiltration carbon membrane and application in oily wastewater treatment,” Separation and Purification Technology, 51(1), 80–84, 2006.
- [44]. Cui, J., Zhang, X., Liu, H., Liu, S., Yeung, K. L., “Preparation and application of zeolite/ceramic microfiltration membranes for treatment of oil contaminated water,” Journal of Membrane Science, 325(1), 420–426, 2008.
- [45]. Song, H., Zhou, L., Zhang, L., Gao, B., Wei, D., Shen, Y., … Jiang, Z., “Construction of a whole-cell catalyst displaying a fungal lipase for effective treatment of oily wastewaters,” Journal of Molecular Catalysis B: Enzymatic, 71(3–4), 166–170, 2011.
- [46]. Dumore, N. S., Mukhopadhyay, M., “Removal of oil and grease using immobilized triacylglycerin lipase,” International Biodeterioration & Biodegradation, 68, 65–70, 2012.
- [47]. Tang, H. L., Xie, Y. F., Chen, Y. C., “Use of Bio-Amp, a commercial bio-additive for the treatment of grease trap wastewater containing fat, oil, and grease,” Bioresource Technology, 124, 52–58, 2012.
- [48]. Zhao, X., Wang, Y., Ye, Z., Borthwick, A. G. L., Ni, J., “Oil field wastewater treatment in Biological Aerated Filter by immobilized microorganisms,” Process Biochemistry, 41(7), 1475–1483, 2006.
- [49]. Xie, W., Zhong, L., Chen, J., “Treatment of slightly polluted wastewater in an oil refinery using a biological aerated filter process,” Wuhan University Journal of Natural Sciences 2007 12:6, 12(6), 1094–1098, 2007.
- [50]. Ibrahim, S., Ang, H.-M., Wang, S., “Adsorptive separation of emulsified oil in wastewater using biosorbents,” Asia-Pacific Journal of Chemical Engineering, 7(SUPPL. 2), S216–S221, 2012.
- [51]. Srinivasan, A., Viraraghavan, T., “Oil removal from water by fungal biomass: A factorial design analysis,” Journal of Hazardous Materials, 175(1–3), 695–702, 2010.
- [52]. Nopcharoenkul, W., Netsakulnee, P., Pinyakong, O., “Diesel oil removal by immobilized Pseudoxanthomonas sp. RN402,” Biodegradation, 24, 387–397, 2013.
- [53]. Chanthamalee, J., Wongchitphimon, T., Luepromchai, E., “Treatment of Oily Bilge Water from Small Fishing Vessels by PUF-Immobilized Gordonia sp. JC11,” Water, Air, & Soil Pollution 2013 224:7, 224(7), 1–13, 2013.
- [54]. Otadi, N., Hassani, A. H., Javid, A. H., Khiabani, F. F., “Oily compounds removal in wastewater treatment system of pars oil refinery to improve its efficiency in a lab scale pilot,” Journal of Water Chemistry and Technology 2010 32:6, 32(6), 370–377, 2011.
- [55]. Rattanapan, C., Sawain, A., Suksaroj, T., Suksaroj, C., “Enhanced efficiency of dissolved air flotation for biodiesel wastewater treatment by acidification and coagulation processes,” Desalination, 280(1–3), 370–377, 2011.
- [56]. McLaughlin, C., Falatko, D., Danesi, R., Albert, R., “Characterizing shipboard bilgewater effluent before and after treatment,” Environmental Science and Pollution Research 2014 21:8, 21(8), 5637–5652, 2014.
- [57]. Salahi, A., Badrnezhad, R., Abbasi, M., Mohammadi, T., Rekabdar, F., “Oily wastewater treatment using a hybrid UF/RO system,” New pub: Balaban, 28(1–3), 75–82, 2012.
- [58]. Masoudnia, K., Raisi, A., Aroujalian, A., Fathizadeh, M., “A hybrid microfiltration/ultrafiltration membrane process for treatment of oily wastewater,” New pub: Balaban, 55(4), 901–912, 2014.
- [59]. Ong, C. S., Lau, W. J., Goh, P. S., Ng, B. C., Ismail, A. F., “Investigation of submerged membrane photocatalytic reactor (sMPR) operating parameters during oily wastewater treatment process,” Desalination, 353, 48–56, 2014.