Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi 0.4 Mn 0.4 Co 0.2 O 2 Lithium-ion Battery Cathode Material

Muharrem Kunduracı

Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material

Abstract

Nano-sized LiNi_0.4Mn_0.4Co_0.2O₂ lithium-ion battery cathode materials with and without dual Mg & Al doping were synthesized by Pechini method. The powdered materials were characterized using X-ray diffraction, scanning electron microscopy and electrochemical techniques. X-ray analyses showed that 003/104 peaks intensity ratio increased from 0.95 for undoped material to 1.27 for doped material, thereby suggesting that dual doping was beneficial in terms reducing Li/Ni cation mixing. Although dual doping caused some reduction in initial discharge capacity (140 vs. 128 mAh/g) and increase in charge transfer resistance relative to the undoped material, it noticeably helped increase capacity retention during battery testing at high voltage.

Keywords

Lithium-ion batteries,Cathode; High voltage; Doping

References

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Details

Primary Language

Turkish

Subjects

-

Journal Section

-

Authors

Muharrem Kunduracı

Publication Date

August 15, 2018

Submission Date

February 12, 2018

Acceptance Date

-

Published in Issue

Year 2018 Volume: 22 Number: 2

IZ

https://izlik.org/JA62HL94WT

Cite

RIS / Bibtex

APA

Kunduracı, M. (2018). Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(2), 577-582. https://izlik.org/JA62HL94WT

AMA

1.Kunduracı M. Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material. J. Nat. Appl. Sci. 2018;22(2):577-582. https://izlik.org/JA62HL94WT

Chicago

Kunduracı, Muharrem. 2018. “Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-Ion Battery Cathode Material”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 (2): 577-82. https://izlik.org/JA62HL94WT.

EndNote

Kunduracı M (August 1, 2018) Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 2 577–582.

IEEE

[1]M. Kunduracı, “Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material”, J. Nat. Appl. Sci., vol. 22, no. 2, pp. 577–582, Aug. 2018, [Online]. Available: https://izlik.org/JA62HL94WT

ISNAD

Kunduracı, Muharrem. “Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-Ion Battery Cathode Material”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22/2 (August 1, 2018): 577-582. https://izlik.org/JA62HL94WT.

JAMA

1.Kunduracı M. Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material. J. Nat. Appl. Sci. 2018;22:577–582.

MLA

Kunduracı, Muharrem. “Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-Ion Battery Cathode Material”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 22, no. 2, Aug. 2018, pp. 577-82, https://izlik.org/JA62HL94WT.

Vancouver

1.Muharrem Kunduracı. Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi0.4Mn0.4Co0.2O2 Lithium-ion Battery Cathode Material. J. Nat. Appl. Sci. [Internet]. 2018 Aug. 1;22(2):577-82. Available from: https://izlik.org/JA62HL94WT

Effect of Mg and Al Dual Doping on High Voltage Cycling of LiNi<sub>0.4</sub>Mn<sub>0.4</sub>Co<sub>0.2</sub>O<sub>2</sub> Lithium-ion Battery Cathode Material