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YÜKSEK ENTROPİLİ OKSİ-HİDROKSİTLERIN ÜRETİLMESİ, KARAKTERİZASYONU VE OKSİJEN ÇEVRİM REAKSİYONU ELEKTRO KATALİZÖRÜ OLARAK UYGULANMASI

Year 2023, Volume: 31 Issue: 2, 698 - 704, 21.08.2023
https://doi.org/10.31796/ogummf.1290574

Abstract

Artan enerji talebini karşılamak ve çevre kirliliği endişelerini azaltmak için yenilenebilir enerji sistemleri ve verimli enerji dönüşüm cihazları kullanmak, yeni elektrokimyasal enerji depolama sistemleri geliştirmek gerekmektedir. Bu bağlamda, hidrojen üretimi, kati yakıt hücreleri ve metal-hava bataryaları gibi yeni nesi enerji üretme ve depolama sistemlerinde oksijen cevrim reaksiyonları sistemlerin performanslarında önemli rol oynamaktadır. Dolayısı ile bu reaksiyonları hızlandırmak için yeni fonksiyonel malzemeler araştırılmaktadır. Yüksek entropili hidroksitler, son zamanlarda, katı oksit yakıt hücreleri, hidrojen üretimi ve metal-hava pilleri için merkezi olan evrensel su ayırma reaksiyonları için umut verici bir elektrokatalizör malzemesi olarak on plana çıkmıştır. Bu çalışmada, tek adımlı elektrodepozisyon tekniği ile Nikel köpük üzerinde farklı kompozisyonlarda yüksek entropili hidroksitler’ in direkt üretimi araştırılmıştır. Elde edilen elektrokatalizorlerin elektrokimyasal performanslarına üretim voltaji, suresi ve elementel etki incelenmiştir. Sonuçlar, yüksek entropili FeCoNiMnOOH' un 100 mA cm-2' lik akım yoğunluğunda 151 mV' lik düşük bir aşırı potansiyeli sergilediğini göstermiştir. FeCoNiMnOOH yüksek oksijen oluşum reaksiyonu katalitik aktivitesi ise yapıda bulunan oksijen hataları ile ilişkilendirilmiştir

References

  • Bayraktar, O., Lökçü, E., Ozgur, C., Erdil, T. & Toparli, C. (2022). Effect of synthesis environment on the electrochemical properties of (FeMnCrCoZn)3O4 high-entropy oxides for Li-ion batteries. International Journal of Energy Research 46, 22124–22133. doi: https://doi.org/10.1002/er.8749
  • Dai, W., Lu, T. & Pan, Y. (2019). Novel and promising electrocatalyst for oxygen evolution reaction based on MnFeCoNi high entropy alloy. Journal of Power Sources 430, 104-111. doi: https://doi.org/10.1016/j.jpowsour.2019.05.030
  • Erdil, E., Lökçü, E., Yildiz I., Okuyucu, C., Kalay, Y. E., Toparli, C. (2022). Facile Synthesis and Origin of Enhanced Electrochemical Oxygen Evolution Reaction Performance of 2H-Hexagonal Ba2CoMnO6−δ as a New Member in Double Perovskite Oxides. ACS Omega 7(48), 44147–44155. doi: https://doi.org/10.1021/acsomega.2c05627
  • Liu, P. F., Yin, H., Fu, H.Q., Zu, M.Y., Yang, H.G., Zhao, H. (2020). Activation strategies of water-splitting electrocatalysts. Journal of Materials Chemistry A 8, 10096-10129.doi: https://doi.org/10.1039/D0TA01680B
  • Lokcu, E. Toparli, C. & Anik, M. (2020). Electrochemical Performance of (MgCoNiZn)1–xLixO High-Entropy Oxides in Lithium-Ion Batteries. ACS Applied Materials Interfaces 12 (21), 23860–23866. doi: https://doi.org/10.1021/acsami.0c03562
  • Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, ... Maria, J. P. (2015). Entropy-Stabilized Oxides. Nature Communications 6 (1), 8485. doi: https://doi.org/10.1038/ncomms9485
  • Trotochaud, L., Young, S. L., Ranney, J. K., & Boettcher, S. W. (2014). Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation. Journal of Ameriacan Chemical Society 136 (18), 6744–6753. doi: https://doi.org/10.1021/ja502379c
  • Wang, T., Chen, H., Yang, Z., Liang, J. & Dai, S. (2020). High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis. Journal of American Chemical Society 142 (10), 4550–4554. doi: https://doi.org/10.1021/jacs.9b12377
  • Wang, Q., Li., J., Li., Y., Shao, G., Jia, Z., Shen, B. (2022). Non-Noble Metal-Based Amorphous High-Entropy Oxides as Efficient and Reliable Electrocatalysts for Oxygen Evolution Reaction. Nano Research 15, 8751–8759. doi: https://doi.org/10.1007/s12274-022-4179-8.
  • Zhou, C., Chen, X., Liu, S., Han, Y., Meng, H., Jiang, Q., ...Zhang, R. (2022). Superdurable Bifunctional Oxygen Electrocatalyst for High-Performance Zinc–Air Batteries. Journal of American Chemical Society 144 (6), 2694–2704. doi: https://doi.org/10.1021/jacs.1c11675

SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION

Year 2023, Volume: 31 Issue: 2, 698 - 704, 21.08.2023
https://doi.org/10.31796/ogummf.1290574

Abstract

The need for energy is rising quickly, and the usage of fossil fuels is contributing to the greenhouse effect and environmental pollution, both of which are raising public concerns. The development of novel electrochemical energy storage techniques as well as the creation of cleaner, more sustainable energies have both become highly researched topics as a result of this condition. New functional materials are being investigated for the advancement of energy storage. High entropy hydroxides (HEH) have lately been emerged as promising electrocatalyst for universal water splitting reactions, which are central for solid oxide fuel cells, hydrogen production and metal-air batteries. In this work, a cost-effective and scalable fabrication method was applied to fabricate several HEH on Nickel foam through single-step electrodeposition technique. Results showed that high-entropy FeCoNiMnOOH exhibits excellent OER activity with a low overpotential of 151 mV at current density of 100 mA cm−2, which is associated with it’s defective structure.

References

  • Bayraktar, O., Lökçü, E., Ozgur, C., Erdil, T. & Toparli, C. (2022). Effect of synthesis environment on the electrochemical properties of (FeMnCrCoZn)3O4 high-entropy oxides for Li-ion batteries. International Journal of Energy Research 46, 22124–22133. doi: https://doi.org/10.1002/er.8749
  • Dai, W., Lu, T. & Pan, Y. (2019). Novel and promising electrocatalyst for oxygen evolution reaction based on MnFeCoNi high entropy alloy. Journal of Power Sources 430, 104-111. doi: https://doi.org/10.1016/j.jpowsour.2019.05.030
  • Erdil, E., Lökçü, E., Yildiz I., Okuyucu, C., Kalay, Y. E., Toparli, C. (2022). Facile Synthesis and Origin of Enhanced Electrochemical Oxygen Evolution Reaction Performance of 2H-Hexagonal Ba2CoMnO6−δ as a New Member in Double Perovskite Oxides. ACS Omega 7(48), 44147–44155. doi: https://doi.org/10.1021/acsomega.2c05627
  • Liu, P. F., Yin, H., Fu, H.Q., Zu, M.Y., Yang, H.G., Zhao, H. (2020). Activation strategies of water-splitting electrocatalysts. Journal of Materials Chemistry A 8, 10096-10129.doi: https://doi.org/10.1039/D0TA01680B
  • Lokcu, E. Toparli, C. & Anik, M. (2020). Electrochemical Performance of (MgCoNiZn)1–xLixO High-Entropy Oxides in Lithium-Ion Batteries. ACS Applied Materials Interfaces 12 (21), 23860–23866. doi: https://doi.org/10.1021/acsami.0c03562
  • Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, ... Maria, J. P. (2015). Entropy-Stabilized Oxides. Nature Communications 6 (1), 8485. doi: https://doi.org/10.1038/ncomms9485
  • Trotochaud, L., Young, S. L., Ranney, J. K., & Boettcher, S. W. (2014). Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation. Journal of Ameriacan Chemical Society 136 (18), 6744–6753. doi: https://doi.org/10.1021/ja502379c
  • Wang, T., Chen, H., Yang, Z., Liang, J. & Dai, S. (2020). High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis. Journal of American Chemical Society 142 (10), 4550–4554. doi: https://doi.org/10.1021/jacs.9b12377
  • Wang, Q., Li., J., Li., Y., Shao, G., Jia, Z., Shen, B. (2022). Non-Noble Metal-Based Amorphous High-Entropy Oxides as Efficient and Reliable Electrocatalysts for Oxygen Evolution Reaction. Nano Research 15, 8751–8759. doi: https://doi.org/10.1007/s12274-022-4179-8.
  • Zhou, C., Chen, X., Liu, S., Han, Y., Meng, H., Jiang, Q., ...Zhang, R. (2022). Superdurable Bifunctional Oxygen Electrocatalyst for High-Performance Zinc–Air Batteries. Journal of American Chemical Society 144 (6), 2694–2704. doi: https://doi.org/10.1021/jacs.1c11675
There are 10 citations in total.

Details

Primary Language English
Subjects Material Production Technologies
Journal Section Research Articles
Authors

Cıgdem Toparli 0000-0002-4374-4910

Early Pub Date August 21, 2023
Publication Date August 21, 2023
Acceptance Date July 17, 2023
Published in Issue Year 2023 Volume: 31 Issue: 2

Cite

APA Toparli, C. (2023). SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 31(2), 698-704. https://doi.org/10.31796/ogummf.1290574
AMA Toparli C. SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION. ESOGÜ Müh Mim Fak Derg. August 2023;31(2):698-704. doi:10.31796/ogummf.1290574
Chicago Toparli, Cıgdem. “SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 31, no. 2 (August 2023): 698-704. https://doi.org/10.31796/ogummf.1290574.
EndNote Toparli C (August 1, 2023) SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 31 2 698–704.
IEEE C. Toparli, “SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION”, ESOGÜ Müh Mim Fak Derg, vol. 31, no. 2, pp. 698–704, 2023, doi: 10.31796/ogummf.1290574.
ISNAD Toparli, Cıgdem. “SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 31/2 (August 2023), 698-704. https://doi.org/10.31796/ogummf.1290574.
JAMA Toparli C. SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION. ESOGÜ Müh Mim Fak Derg. 2023;31:698–704.
MLA Toparli, Cıgdem. “SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 31, no. 2, 2023, pp. 698-04, doi:10.31796/ogummf.1290574.
Vancouver Toparli C. SYNTHESIS AND CHARACTERIZATION OF HIGH ENTROPY OXY-HYDROXIDES FOR ELECTROCATALYTIC OXYGEN EVOLUTION AND REDUCTION REACTION. ESOGÜ Müh Mim Fak Derg. 2023;31(2):698-704.

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