Sol-jel yöntemi ile zirkonyum fosfat ve poli (etilen oksit) temelli polimer kompozit malzeme (ZRP/PEO) sentezi ve karakterizasyonu

Year 2018, Volume: 22 Issue: 2, 748 - 754, 01.04.2018

Asuman Çelik Küçük , Emrah Demirkal

https://doi.org/10.16984/saufenbilder.343027

Cited By: 1

Abstract

Bu çalışmada,  sol-jel
yöntemi ile tetraetil ortosilikat (TEOS) ön başlatıcısı varlığında zirkonyum
fosfat  (ZrP) ve Poli (etilen oksit)
temelli ZrP/ PEO kompozit malzemesi üretilmiştir. Hazırlanan malzemenin yapısı
X-ışını difraksiyonu (XRD) ve Fourier transform IR spektroskopisi (FTIR)
yöntemleri ile incelenmiştir. Isısal özellikleri ise termal gravimetrik analiz
(TGA) ile incelenmiştir. TGA analizinde, sentezlenen malzemenin 300 °C’e kadar
kararlı olduğu bulunmuştur. Üretilen bu malzemenin maliyeti düşüktür, ayrıca
ısıtıldığında 100 °C’nin üzerindeki sıcaklıklarda 300 °C ye kadar bozulmaya
uğramamaktadır. 300 °C’ye kadar olan ısısal kararlılığı ve su tutma kabiliyeti
sayesinde ZrP/PEO kompozit malzemesi, ara sıcaklık yakıt pillerinde
kullanılabilme potansiyeline sahiptir.

Keywords

Zirkonyum ve Poli (etilen oksit) temelli kompozit malzeme, sol-jel

Synthesis and characterization of zirconium phosphate and poly(ethylene oxide) based polymer composite

Abstract

In this study, by using tetraethyl orthosilicate (TEOS) as
precursor, a composite material based on the zirkonium phosphate and poly (ethylene
oksit) (PEO) polymer (ZrP / PEO) has been prepared through the sol-gel method.
The characterisation of the obtained material has been carried out by using
flourer transform–infrared spectroscopy (FTIR) and X-ray diffraction (XRD)
methods. Thermal properties have been investigated with thermal gravimetric
analyzing (TGA). It has been founded that ZrP/PEO polymer composite material is
stable even up to 300 °C. Thanks to the thermal stability and water uptake
ability, ZrP/PEO polymer composite is the promising candidate to be used as a
medium temperature fuel-cell electrolyte material. 

Keywords

Zirkonium and Poly(ethylene oxide) based polymer composite, sol-gel, characterization

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