Pseudo-ternary piezoelectric ceramics of PMN-PT [Pb(Mg1/3Nb2/3)O3-PbTiO3] composition
modified with PMS [Pb(Mn1/3Sb2/3)O3] were produced by solid-state sintering method using different
temperatures in a range of 1100-1250 °C. The effect of sintering temperature on the crystal phases,
microstructure and electrical properties were systematically investigated. Microstructural and
compositional analyses have been carried out using scanning electron microscope (SEM) and X-ray
diffraction (XRD). Besides, electrical characterization was performed using an inductance-capacitanceresistance
(LCR) meter, impedance analyzer and a Berlincourt d33-piezometer. XRD and SEM results
indicated that the sintering temperature was effective on the formation of a homogeneous
microstructure and a pure perovskite structure. Densification during sintering could not be completed
and pure perovskite structure was not o tained at 1150 °C and lower sintering temperatures.
Furthermore, sintering at temperatures higher than 1200 °C resulted in heterogeneous microstructure.
The high dielectric and piezoelectric response of PMN-PT-PMS ceramics is considered to be a result of
their high densities and homogeneous microstructure obtained via proper sintering condition. The
results showed that the ceramic samples sintered at 1175 °C for 2 h possessed the optimum properties
(d33=265 pC/N, KT=4745, kp=0.417, tanδ=2.5%, Qm=222).
Primary Language | Turkish |
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Subjects | Engineering |
Journal Section | Articles |
Authors | |
Publication Date | June 1, 2017 |
Published in Issue | Year 2017 Volume: 5 Issue: 2 |