BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ

İlhan Ehsani; Arman Ehsani; Abdullah Obut

doi:10.31796/ogummf.1022705

EN TR

INTERACTION OF BARIUM AND MAGNESIUM CONTAINING SOLIDS WITH CARBONATE LOADED SOLUTIONS

Abstract

In this study, the interaction of barium (Ba(OH)2·8H2O and BaSO4) or magnesium (Mg(OH)2 and MgSO4·7H2O) containing solids with dissolved carbonate-loaded solutions formed after leaching of a local smithsonite (ZnCO3) ore sample in aqueous sodium hydroxide solutions was investigated using X-ray diffraction analyses for the removal of dissolved carbonate (as BaCO3 or MgCO3) in these loaded solutions. It has been observed that solids containing BaCO3 as a single phase and Mg(OH)2 as a main phase are formed, respectively, following the interaction of dissolved carbonate-loaded solutions with Ba(OH)2·8H2O and MgSO4·7H2O solids. On the other hand, it was determined that BaSO4 and Mg(OH)2 solids did not interact with the carbonate-loaded solutions and remained unconverted. However, no conversion to barium or magnesium zincate phases was also found under all studied experimental conditions. Within this study, the conversion properties of alkaline-earth barium and magnesium-containing solids to their corresponding carbonate phases after interacting with dissolved carbonate-loaded solutions were discussed considering the solubilities of these solids. In addition, infrared spectra and scanning electron microscope images of some converted solids obtained after selected experiments were also presented within the scope of this study.

Keywords

Barium hydroxide , Barium Sulfate , Direct conversion , Magnesium hydroxide , Magnesium sulfate

BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ

Öz

Bu çalışmada, baryum (Ba(OH)2·8H2O ve BaSO4) veya magnezyum (Mg(OH)2 ve MgSO4·7H2O) içeren katıların, yerel bir simitsonit (ZnCO3) cevher örneğinin sulu sodyum hidroksit çözeltilerinde liçi sonrasında oluşan çözünmüş karbonat yüklü çözeltilerle etkileşimi, bu yüklü çözeltilerdeki çözünmüş karbonatın (BaCO3 veya MgCO3 olarak) uzaklaştırılması amacıyla, X-ışını kırınımı analizleri kullanılarak incelenmiştir. Çözünmüş karbonat yüklü çözeltilerin Ba(OH)2·8H2O ve MgSO4·7H2O katılarıyla etkileşimini takiben, sırasıyla, tek faz olarak BaCO3 ve ana faz olarak Mg(OH)2 içeren katıların oluştuğu gözlenmiştir. Diğer taraftan, BaSO4 ve Mg(OH)2 katılarının yüklü çözeltilerle herhangi bir etkileşime girmediği ve dönüşmeden kaldıkları belirlenmiştir. Bununla birlikte, çalışılan tüm deneysel koşullar altında, baryum veya magnezyum zinkat fazlarına dönüşümün olmadığı da ortaya çıkarılmıştır. Bu çalışma kapsamında, toprak alkali baryum ve magnezyum içerikli katıların çözünmüş karbonat yüklü çözeltilerle etkileştirilmeleri sonrasında ilgili karbonat fazlarına dönüşüm özellikleri, bu katıların çözünürlükleri dikkate alınarak tartışılmıştır. Ayrıca, seçilmiş deneyler sonrasında elde edilen bazı dönüşmüş katıların kızılötesi spektrumları ve taramalı elektron mikroskop görüntüleri de bu çalışma kapsamında sunulmuştur.

Anahtar Kelimeler

Baryum hidroksit , Baryum sülfat , Doğrudan dönüşüm , Magnezyum hidroksit , Magnezyum sülfat

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Details

Primary Language

Turkish

Subjects

Geological Sciences and Engineering (Other)

Journal Section

Research Article

Authors

İlhan Ehsani ^*
0000-0001-9741-8777
Türkiye

Arman Ehsani
0000-0002-1758-8694
Türkiye

Abdullah Obut
0000-0003-2979-322X
Türkiye

Publication Date

August 18, 2022

Submission Date

November 12, 2021

Acceptance Date

April 6, 2022

Published in Issue

Year 2022 Volume: 30 Number: 2

DOI

https://doi.org/10.31796/ogummf.1022705

IZ

https://izlik.org/JA89GX78JE

APA

Ehsani, İ., Ehsani, A., & Obut, A. (2022). BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 30(2), 211-219. https://doi.org/10.31796/ogummf.1022705

AMA

1.Ehsani İ, Ehsani A, Obut A. BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2022;30(2):211-219. doi:10.31796/ogummf.1022705

Chicago

Ehsani, İlhan, Arman Ehsani, and Abdullah Obut. 2022. “BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 30 (2): 211-19. https://doi.org/10.31796/ogummf.1022705.

EndNote

Ehsani İ, Ehsani A, Obut A (August 1, 2022) BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 30 2 211–219.

IEEE

[1]İ. Ehsani, A. Ehsani, and A. Obut, “BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ”, Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, vol. 30, no. 2, pp. 211–219, Aug. 2022, doi: 10.31796/ogummf.1022705.

ISNAD

Ehsani, İlhan - Ehsani, Arman - Obut, Abdullah. “BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 30/2 (August 1, 2022): 211-219. https://doi.org/10.31796/ogummf.1022705.

JAMA

1.Ehsani İ, Ehsani A, Obut A. BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2022;30:211–219.

MLA

Ehsani, İlhan, et al. “BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 30, no. 2, Aug. 2022, pp. 211-9, doi:10.31796/ogummf.1022705.

Vancouver

1.İlhan Ehsani, Arman Ehsani, Abdullah Obut. BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2022 Aug. 1;30(2):211-9. doi:10.31796/ogummf.1022705

INTERACTION OF BARIUM AND MAGNESIUM CONTAINING SOLIDS WITH CARBONATE LOADED SOLUTIONS

Abstract

Keywords

BARYUM VE MAGNEZYUM İÇEREN KATILARIN KARBONAT YÜKLÜ ÇÖZELTİLERLE ETKİLEŞİMİ

Öz

Anahtar Kelimeler

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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