Research Article
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Year 2023, , 965 - 974, 18.10.2023
https://doi.org/10.16984/saufenbilder.1225856

Abstract

References

  • M. Kayfeci, A. Keçebaş, M. Bayat, "Chapter 3 - Hydrogen production," Solar hydrogen production, Elsevier, 2019, p. 45-83.
  • A. J. Esswein, D. G. Nocera, "Hydrogen production by molecular photocatalysis," Chemical Reviews, vol. 107, no.10, pp. 4022-47, 2007.
  • J. D. Holladay, J. Hu, D. L. King, Y. Wang, "An overview of hydrogen production technologies," Catalysis Today, vol. 139, no. 4, pp. 244-60, 2009.
  • H. F. Abbas, W. W. Daud, "Hydrogen production by methane decomposition: a review," International Journal of Hydrogen Energy, vol. 35, no. 3, pp. 1160-90, 2010.
  • Y. Kashiwaya, M. Watanabe, "Kinetic analysis of the decomposition reaction of CH4 injecting into molten slag," ISIJ International, vol. 52, no. 8, pp. 1394-403, 2012.
  • D. Hirsch, A. Steinfeld, "Solar hydrogen production by thermal decomposition of natural gas using a vortex-flow reactor," International Journal of Hydrogen Energy, vol. 29, no. 1, pp. 47-55, 2004.
  • J. K. Dahl, K. J. Buechler, A.W. Weimer, A. Lewandowski, C. Bingham, "Solar-thermal dissociation of methane in a fluid-wall aerosol flow reactor," International Journal of Hydrogen Energy, vol. 29, no. 7, pp. 725-36, 2004.
  • G. Maag, G. Zanganeh, A. Steinfeld, "Solar thermal cracking of methane in a particle-flow reactor for the co-production of hydrogen and carbon," International Journal of Hydrogen Energy, vol. 34, no. 18, pp. 7676-85, 2009.
  • D. P. Serrano, J. A. Botas, J. L. G. Fierro, R. Guil-López, P. Pizarro, G. Gómez, "Hydrogen production by methane decomposition: origin of the catalytic activity of carbon materials," Fuel, vol. 89, no. 6, pp. 1241-8, 2010.
  • I. Suelves, M. Lázaro, R. Moliner, B. Corbella, J. Palacios, "Hydrogen production by thermo catalytic decomposition of methane on Ni-based catalysts: influence of operating conditions on catalyst deactivation and carbon characteristics," International Journal of Hydrogen Energy, vol. 30, no. 15, pp. 1555-67, 2005.
  • S. Takenaka, M. Serizawa, K. Otsuka, "Formation of filamentous carbons over supported Fe catalysts through methane decomposition," Journal of Catalysis, vol. 222, no. 2, pp.520-31, 2004.
  • A. A. Kiss, R. Geertman, M. Wierschem, M. Skiborowski, B. Gielen, J. Jordens, J. J. John, T. V. Gerven, "Ultrasound‐assisted emerging technologies for chemical processes," Journal of Chemical Technology & Biotechnology, vol.93, no. 5, pp. 1219-27, 2018.
  • M. Nuechter, U. Mueller, B. Ondruschka, A. Tied, W. Lautenschlaeger, "Microwave‐assisted chemical reactions," Chemical Engineering & Technology, vol. 26, no. 12, pp. 1207-16, 2003.
  • P. Atkins, J. Paula, Physical Chemistry. Oxford University Press, 2014.
  • F. Huarte-Larrañaga, U. Manthe, "Quantum dynamics of the CH4+H→ CH3+H2 reaction: full-dimensional and reduced dimensionality rate constant calculations," The Journal of Physical Chemistry A, vol. 105, no. 12, pp. 2522-9, 2001.
  • J. Palma, J. Echave, D. C. Clary, "Rate constants for the CH4+H→CH3+H2 reaction calculated with a generalized reduced-dimensionality method," The Journal of Physical Chemistry A, vol. 106, no. 36, pp. 8256-60, 2002.
  • J. P. Camden, H. A. Bechtel, D. J. A. Brown, R. N. Zare, "Effects of C–H stretch excitation on the H+CH4 reaction," The Journal of chemical physics, vol. 123, no. 13, 134301, 2005.
  • W. R. Simpson, T. P. Rakitzis, S. A. Kandel, A. J. Orr‐Ewing, R. N. Zare, "Reaction of Cl with vibrationally excited CH4 and CHD3: State‐to‐state differential cross sections and steric effects for the HCl product," The Journal of Chemical Physics, vol. 103, no. 17, pp. 7313-35, 1995.
  • F. Menard-Bourcin, C. Boursier, L. Doyennette, J. Menard, "Rotational and vibrational relaxation of methane excited to 2ν3 in CH4/H2 and CH4/He mixtures at 296 and 193 K from double-resonance measurements," The Journal of Physical Chemistry A, vol. 109, no. 14, pp. 3111-9, 2005.
  • J. C. Corchado, J. L. Bravo, J. Espinosa-Garcia, "The hydrogen abstraction reaction H+CH4. I. New analytical potential energy surface based on fitting to ab initio calculations," The Journal of Chemical Physics, vol. 130, no.18, pp. 184314, 2009.
  • H. Hoshina, M. Fushitani, T. Momose, "Infrared spectroscopy of rovibrational transitions of methyl radicals (CH3, CD3) in solid parahydrogen," Journal of Molecular Spectroscopy, vol. 268, no.1-2, pp. 164-72, 2011.
  • D. A. McQuarrie, J. D. Simon, Physical Chemistry: A Molecular Approach, University Science Books Sausalito, CA, 1997.
  • F. Kumsar, "Investigation of the rotation-vibration energies of diatomic and polyatomic molecules by approximation method," Hitit University, 2015.
  • P. Maroni, "Bond-and mode-specific reactivity of methane on Ni (100)," Pisa University, EPFL, 2005.
  • W. Kauzmann, Kinetic Theory of Gases, Courier Corporation, 2012.
  • R. Sanderson, Chemical Bonds and Bonds Energy, Elsevier, 2012.
  • C. K. Law, Combustion Physics, Cambridge University Press, 2010.
  • M. Brouard, D. H. Parker, S. Y. Van de Meerakker, "Taming molecular collisions using electric and magnetic fields," Chemical Society Reviews, vol. 43, no. 21, pp. 7279-94, 2014.
  • A. Laganà, G. A. Parker, Chemical Reactions: Basic Theory and Computing, Springer, 2018.
  • A. Domínguez, B. Fidalgo, Y. Fernández, J. Pis, J. Menéndez, "Microwave-assisted catalytic decomposition of methane over activated carbon for CO2-free hydrogen production," International Journal of Hydrogen Energy, vol. 32, no. 18, pp. 4792-9, 2007.
  • Y. Y. Tanashev, V. I. Fedoseev, Y. I. Aristov, V. V. Pushkarev, L.B. Avdeeva, V. I. Zaikovskii, V. N. Parmon, "Methane processing under microwave radiation: Recent findings and problems," Catalysis Today, vol. 42, no. 3, pp. 333-6, 1998.
  • W. H. Chen, H. J. Liou, C. I. Hung, "A numerical approach of interaction of methane thermocatalytic decomposition and microwave irradiation," International Journal of Hydrogen Energy, vol. 38, no. 30, pp. 13260-71, 2013.
  • A. G. Smolin, O. S. Vasyutinskii, G. G. Balint-Kurti, A. Brown, "Photodissociation of HBr. 1. Electronic structure, photodissociation dynamics, and vector correlation coefficients," The Journal of Physical Chemistry A, vol. 110, no.16, pp.5371-8, 2006.
  • N. H. Nahler, R. Baumfalk, U. Buck, H. Vach, P. Slavíček, P. Jungwirth, "Photodissociation of HBr in and on Ar n clusters: the role of the position of the molecule," Physical Chemistry Chemical Physics, vol. 5, no. 16, pp. 3394-401, 2003.
  • P. M. Regan, S. R. Langford, A. J. Orr-Ewing, M. N. Ashfold. "The ultraviolet photodissociation dynamics of hydrogen bromide," The Journal of Chemical Physics, vol. 110, no. 1, pp. 281-8, 1999.
  • V. Belyi, N. Kondratyuk, A. Shagov, A. Mashchenko, "Parametric amplification of light in a BBO crystal with pumping by YAG: Nd laser radiation," Journal of Applied Spectroscopy, vol. 67, pp. 364-8, 2000.
  • K. Semwal, S. Bhatt, "Tuning of wavelengths for producing eye safe laser using second order nonlinear processes," International Journal of Optics and Applications, vol. 2, no. 3, pp. 20-8, 2012.
  • Y. R. Luo, Comprehensive Handbook of Chemical Bond Energies, CRC Press, 2007.

Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration

Year 2023, , 965 - 974, 18.10.2023
https://doi.org/10.16984/saufenbilder.1225856

Abstract

Some factors, such as pressure and temperature, affect the rate of chemical reactions. In addition, the activation energy barrier must be overcome for the reaction to be initiated. It can be preferred to overcome this barrier by using catalysts and preheating. The catalyst ensures that it obtains the energy to react quickly by transferring it to the reactants. Similarly, the translational, vibrational, and rotational energy levels of reactants can be increased by preheating. According to the kinetic molecular theory of gases, preheating increases the kinetic energies of the gases and the speed of their collision, so the reaction takes place faster. This study theoretically investigates possible reactions of methane that can occur with the effect of only vibrational energy levels. The vibrational excitation of the molecules affects the reaction rates, and the activation barrier is overcome with lower energies. Using laser-based techniques makes the excitation of well-defined vibrational modes possible. This study investigated inelastic collisions of a methane molecule with well-characterized energy levels in infrared spectroscopy with some gases and the vibrational energy transfers that occur in these collisions. The methane molecule is the simplest form of a molecular structure consisting of more than three atoms of hydrogen atoms, which play an essential role in combustion chemistry. It shows that C⸺H stretch excitation increases the reaction rate of methane (CH4) molecules.

References

  • M. Kayfeci, A. Keçebaş, M. Bayat, "Chapter 3 - Hydrogen production," Solar hydrogen production, Elsevier, 2019, p. 45-83.
  • A. J. Esswein, D. G. Nocera, "Hydrogen production by molecular photocatalysis," Chemical Reviews, vol. 107, no.10, pp. 4022-47, 2007.
  • J. D. Holladay, J. Hu, D. L. King, Y. Wang, "An overview of hydrogen production technologies," Catalysis Today, vol. 139, no. 4, pp. 244-60, 2009.
  • H. F. Abbas, W. W. Daud, "Hydrogen production by methane decomposition: a review," International Journal of Hydrogen Energy, vol. 35, no. 3, pp. 1160-90, 2010.
  • Y. Kashiwaya, M. Watanabe, "Kinetic analysis of the decomposition reaction of CH4 injecting into molten slag," ISIJ International, vol. 52, no. 8, pp. 1394-403, 2012.
  • D. Hirsch, A. Steinfeld, "Solar hydrogen production by thermal decomposition of natural gas using a vortex-flow reactor," International Journal of Hydrogen Energy, vol. 29, no. 1, pp. 47-55, 2004.
  • J. K. Dahl, K. J. Buechler, A.W. Weimer, A. Lewandowski, C. Bingham, "Solar-thermal dissociation of methane in a fluid-wall aerosol flow reactor," International Journal of Hydrogen Energy, vol. 29, no. 7, pp. 725-36, 2004.
  • G. Maag, G. Zanganeh, A. Steinfeld, "Solar thermal cracking of methane in a particle-flow reactor for the co-production of hydrogen and carbon," International Journal of Hydrogen Energy, vol. 34, no. 18, pp. 7676-85, 2009.
  • D. P. Serrano, J. A. Botas, J. L. G. Fierro, R. Guil-López, P. Pizarro, G. Gómez, "Hydrogen production by methane decomposition: origin of the catalytic activity of carbon materials," Fuel, vol. 89, no. 6, pp. 1241-8, 2010.
  • I. Suelves, M. Lázaro, R. Moliner, B. Corbella, J. Palacios, "Hydrogen production by thermo catalytic decomposition of methane on Ni-based catalysts: influence of operating conditions on catalyst deactivation and carbon characteristics," International Journal of Hydrogen Energy, vol. 30, no. 15, pp. 1555-67, 2005.
  • S. Takenaka, M. Serizawa, K. Otsuka, "Formation of filamentous carbons over supported Fe catalysts through methane decomposition," Journal of Catalysis, vol. 222, no. 2, pp.520-31, 2004.
  • A. A. Kiss, R. Geertman, M. Wierschem, M. Skiborowski, B. Gielen, J. Jordens, J. J. John, T. V. Gerven, "Ultrasound‐assisted emerging technologies for chemical processes," Journal of Chemical Technology & Biotechnology, vol.93, no. 5, pp. 1219-27, 2018.
  • M. Nuechter, U. Mueller, B. Ondruschka, A. Tied, W. Lautenschlaeger, "Microwave‐assisted chemical reactions," Chemical Engineering & Technology, vol. 26, no. 12, pp. 1207-16, 2003.
  • P. Atkins, J. Paula, Physical Chemistry. Oxford University Press, 2014.
  • F. Huarte-Larrañaga, U. Manthe, "Quantum dynamics of the CH4+H→ CH3+H2 reaction: full-dimensional and reduced dimensionality rate constant calculations," The Journal of Physical Chemistry A, vol. 105, no. 12, pp. 2522-9, 2001.
  • J. Palma, J. Echave, D. C. Clary, "Rate constants for the CH4+H→CH3+H2 reaction calculated with a generalized reduced-dimensionality method," The Journal of Physical Chemistry A, vol. 106, no. 36, pp. 8256-60, 2002.
  • J. P. Camden, H. A. Bechtel, D. J. A. Brown, R. N. Zare, "Effects of C–H stretch excitation on the H+CH4 reaction," The Journal of chemical physics, vol. 123, no. 13, 134301, 2005.
  • W. R. Simpson, T. P. Rakitzis, S. A. Kandel, A. J. Orr‐Ewing, R. N. Zare, "Reaction of Cl with vibrationally excited CH4 and CHD3: State‐to‐state differential cross sections and steric effects for the HCl product," The Journal of Chemical Physics, vol. 103, no. 17, pp. 7313-35, 1995.
  • F. Menard-Bourcin, C. Boursier, L. Doyennette, J. Menard, "Rotational and vibrational relaxation of methane excited to 2ν3 in CH4/H2 and CH4/He mixtures at 296 and 193 K from double-resonance measurements," The Journal of Physical Chemistry A, vol. 109, no. 14, pp. 3111-9, 2005.
  • J. C. Corchado, J. L. Bravo, J. Espinosa-Garcia, "The hydrogen abstraction reaction H+CH4. I. New analytical potential energy surface based on fitting to ab initio calculations," The Journal of Chemical Physics, vol. 130, no.18, pp. 184314, 2009.
  • H. Hoshina, M. Fushitani, T. Momose, "Infrared spectroscopy of rovibrational transitions of methyl radicals (CH3, CD3) in solid parahydrogen," Journal of Molecular Spectroscopy, vol. 268, no.1-2, pp. 164-72, 2011.
  • D. A. McQuarrie, J. D. Simon, Physical Chemistry: A Molecular Approach, University Science Books Sausalito, CA, 1997.
  • F. Kumsar, "Investigation of the rotation-vibration energies of diatomic and polyatomic molecules by approximation method," Hitit University, 2015.
  • P. Maroni, "Bond-and mode-specific reactivity of methane on Ni (100)," Pisa University, EPFL, 2005.
  • W. Kauzmann, Kinetic Theory of Gases, Courier Corporation, 2012.
  • R. Sanderson, Chemical Bonds and Bonds Energy, Elsevier, 2012.
  • C. K. Law, Combustion Physics, Cambridge University Press, 2010.
  • M. Brouard, D. H. Parker, S. Y. Van de Meerakker, "Taming molecular collisions using electric and magnetic fields," Chemical Society Reviews, vol. 43, no. 21, pp. 7279-94, 2014.
  • A. Laganà, G. A. Parker, Chemical Reactions: Basic Theory and Computing, Springer, 2018.
  • A. Domínguez, B. Fidalgo, Y. Fernández, J. Pis, J. Menéndez, "Microwave-assisted catalytic decomposition of methane over activated carbon for CO2-free hydrogen production," International Journal of Hydrogen Energy, vol. 32, no. 18, pp. 4792-9, 2007.
  • Y. Y. Tanashev, V. I. Fedoseev, Y. I. Aristov, V. V. Pushkarev, L.B. Avdeeva, V. I. Zaikovskii, V. N. Parmon, "Methane processing under microwave radiation: Recent findings and problems," Catalysis Today, vol. 42, no. 3, pp. 333-6, 1998.
  • W. H. Chen, H. J. Liou, C. I. Hung, "A numerical approach of interaction of methane thermocatalytic decomposition and microwave irradiation," International Journal of Hydrogen Energy, vol. 38, no. 30, pp. 13260-71, 2013.
  • A. G. Smolin, O. S. Vasyutinskii, G. G. Balint-Kurti, A. Brown, "Photodissociation of HBr. 1. Electronic structure, photodissociation dynamics, and vector correlation coefficients," The Journal of Physical Chemistry A, vol. 110, no.16, pp.5371-8, 2006.
  • N. H. Nahler, R. Baumfalk, U. Buck, H. Vach, P. Slavíček, P. Jungwirth, "Photodissociation of HBr in and on Ar n clusters: the role of the position of the molecule," Physical Chemistry Chemical Physics, vol. 5, no. 16, pp. 3394-401, 2003.
  • P. M. Regan, S. R. Langford, A. J. Orr-Ewing, M. N. Ashfold. "The ultraviolet photodissociation dynamics of hydrogen bromide," The Journal of Chemical Physics, vol. 110, no. 1, pp. 281-8, 1999.
  • V. Belyi, N. Kondratyuk, A. Shagov, A. Mashchenko, "Parametric amplification of light in a BBO crystal with pumping by YAG: Nd laser radiation," Journal of Applied Spectroscopy, vol. 67, pp. 364-8, 2000.
  • K. Semwal, S. Bhatt, "Tuning of wavelengths for producing eye safe laser using second order nonlinear processes," International Journal of Optics and Applications, vol. 2, no. 3, pp. 20-8, 2012.
  • Y. R. Luo, Comprehensive Handbook of Chemical Bond Energies, CRC Press, 2007.
There are 38 citations in total.

Details

Primary Language English
Subjects Mechanical Engineering
Journal Section Research Articles
Authors

Sinan Erdoğan 0000-0001-8844-0761

Early Pub Date October 5, 2023
Publication Date October 18, 2023
Submission Date December 28, 2022
Acceptance Date June 16, 2023
Published in Issue Year 2023

Cite

APA Erdoğan, S. (2023). Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration. Sakarya University Journal of Science, 27(5), 965-974. https://doi.org/10.16984/saufenbilder.1225856
AMA Erdoğan S. Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration. SAUJS. October 2023;27(5):965-974. doi:10.16984/saufenbilder.1225856
Chicago Erdoğan, Sinan. “Production of Hydrogen Molecule from Methane Molecule Amplified With Excitation of Anti-Symmetric Modes of Vibration”. Sakarya University Journal of Science 27, no. 5 (October 2023): 965-74. https://doi.org/10.16984/saufenbilder.1225856.
EndNote Erdoğan S (October 1, 2023) Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration. Sakarya University Journal of Science 27 5 965–974.
IEEE S. Erdoğan, “Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration”, SAUJS, vol. 27, no. 5, pp. 965–974, 2023, doi: 10.16984/saufenbilder.1225856.
ISNAD Erdoğan, Sinan. “Production of Hydrogen Molecule from Methane Molecule Amplified With Excitation of Anti-Symmetric Modes of Vibration”. Sakarya University Journal of Science 27/5 (October 2023), 965-974. https://doi.org/10.16984/saufenbilder.1225856.
JAMA Erdoğan S. Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration. SAUJS. 2023;27:965–974.
MLA Erdoğan, Sinan. “Production of Hydrogen Molecule from Methane Molecule Amplified With Excitation of Anti-Symmetric Modes of Vibration”. Sakarya University Journal of Science, vol. 27, no. 5, 2023, pp. 965-74, doi:10.16984/saufenbilder.1225856.
Vancouver Erdoğan S. Production of Hydrogen Molecule from Methane Molecule Amplified with Excitation of Anti-Symmetric Modes of Vibration. SAUJS. 2023;27(5):965-74.

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