Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması

Ayça Demirel Özel; Semra Muratoğlu; H. Elif Kormalı Ertürün

doi:10.19113/sdufbed.82321

Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması

Abstract

Dibromo[1,1′-bis(difenilfosfin)ferrosen] paladyum(II) (iyonofor I) ve dikloro[1,1′-bis(difenilfosfin)ferrosen] paladyum(II) (iyonofor II) olarak adlandırılan paladyum komplekslerinin kullanıldığı yeni iyodür-seçici karbon pasta elektrotlar hazırlandı. İyonofor I ve II kullanılarak optimum karbon pasta bileşimiyle hazırlanan elektrotların pH 4,0’da sırasıyla −43,2 ± 0,6 mV/pI ve −43,8 ± 0,6 mV/pI eğimle, 3,5×10⁻⁶M ve 3,7×10⁻⁷M gözlenebilme sınırıyla, 1,0×10⁻⁵− 1,0×10⁻¹ M ve 1,0×10⁻⁶− 1,0×10⁻¹ M derişim aralığında doğrusal cevap verdikleri gözlendi. Önerilen elektrotların kısa cevap sürelerine, 3 aylık ömre, iyi bir tekrarlanabilirlik ve üretilebilirliğe sahip oldukları bulundu. Ayrıca, elektrotlar, iyodür içeren ilaç numunelerinde iyodürün potansiyometrik tayini için indikatör elektrot olarak başarılı bir şekilde kullanıldı.

Keywords

Karbon pasta elektrot,İyodür-seçici elektrot; Potansiyometri; Paladyum kompleksleri

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Details

Primary Language

Turkish

Subjects

-

Journal Section

-

Authors

Ayça Demirel Özel

Semra Muratoğlu This is me

H. Elif Kormalı Ertürün This is me

Publication Date

April 16, 2018

Submission Date

February 27, 2017

Acceptance Date

-

Published in Issue

Year 2018 Volume: 22 Number: 1

DOI

https://doi.org/10.19113/sdufbed.82321

IZ

https://izlik.org/JA42ZY46JZ

Cite

RIS / Bibtex

APA

Demirel Özel, A., Muratoğlu, S., & Kormalı Ertürün, H. E. (2018). Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(1), 237-246. https://doi.org/10.19113/sdufbed.82321

AMA

1.Demirel Özel A, Muratoğlu S, Kormalı Ertürün HE. Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. J. Nat. Appl. Sci. 2018;22(1):237-246. doi:10.19113/sdufbed.82321

Chicago

Demirel Özel, Ayça, Semra Muratoğlu, and H. Elif Kormalı Ertürün. 2018. “Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 (1): 237-46. https://doi.org/10.19113/sdufbed.82321.

EndNote

Demirel Özel A, Muratoğlu S, Kormalı Ertürün HE (April 1, 2018) Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 1 237–246.

IEEE

[1]A. Demirel Özel, S. Muratoğlu, and H. E. Kormalı Ertürün, “Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması”, J. Nat. Appl. Sci., vol. 22, no. 1, pp. 237–246, Apr. 2018, doi: 10.19113/sdufbed.82321.

ISNAD

Demirel Özel, Ayça - Muratoğlu, Semra - Kormalı Ertürün, H. Elif. “Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22/1 (April 1, 2018): 237-246. https://doi.org/10.19113/sdufbed.82321.

JAMA

1.Demirel Özel A, Muratoğlu S, Kormalı Ertürün HE. Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. J. Nat. Appl. Sci. 2018;22:237–246.

MLA

Demirel Özel, Ayça, et al. “Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 22, no. 1, Apr. 2018, pp. 237-46, doi:10.19113/sdufbed.82321.

Vancouver

1.Ayça Demirel Özel, Semra Muratoğlu, H. Elif Kormalı Ertürün. Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. J. Nat. Appl. Sci. 2018 Apr. 1;22(1):237-46. doi:10.19113/sdufbed.82321

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Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi

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