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Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri

Year 2018, Volume: 22 Issue: 2, 1016 - 1021, 15.08.2018

Cengiz Okay Cihat Boyraz Dimitri A. Shulgın Georgy Mozzhukhın Bulat Rameev

Abstract

Birçok sülfat tuzu mineralleri arasında, tetrahedrit/tennantit grubu, termoelektrik ve fotovoltaik gibi ileri teknoloji uygulamalarında umut verici bir yere sahip olduğundan dolayı araştırmacıların ilgisini çekmektedir. Bu çalışmada katıhal reaksiyon metodu hazırlanmış ve ayrı ayrı vakumlu kuartz tüplere kapatılmış (Cu12Sb4S13) tetrahedrit ana malzemesi, %50Sb %50As tetrahedrit/tennantit bileşiği (Cu12As2Sb2S13) ve Cu12Sb4S13 ana malzemesindeki Cu elementi yerine kısmi olarak Fe katkılanan bileşiğinin (Cu10Fe2Sb4S13) yapısal karakteristikleri X-ışını kırımı tekniği (XRD) analiz edilmiştir. Oluşan bileşiklerin morfolojileri taramalı elektron mikroskobu (SEM) ile görüntülenmiş ve buna bağlı enerji dağıtıcı X-ışını spektrometresi (EDX) ile oluşan kompozisyonun element oranlarının analizleri yapılmıştır. Bu bileşiklerin ayrıca manyetik özellikleri, titreşimli örnek manyetik ölçüm tekniği (VSM) ile incelenerek belirlenmiştir. Tüm örnekler paramanyetik özellik göstermekte olup manyetik moment eğrilerinde Curie yasası ile uyumlu davranış gözlemlenmiştir.

Keywords

Tetrahedrit/tennantit Sinterleme aşaması; Yapısal ve manyetik özellikler

References

  • [1] Matsubara, K. 2002. Development of a high efficient thermoelectric stack for a waste exhaust heat recovery of vehicles. Thermoelectrics, 7803, 418-423.
  • [2] Allen, H., Chen, R., Diaz, D. R., Liang, W., Garnett, E. C., Mark, N., Majumdar, A., Peidong, Y. 2008. Enhanced thermoelectric performance of rough silicon nanowires. Nature, 451, 163–7.
  • [3] Snyder, G.J., Toberer, E.S., 2008. Complex thermoelectric materials. Nature materials, 7(2), 105.
  • [4] Rowe, D. M., Raton, B. 2005. CRC Handbook of Thermoelectrics. Macro to Nano Newyok Yayınları.
  • [5] Ramasamy, K., Sims, H., Butler, W.H., Gupta, A., 2014. Selective nanocrystal synthesis and calculated electronic structure of all four phases of copper–antimony–sulfide. Chemistry of Materials, 26(9), 2891-2899.
  • [6] Lu, X., Morelli, D.T., Xia, Y., Zhou, F., Ozolins, V., Chi, H., Zhou, X., Uher, C., 2013. High performance thermoelectricity in earth‐abundant compounds based on natural mineral tetrahedrites. Advanced Energy Materials, 3(3), 342-348.
  • [7] Lu, X., Morelli, D.T., 2013. Natural mineral tetrahedrite as a direct source of thermoelectric materials. Physical Chemistry Chemical Physics, 15(16), 5762-5766.
  • [8] James, D.J., Lu, X., Morelli, D.T., Brock, S.L., 2015. Solvothermal synthesis of tetrahedrite: Speeding up the process of thermoelectric material generation. ACS applied materials & interfaces, 7(42), 23623-23632.
  • [9] Johnson, N.E., Craig, J.R., Rimstidt, J.D., 1986. Compositional trends in tetrahedrite. The Canadian Mineralogist, 24(2), pp.385-397.
  • [10] Seal, R.R., Essene, E.J., Kelly, W.C., 1990. Tetrahedrite and tennantite; evaluation of thermodynamic data and phase equilibria. The Canadian Mineralogist, 28(4), 725-738.
  • [11] Barbier, T., Lemoine, P., Gascoin, S. 2015. Structural stability of the synthetic thermoelectric ternary and nickel-substituted tetrahedrite phases. Journal of Alloys and Compounds, 634, 253-262.
  • [12] Lu, X., Morelli, D. T. 2013. Natural mineral tetrahedrite as a direct source of thermoelectric materials. Physical Chemistry Chemical Physics, 15, 5762-5766 5 p.
  • [13] Lai, W., Wang, Y., Morelli, D.T., Lu, X., 2015. From bonding asymmetry to anharmonic rattling in Cu12Sb4S13 tetrahedrites: When lone‐pair electrons are not so lonely. Advanced Functional Materials, 25(24), 3648-3657.
  • [14] Lu, X., Morelli, D.T., Xia, Y., Zhou, F., Ozolins, V., Chi, H., Zhou, X., Uher, C., 2013. High performance thermoelectricity in earth‐abundant compounds based on natural mineral tetrahedrites. Advanced Energy Materials, 3(3), 342-348.
  • [15] Guler, A., Boyraz, C., 2017. The Pt dopant effect on physical properties of Ba0. 2La0. 8Fe2As2. Journal of Superconductivity and Novel Magnetism, 30(11), 3285-3288.
  • [16] Boyraz, C., Guler, A., Ozdemir, M., Oner, Y., 2017. Structural and superconductivity properties of BaFe 2− x Pt x As 2. Journal of Superconductivity and Novel Magnetism, 30(5), 1145-1151.
  • [17] Boyraz, C., Guler, A., Oner, Y., 2018. Electronic, Transport, and Magnetic Properties of La-Doped Ba1− xFe1. 9Pt0. 1As2 (x= 0, 0.4, 0.6, 0.8) Compounds. Journal of Superconductivity and Novel Magnetism, 31(1), 47-53.
  • [18] Sertkol, M. Ballıkaya, S. Aydoğdu, F. Güler, A. Özdemir, M. Öner, Y. 2017. Thermoelectric and Magnetic Properties of Pt-Substituted BaFe4-xPtxSb12 Compounds. Journal of Electronic Materials, 46(1), 73-78.
  • [19] Barbier, T., Lemoine, P., Gascoin, S., Lebedev, O.I., Kaltzoglou, A., Vaqueiro, P., Powell, A.V., Smith, R.I., Guilmeau, E., 2015. Structural stability of the synthetic thermoelectric ternary and nickel-substituted tetrahedrite phases. Journal of Alloys and Compounds, 634, 253-262.

Year 2018, Volume: 22 Issue: 2, 1016 - 1021, 15.08.2018

Cengiz Okay Cihat Boyraz Dimitri A. Shulgın Georgy Mozzhukhın Bulat Rameev

Abstract

References

  • [1] Matsubara, K. 2002. Development of a high efficient thermoelectric stack for a waste exhaust heat recovery of vehicles. Thermoelectrics, 7803, 418-423.
  • [2] Allen, H., Chen, R., Diaz, D. R., Liang, W., Garnett, E. C., Mark, N., Majumdar, A., Peidong, Y. 2008. Enhanced thermoelectric performance of rough silicon nanowires. Nature, 451, 163–7.
  • [3] Snyder, G.J., Toberer, E.S., 2008. Complex thermoelectric materials. Nature materials, 7(2), 105.
  • [4] Rowe, D. M., Raton, B. 2005. CRC Handbook of Thermoelectrics. Macro to Nano Newyok Yayınları.
  • [5] Ramasamy, K., Sims, H., Butler, W.H., Gupta, A., 2014. Selective nanocrystal synthesis and calculated electronic structure of all four phases of copper–antimony–sulfide. Chemistry of Materials, 26(9), 2891-2899.
  • [6] Lu, X., Morelli, D.T., Xia, Y., Zhou, F., Ozolins, V., Chi, H., Zhou, X., Uher, C., 2013. High performance thermoelectricity in earth‐abundant compounds based on natural mineral tetrahedrites. Advanced Energy Materials, 3(3), 342-348.
  • [7] Lu, X., Morelli, D.T., 2013. Natural mineral tetrahedrite as a direct source of thermoelectric materials. Physical Chemistry Chemical Physics, 15(16), 5762-5766.
  • [8] James, D.J., Lu, X., Morelli, D.T., Brock, S.L., 2015. Solvothermal synthesis of tetrahedrite: Speeding up the process of thermoelectric material generation. ACS applied materials & interfaces, 7(42), 23623-23632.
  • [9] Johnson, N.E., Craig, J.R., Rimstidt, J.D., 1986. Compositional trends in tetrahedrite. The Canadian Mineralogist, 24(2), pp.385-397.
  • [10] Seal, R.R., Essene, E.J., Kelly, W.C., 1990. Tetrahedrite and tennantite; evaluation of thermodynamic data and phase equilibria. The Canadian Mineralogist, 28(4), 725-738.
  • [11] Barbier, T., Lemoine, P., Gascoin, S. 2015. Structural stability of the synthetic thermoelectric ternary and nickel-substituted tetrahedrite phases. Journal of Alloys and Compounds, 634, 253-262.
  • [12] Lu, X., Morelli, D. T. 2013. Natural mineral tetrahedrite as a direct source of thermoelectric materials. Physical Chemistry Chemical Physics, 15, 5762-5766 5 p.
  • [13] Lai, W., Wang, Y., Morelli, D.T., Lu, X., 2015. From bonding asymmetry to anharmonic rattling in Cu12Sb4S13 tetrahedrites: When lone‐pair electrons are not so lonely. Advanced Functional Materials, 25(24), 3648-3657.
  • [14] Lu, X., Morelli, D.T., Xia, Y., Zhou, F., Ozolins, V., Chi, H., Zhou, X., Uher, C., 2013. High performance thermoelectricity in earth‐abundant compounds based on natural mineral tetrahedrites. Advanced Energy Materials, 3(3), 342-348.
  • [15] Guler, A., Boyraz, C., 2017. The Pt dopant effect on physical properties of Ba0. 2La0. 8Fe2As2. Journal of Superconductivity and Novel Magnetism, 30(11), 3285-3288.
  • [16] Boyraz, C., Guler, A., Ozdemir, M., Oner, Y., 2017. Structural and superconductivity properties of BaFe 2− x Pt x As 2. Journal of Superconductivity and Novel Magnetism, 30(5), 1145-1151.
  • [17] Boyraz, C., Guler, A., Oner, Y., 2018. Electronic, Transport, and Magnetic Properties of La-Doped Ba1− xFe1. 9Pt0. 1As2 (x= 0, 0.4, 0.6, 0.8) Compounds. Journal of Superconductivity and Novel Magnetism, 31(1), 47-53.
  • [18] Sertkol, M. Ballıkaya, S. Aydoğdu, F. Güler, A. Özdemir, M. Öner, Y. 2017. Thermoelectric and Magnetic Properties of Pt-Substituted BaFe4-xPtxSb12 Compounds. Journal of Electronic Materials, 46(1), 73-78.
  • [19] Barbier, T., Lemoine, P., Gascoin, S., Lebedev, O.I., Kaltzoglou, A., Vaqueiro, P., Powell, A.V., Smith, R.I., Guilmeau, E., 2015. Structural stability of the synthetic thermoelectric ternary and nickel-substituted tetrahedrite phases. Journal of Alloys and Compounds, 634, 253-262.
There are 19 citations in total.

Details

Journal Section Articles
Authors

Cengiz Okay

Cihat Boyraz

Dimitri A. Shulgın This is me

Georgy Mozzhukhın This is me

Bulat Rameev This is me

Publication Date August 15, 2018
Published in Issue Year 2018 Volume: 22 Issue: 2

Cite

APA Okay, C., Boyraz, C., Shulgın, D. A., Mozzhukhın, G., et al. (2018). Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22(2), 1016-1021.
AMA Okay C, Boyraz C, Shulgın DA, Mozzhukhın G, Rameev B. Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri. SDÜ Fen Bil Enst Der. August 2018;22(2):1016-1021.
Chicago Okay, Cengiz, Cihat Boyraz, Dimitri A. Shulgın, Georgy Mozzhukhın, and Bulat Rameev. “Fe Ve As Elementleri Ile Katkılı Tetrahedritlerin Karakterizasyonu Ve Fiziksel Özellikleri”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22, no. 2 (August 2018): 1016-21.
EndNote Okay C, Boyraz C, Shulgın DA, Mozzhukhın G, Rameev B (August 1, 2018) Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 2 1016–1021.
IEEE C. Okay, C. Boyraz, D. A. Shulgın, G. Mozzhukhın, and B. Rameev, “Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri”, SDÜ Fen Bil Enst Der, vol. 22, no. 2, pp. 1016–1021, 2018.
ISNAD Okay, Cengiz et al. “Fe Ve As Elementleri Ile Katkılı Tetrahedritlerin Karakterizasyonu Ve Fiziksel Özellikleri”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22/2 (August 2018), 1016-1021.
JAMA Okay C, Boyraz C, Shulgın DA, Mozzhukhın G, Rameev B. Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri. SDÜ Fen Bil Enst Der. 2018;22:1016–1021.
MLA Okay, Cengiz et al. “Fe Ve As Elementleri Ile Katkılı Tetrahedritlerin Karakterizasyonu Ve Fiziksel Özellikleri”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 22, no. 2, 2018, pp. 1016-21.
Vancouver Okay C, Boyraz C, Shulgın DA, Mozzhukhın G, Rameev B. Fe ve As Elementleri ile Katkılı Tetrahedritlerin Karakterizasyonu ve Fiziksel Özellikleri. SDÜ Fen Bil Enst Der. 2018;22(2):1016-21.
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