Research Article
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Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles

Year 2024, Volume: 28 Issue: 2, 353 - 363, 30.04.2024
https://doi.org/10.16984/saufenbilder.1356129

Abstract

Citric acid, which is a type of polycarboxylic acid, is environmentally friendly, and non-harmful and it can be used as a cross-linker. Titanium dioxide (TiO2) nanoparticle is a catalyst that provides many properties for textile products with its large surface area. Present study, a mixture was prepared with different concentrations of citric acid and commercial TiO2 Degussa P25 nanopowder suspensions. Two different curing temperatures (120°C and 140°C) were applied to the cotton fabrics in the pad-dry-cure method. The adhesion of the chemicals to the fiber surface was confirmed by scanning electron microscopy (SEM) and Fourier transform infrared spectrophotometer (FT/IR) analysis. The yellowing effect caused by citric acid on cotton fabrics was eliminated with white TiO2 nanoparticles. Methylene blue was used for staining the samples. Color analyses were performed with a spectrophotometer to determine photocatalytic properties of the samples. It was determined that the samples treated with a mixture of 30 g/L citric acid and TiO2 suspensions were the most discolored samples after exposure to solar light. The photocatalyst properties of the samples were further improved by removing the aggregation of TiO2 NPs on the fiber surface with the washing procedure.

Supporting Institution

This work was supported by the Cukurova University/Adana/TURKEY with FBA-2022-14649 project number.

References

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  • [19] Y. Lu, Q. Yang, “Fabric yellowing caused by citric acid as a crosslinking agent for cotton,” Textile Research Journal, vol. 69, no. 9, pp. 685-690, 1999.
  • [20] W. Yao, B. Wang, T. Ye, Y. Yang, “Durable press finishing of cotton fabrics with citric acid: enhancement of whiteness and wrinkle recovery by polyol extenders,” Industrial & Engineering Chemistry Research, vol. 52, pp.16118-16127, 2013.
  • [21] P. Tang, B. Ji, G. Sun, “Whiteness improvement of citric acid crosslinked cotton fabrics: H2O2 bleaching under alkaline condition,” Carbohydrate Polymers, vol. 147, pp.139-145, 2016.
  • [22] A. Haji, H. Barani, S. S. Qavamina, “Ag/TiO2 nanocomposite on cotton fabric,” 5th Texteh International Conference Bucharest, Romania, 18-19 October, 2012.
  • [23] K. Saeed, I. Khan, T. Gul, M. Sadiq, “Efficient photodegradation of methyl violet dye using TiO2/Pt and TiO2/Pd photocatalysts,” Applied Water Science, vol. 7, pp. 3841–3848, 2017.
  • [24] T. E. Saraswati, I. F. Andhika, Patiha, C. Purnawan, S. Wahyuningsih, M. Anwar, “Photocatalytic degradation of methylene blue using TiO2/carbon nanoparticles fabricated by electrical arc discharge in liquid medium,” Advanced Material Research, vol. 1123, pp. 285–288, 2015.
  • [25] F. Akbal, “Photocatalytic degradation of organic dyes in the presence of titanium dioxide under UV and solar light: effect of operational parameters,” Environmental Progress., vol. 24, no. 3, p. 317-322, 2005.
  • [26] A. Abou-Okeil, R. A. A. Eid, A. Amr, “Multi-functional cotton fabrics using nano-technology and environmentally friendly finishing agents,” Egyptian Journal of Chemistry, vol.60, pp. 161- 169, 2017.
  • [27] H. Wang, C. Zhang, X. Chu, P. Zhu, “Mechanism of antiwrinkle finishing of cotton fabrics using mixed polycarboxylic acids,” International Journal of Polymer Science, pp. 1-10, 2020.
  • [28] Y. S. Chung, K. K. Lee, J. W. Kim, “Durable press and antimicrobial finishing of cotton fabrics with a citric acid and chitosan treatment,” Textile Research Journal, vol. 68, no. 10, pp. 772-775, 1998.
Year 2024, Volume: 28 Issue: 2, 353 - 363, 30.04.2024
https://doi.org/10.16984/saufenbilder.1356129

Abstract

References

  • [1] B. Rani, A. K. Nayak, N. K. Sahu, “Fundamentals principle of photocatalysis”, In: Nanostructured Materials for Visible Light Photocatalysis. Amsterdam: Elsevier Inc, 2022, pp. 1-22.
  • [2] F. Parrino, F. R. Pomilla, G. Camera-Roda, V. Loddo, L, Palmisano, “Properties of titanium dioxide. In:Titanium Dioxide (TiO2) and Its Applications,” Netherlands: Elsevier Inc., 2021, pp. 13-62.
  • [3] M. A. K. L. Diasanayake, G. K. R. Senadeera, H. N. M. Sarangika, P. M. P. C. Ekanayake, C. A. Thorawattage, H. K. D. W. M. N. R. Divarathne, J. M. K. W Kumari, “TiO2 as a low cost, multi functional material,” 5th International Conference on Functional Materials & Devices (ICFMD 2015). Materials Today: Proceedings 3S., 2016, pp. 40 - 47.
  • [4] Y. Zhaodan, “Application of titanium dioxide nano-particles on textile modification,” Advanced Materials Research Vols., vol.821-822, pp. 901-905, 2013.
  • [5] M. Radetiĉ, “Functionalization of textile materials with TiO2 nanoparticles,” Journal of Photochemistry and Photobiology C: Photochemistry Reviews, vol. 16, pp. 62–76, 2013.
  • [6] S. Mallakpour, N. Jarang, “Production of bionanocomposites based on poly(vinyl pyrrolidone) using modified TiO2 nanoparticles with citric acid and ascorbic acid and study of their physicochemical properties” Polymer Bulletin, vol.75, pp. 1441–1456, 2018.
  • [7] I. A. Mudunkotuwa, V. H. Grassian, “Citric Acid Adsorption on TiO2 Nanoparticles in Aqueous Suspensions at Acidic and Circumneutral pH: Surface Coverage, Surface Speciation, and Its Impact on Nanoparticle-Nanoparticle Interactions”, Journal of the American Chemical Society, vol. 132, pp. 14986-14994, 2010.
  • [8] S. Hashemikia, M. Montazer, “Sodium hypophosphite and nano TiO2 inorganic catalysts along with citric acid on textile producing multi-functional properties,” Carbonhydrate Polymers, vol. 147, pp. 139-145, 2016.
  • [9] D. K. Maharani, M. M. S. Basukiwardoyo, S. T. Alawiyah, Rusmini, “The Study of self-cleaning properties of TiO2 coated on cotton fabrics. Mathematics,” Informatics, Science, and Education International Conference (MISEIC 2019). Advances in Computer Science Research, vol. 95, pp. 48-50, 2019.
  • [10] A. A. Okeil, “Citric acid crosslinking of cellulose using TiO2 catalyst by pad-dry-cure method,” Polymer-Plastics Technology and Engineering, vol. 47, pp.174–179, 2008.
  • [11] M. T. Noman, M. A. Ashraf, A. Ali “Synthesis and applications of nano-TiO2: a review,” Environmental Science and Pollution Research, vol. 26, pp. 3262–3291, 2019.
  • [12] S. Lebrette, C. Pagnoux, P. Abélard, “Stability of aqueous TiO2 suspensions: influence of ethanol,” Journal of Colloid and Interface Science, vol. 280, pp. 400–408, 2004.
  • [13] I. Khan, K. Saeed, I. Zekker, , B. Zhang, A. H. Hendi, A. Ahmad, S. Ahmad, N. Zada, H. Ahmad, L. A. Shah, T. Shah, I. Khan, “Review on Methylene Blue: Its Properties, uses, toxicity and photodegradation,” Water, vol. 14, no. 242, pp. 1-30, 2022.
  • [14] P. R. Ginimuge, S. D. Jyothi, “Methylene Blue: Revisited,” Journal of Anaesthesiology Clinical Pharmacology, vol. 26, no.4, pp. 517-520, 2010.
  • [15] M. Orhan, D. Kut, C. Gunesoglu, “Improving the antibacterial activity of cotton fabrics finished with triclosan by the use of 1,2,3,4- butanetetracarboxylic acid and citric acid,” Journal of Applied Polymer Science, vol. 111, no. 3, pp.1344-1352, 2008.
  • [16] W. Zou, H. Bai, S. Gao, X. Zhao, R. Han “Investigations on the batch performance of cationic dyes adsorption by citric acid modified peanut husk,” Desalination and Water Treatment, vol. 49, pp. 41-56, 2012.
  • [17] A. Haji, S. M. Bidoki, F. Gholami “Isotherm and kinetic studies in dyeing of citric acid-crosslinked cotton with cationic natural dye,” Fibers and Polymers, vol. 21, no.11, p. 2547-2555, 2020.
  • [18] A. León, P. Reuquen, C. Garin, R. Segura, P. Vargas, P. Zapata, P. A. Orihuela, “FTIR and raman characterization of TiO2 nanoparticles coated with polyethylene glycol as carrier for 2-methoxyestradiol,” Applied Sciences, vol. 49, no. 7, pp. 1-9, 2017.
  • [19] Y. Lu, Q. Yang, “Fabric yellowing caused by citric acid as a crosslinking agent for cotton,” Textile Research Journal, vol. 69, no. 9, pp. 685-690, 1999.
  • [20] W. Yao, B. Wang, T. Ye, Y. Yang, “Durable press finishing of cotton fabrics with citric acid: enhancement of whiteness and wrinkle recovery by polyol extenders,” Industrial & Engineering Chemistry Research, vol. 52, pp.16118-16127, 2013.
  • [21] P. Tang, B. Ji, G. Sun, “Whiteness improvement of citric acid crosslinked cotton fabrics: H2O2 bleaching under alkaline condition,” Carbohydrate Polymers, vol. 147, pp.139-145, 2016.
  • [22] A. Haji, H. Barani, S. S. Qavamina, “Ag/TiO2 nanocomposite on cotton fabric,” 5th Texteh International Conference Bucharest, Romania, 18-19 October, 2012.
  • [23] K. Saeed, I. Khan, T. Gul, M. Sadiq, “Efficient photodegradation of methyl violet dye using TiO2/Pt and TiO2/Pd photocatalysts,” Applied Water Science, vol. 7, pp. 3841–3848, 2017.
  • [24] T. E. Saraswati, I. F. Andhika, Patiha, C. Purnawan, S. Wahyuningsih, M. Anwar, “Photocatalytic degradation of methylene blue using TiO2/carbon nanoparticles fabricated by electrical arc discharge in liquid medium,” Advanced Material Research, vol. 1123, pp. 285–288, 2015.
  • [25] F. Akbal, “Photocatalytic degradation of organic dyes in the presence of titanium dioxide under UV and solar light: effect of operational parameters,” Environmental Progress., vol. 24, no. 3, p. 317-322, 2005.
  • [26] A. Abou-Okeil, R. A. A. Eid, A. Amr, “Multi-functional cotton fabrics using nano-technology and environmentally friendly finishing agents,” Egyptian Journal of Chemistry, vol.60, pp. 161- 169, 2017.
  • [27] H. Wang, C. Zhang, X. Chu, P. Zhu, “Mechanism of antiwrinkle finishing of cotton fabrics using mixed polycarboxylic acids,” International Journal of Polymer Science, pp. 1-10, 2020.
  • [28] Y. S. Chung, K. K. Lee, J. W. Kim, “Durable press and antimicrobial finishing of cotton fabrics with a citric acid and chitosan treatment,” Textile Research Journal, vol. 68, no. 10, pp. 772-775, 1998.
There are 28 citations in total.

Details

Primary Language English
Subjects Materials Engineering (Other)
Journal Section Research Articles
Authors

Sabiha Sezgin Bozok 0000-0002-8464-0405

Early Pub Date April 24, 2024
Publication Date April 30, 2024
Submission Date September 6, 2023
Acceptance Date January 3, 2024
Published in Issue Year 2024 Volume: 28 Issue: 2

Cite

APA Sezgin Bozok, S. (2024). Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles. Sakarya University Journal of Science, 28(2), 353-363. https://doi.org/10.16984/saufenbilder.1356129
AMA Sezgin Bozok S. Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles. SAUJS. April 2024;28(2):353-363. doi:10.16984/saufenbilder.1356129
Chicago Sezgin Bozok, Sabiha. “Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified With TiO2 Degussa P25 Nanoparticles”. Sakarya University Journal of Science 28, no. 2 (April 2024): 353-63. https://doi.org/10.16984/saufenbilder.1356129.
EndNote Sezgin Bozok S (April 1, 2024) Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles. Sakarya University Journal of Science 28 2 353–363.
IEEE S. Sezgin Bozok, “Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles”, SAUJS, vol. 28, no. 2, pp. 353–363, 2024, doi: 10.16984/saufenbilder.1356129.
ISNAD Sezgin Bozok, Sabiha. “Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified With TiO2 Degussa P25 Nanoparticles”. Sakarya University Journal of Science 28/2 (April 2024), 353-363. https://doi.org/10.16984/saufenbilder.1356129.
JAMA Sezgin Bozok S. Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles. SAUJS. 2024;28:353–363.
MLA Sezgin Bozok, Sabiha. “Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified With TiO2 Degussa P25 Nanoparticles”. Sakarya University Journal of Science, vol. 28, no. 2, 2024, pp. 353-6, doi:10.16984/saufenbilder.1356129.
Vancouver Sezgin Bozok S. Ensuring Photocatalyst Properties on Cellulosic Fabric by Using Citric Acid Modified with TiO2 Degussa P25 Nanoparticles. SAUJS. 2024;28(2):353-6.