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Optimizing Structural and Electrical Properties of PMN-PT-PMS Ceramics via Sintering Temperature

Yıl 2017, Cilt: 5 Sayı: 2, 144 - 152, 01.06.2017
https://doi.org/10.15317/Scitech.2017.78

Öz

Pseudo-ternary piezoelectric ceramics of PMN-PT [Pb(Mg1/3Nb2/3)O3-PbTiO3] composition

modified with PMS [Pb(Mn1/3Sb2/3)O3] were produced by solid-state sintering method using different

temperatures in a range of 1100-1250 °C. The effect of sintering temperature on the crystal phases,

microstructure and electrical properties were systematically investigated. Microstructural and

compositional analyses have been carried out using scanning electron microscope (SEM) and X-ray

diffraction (XRD). Besides, electrical characterization was performed using an inductance-capacitanceresistance

(LCR) meter, impedance analyzer and a Berlincourt d33-piezometer. XRD and SEM results

indicated that the sintering temperature was effective on the formation of a homogeneous

microstructure and a pure perovskite structure. Densification during sintering could not be completed

and pure perovskite structure was not o tained at 1150 °C and lower sintering temperatures.

Furthermore, sintering at temperatures higher than 1200 °C resulted in heterogeneous microstructure.

The high dielectric and piezoelectric response of PMN-PT-PMS ceramics is considered to be a result of

their high densities and homogeneous microstructure obtained via proper sintering condition. The

results showed that the ceramic samples sintered at 1175 °C for 2 h possessed the optimum properties

(d33=265 pC/N, KT=4745, kp=0.417, tanδ=2.5%, Qm=222).

Kaynakça

  • Aydın H.S., 2016, PMN-PT[Pb(Mg1/3Nb2/3)O3-PbTiO3] Esaslı Piezoelektrik Seramiklerin Üretimi ve Karakterizasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
  • Aydın H.S., Kalem V., 2016, ‚PMN-PT [Pb(Mg1/3Nb2/3)O3-PbTiO3] Esaslı Seramiklerde Kompozisyonun Yapısal ve Elektriksel Özelliklere Etkisi‛, Selçuk Üniversitesi Mühendislik Bilim ve Teknoloji Dergisi, Vol. 4, No. 2, pp. 100-110.
  • Bouquin, O., Lejeune, M., Boilot, J.P., 1991, ‚Formation of The Perovskite Phase in the PbMg1/3Nb2/3O3- PbTiO3 system‛, Journal of the American Ceramic Society, Vol.74, No. 5, pp. 1152-56.
  • Carter, C.B., Norton, M.G., 2007, Ceramic Materials: Science and Engineering, Springer, New York.
  • Choi, S.W., Shrout, T.R., Jang, S.J., Bhalla, A.S., 1989, ‚Dielectric and Pyroelectric Properties in The Pb(Mg1/3Nb2/3)O3-PbTiO3 system‛, Ferroelectrics, Vol. 100, pp. 29-38.
  • Guha, J.P., 1999, ‚Reaction Chemistry and Subsolidus Phase Equilibria in Lead-based Relaxor Systems: Part I - Formation and Stability of The Perovskite and Pyrochlore Compounds in The System PbO-MgO-Nb2O5‛, Journal of Materials Science, Vol. 34, No. 20, pp. 4985-94.
  • Hai, L., Bo-Ping, Z., Yu, P., Lei, Z., Kai-sheng, W., Yan-tao, L., 2015, ‚Effects of Sintering Temperature on Structure and Properties of BY-PT-PMN Ternary Piezoelectric Ceramics‛, Journal of Materials Research, Vol. 30, No. 6, pp. 782-790.
  • Hoffmann, M.J., Hammer M., Endriss A., Lupascu D.C., 2001, ‚Correlation Between Microstructure, Strain Behavior, and Acoustic Emission of Soft PZT Ceramics‛, Acta Materialia, Vol.49, pp. 1301–1310.
  • Inada, M., 1977, ‚Analysis of The Formation Process of the Piezoelectric PCM Ceramics‛, National Technical Report (Matsushita Elect. Ind. Co.), Vol. 27, No. 1, pp. 95-102.
  • Ketsuwan, P., Ngamjarurojana, A., Laosiritaworn, Y., Ananta, S., Yimnirun, R., 2007, ‚Effect of Sintering Temperature on Phase Formation, Dielectric, Piezoelectric, and Ferroelectric Properties of Nb- Doped Pb(Zr0.52Ti0.48)O3 Ceramics‛, Ferroelectrics, Vol. 358, pp. 35-41.
  • Liu, L., Fan, H., Ke, S., Chen, X., 2008, ‚Effect of Sintering Temperature on The Structure and Properties of Cerium-Doped 0.94(Bi0.5Na0.5)TiO3–0.06BaTiO3 Piezoelectric Ceramics‛, Journal of Alloys and Compounds, Vol. 458, pp. 504-508.
  • Naceur, H., Megriche, A., El Maaoui, M., 2014, ‚Effect of Sintering Temperature on Microstructure and Electrical Properties of Sr1-x(Na0.5Bi0.5)xBi2Nb2O9 Solid Solutions‛, Journal of Advanced Ceramics, Vol. 3, No. 1, pp. 17-30.
  • Shrout, T.R., Swartz, S.L., 1983, ‚Dielectric-properties of Pyrochlore Lead Magnesium Niobate‛, Materials Research Bulletin, Vol. 18, No. 6, pp. 663-7.
  • Swartz, S.L., Shrout, T.R., 1982, ‚Fabrication of Perovskite Lead Magnesium Niobate‛, Materials Research Bulletin, Vol.17, No. 10, pp. 1245-50.
  • Takahashi, S., Sasaki, Y., Kawai, H., Hirose, S., 1996, ‚High-power Piezoelectric Characteristics in Pb(Mo1/3Sb2/3)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 Solid Solution System‛, Isaf '96 - Proceedings of the Tenth Ieee International Symposium on Applications of Ferroelectric, Vol.1, pp. 2309-312.
  • Takahashi, S., Yamamoto, M., Sasaki, Y., 1998, ‚Nonlinear Piezoelectric Effect in Ferroelectric Ceramics‛, Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers, Vol. 37, No. 9B, pp. 5292-6.
  • Taşpınar, E., 1997, Production and Characterization of Lead Zirconate Titanate and Lead Magnesium Niobate- Lead Titanate Piezoceramics, Yüksek Lisans Tezi, Orta Doğu Teknik Üniversitesi, Ankara.
  • Wakiya, N., Kim, B.H., Shinozaki, K., Mizutani, N., 1994, ‚Composition Range of Cubic Pyrochlore Type Compound in Lead Magnesium Niobium Oxygen System‛, Nippon Seramikkusu Kyokai
  • Gakujutsu Ronbunshi-Journal of the Ceramic Society of Japan, Vol.102, No. 6, pp. 612-615.
  • Wakiya, N., Saiki, A., Ishizawa, N., Shinozaki, K., Mizutani, N., 1993, ‚Crystal-growth, Crystal-structure and Chemical-composition of a Pyrochlore Type Compound in Lead-magnesium-niobiumoxygen System‛, Materials Research Bulletin, Vol. 28, No. 2, pp. 137-143.
  • Zhu, R., Yin, Y., Fang, B., Chen, Z., Zhang, S., Ding, J., Zhao, X., Luo, H., 2016, ‚Optimizing Structure and Electrical Properties of High-Curie Temperature PMN-PHT Piezoelectric Ceramics via Tailoring Sintering Process‛, The European Physical Journal-Applied Physics, Vol. 74, No. 3, pp. 30101.

PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU

Yıl 2017, Cilt: 5 Sayı: 2, 144 - 152, 01.06.2017
https://doi.org/10.15317/Scitech.2017.78

Öz

PMS [Pb(Mn1/3Sb2/3)O3] ile katkılanmış PMN-PT [Pb(Mg1/3Nb2/3)O3-PbTiO3] üçlü piezoelektrik
seramikleri (PMN-PT-PMS) 1100–1250 °C aralığında farklı sinterleme sıcaklıklarının kullanıldığı katı-hal
reaksiyon yöntemi ile üretilmiştir. Sinterleme sıcaklığının kristal fazlar, mikroyapı ve elektriksel
özellikler üzerindeki etkisi sistematik olarak incelenmiştir. Mikroyapı ve kompozisyon analizleri
taramalı elektron mikrosko u SEM ve X-ışınları kırınımı XRD ile, elektriksel karakterizasyon ise
indüktans-kapasitans-direnç ölöer LCR metre , empedans analizöru ve Berlincourt d33-piezometre
kullanılarak gerçekleştirilmiştir. XRD ve SEM sonuçları, saf perovskit yapının ve homojen ir
mikroyapının elde edilmesinde sinterleme sıcaklığının etkili olduğunu ortaya koymuştur. 1150 °C ve
altındaki sinterleme sıcaklıklarında yoğunlaşma yetersiz olmakta ve saf perovskit yapı elde
edilememekte, 1200 °C’nin üstündeki sıcaklıklarda ise kurşun oksitin uçuculuğu nedeniyle heterojen ir
mikroyapı oluşmaktadır. Uygun sinterleme sıcaklığında elde edilen yüksek yoğunluk ve homojen
mikroyapı; PMN-PT-PMS seramiklerinin yüksek piezoelektrik ve dielektrik davranış sergilemesini
sağlamaktadır. Deneysel sonuçlar, 1175 °C’de 2 saat süre ile sinterlenmiş numunelerin optimum
elektriksel özellikler d33=265 pC/N, KT=4745, kp=0,417, tanδ=%2,5 ve Qm=222) sergilediğini göstermiştir.

Kaynakça

  • Aydın H.S., 2016, PMN-PT[Pb(Mg1/3Nb2/3)O3-PbTiO3] Esaslı Piezoelektrik Seramiklerin Üretimi ve Karakterizasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
  • Aydın H.S., Kalem V., 2016, ‚PMN-PT [Pb(Mg1/3Nb2/3)O3-PbTiO3] Esaslı Seramiklerde Kompozisyonun Yapısal ve Elektriksel Özelliklere Etkisi‛, Selçuk Üniversitesi Mühendislik Bilim ve Teknoloji Dergisi, Vol. 4, No. 2, pp. 100-110.
  • Bouquin, O., Lejeune, M., Boilot, J.P., 1991, ‚Formation of The Perovskite Phase in the PbMg1/3Nb2/3O3- PbTiO3 system‛, Journal of the American Ceramic Society, Vol.74, No. 5, pp. 1152-56.
  • Carter, C.B., Norton, M.G., 2007, Ceramic Materials: Science and Engineering, Springer, New York.
  • Choi, S.W., Shrout, T.R., Jang, S.J., Bhalla, A.S., 1989, ‚Dielectric and Pyroelectric Properties in The Pb(Mg1/3Nb2/3)O3-PbTiO3 system‛, Ferroelectrics, Vol. 100, pp. 29-38.
  • Guha, J.P., 1999, ‚Reaction Chemistry and Subsolidus Phase Equilibria in Lead-based Relaxor Systems: Part I - Formation and Stability of The Perovskite and Pyrochlore Compounds in The System PbO-MgO-Nb2O5‛, Journal of Materials Science, Vol. 34, No. 20, pp. 4985-94.
  • Hai, L., Bo-Ping, Z., Yu, P., Lei, Z., Kai-sheng, W., Yan-tao, L., 2015, ‚Effects of Sintering Temperature on Structure and Properties of BY-PT-PMN Ternary Piezoelectric Ceramics‛, Journal of Materials Research, Vol. 30, No. 6, pp. 782-790.
  • Hoffmann, M.J., Hammer M., Endriss A., Lupascu D.C., 2001, ‚Correlation Between Microstructure, Strain Behavior, and Acoustic Emission of Soft PZT Ceramics‛, Acta Materialia, Vol.49, pp. 1301–1310.
  • Inada, M., 1977, ‚Analysis of The Formation Process of the Piezoelectric PCM Ceramics‛, National Technical Report (Matsushita Elect. Ind. Co.), Vol. 27, No. 1, pp. 95-102.
  • Ketsuwan, P., Ngamjarurojana, A., Laosiritaworn, Y., Ananta, S., Yimnirun, R., 2007, ‚Effect of Sintering Temperature on Phase Formation, Dielectric, Piezoelectric, and Ferroelectric Properties of Nb- Doped Pb(Zr0.52Ti0.48)O3 Ceramics‛, Ferroelectrics, Vol. 358, pp. 35-41.
  • Liu, L., Fan, H., Ke, S., Chen, X., 2008, ‚Effect of Sintering Temperature on The Structure and Properties of Cerium-Doped 0.94(Bi0.5Na0.5)TiO3–0.06BaTiO3 Piezoelectric Ceramics‛, Journal of Alloys and Compounds, Vol. 458, pp. 504-508.
  • Naceur, H., Megriche, A., El Maaoui, M., 2014, ‚Effect of Sintering Temperature on Microstructure and Electrical Properties of Sr1-x(Na0.5Bi0.5)xBi2Nb2O9 Solid Solutions‛, Journal of Advanced Ceramics, Vol. 3, No. 1, pp. 17-30.
  • Shrout, T.R., Swartz, S.L., 1983, ‚Dielectric-properties of Pyrochlore Lead Magnesium Niobate‛, Materials Research Bulletin, Vol. 18, No. 6, pp. 663-7.
  • Swartz, S.L., Shrout, T.R., 1982, ‚Fabrication of Perovskite Lead Magnesium Niobate‛, Materials Research Bulletin, Vol.17, No. 10, pp. 1245-50.
  • Takahashi, S., Sasaki, Y., Kawai, H., Hirose, S., 1996, ‚High-power Piezoelectric Characteristics in Pb(Mo1/3Sb2/3)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 Solid Solution System‛, Isaf '96 - Proceedings of the Tenth Ieee International Symposium on Applications of Ferroelectric, Vol.1, pp. 2309-312.
  • Takahashi, S., Yamamoto, M., Sasaki, Y., 1998, ‚Nonlinear Piezoelectric Effect in Ferroelectric Ceramics‛, Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers, Vol. 37, No. 9B, pp. 5292-6.
  • Taşpınar, E., 1997, Production and Characterization of Lead Zirconate Titanate and Lead Magnesium Niobate- Lead Titanate Piezoceramics, Yüksek Lisans Tezi, Orta Doğu Teknik Üniversitesi, Ankara.
  • Wakiya, N., Kim, B.H., Shinozaki, K., Mizutani, N., 1994, ‚Composition Range of Cubic Pyrochlore Type Compound in Lead Magnesium Niobium Oxygen System‛, Nippon Seramikkusu Kyokai
  • Gakujutsu Ronbunshi-Journal of the Ceramic Society of Japan, Vol.102, No. 6, pp. 612-615.
  • Wakiya, N., Saiki, A., Ishizawa, N., Shinozaki, K., Mizutani, N., 1993, ‚Crystal-growth, Crystal-structure and Chemical-composition of a Pyrochlore Type Compound in Lead-magnesium-niobiumoxygen System‛, Materials Research Bulletin, Vol. 28, No. 2, pp. 137-143.
  • Zhu, R., Yin, Y., Fang, B., Chen, Z., Zhang, S., Ding, J., Zhao, X., Luo, H., 2016, ‚Optimizing Structure and Electrical Properties of High-Curie Temperature PMN-PHT Piezoelectric Ceramics via Tailoring Sintering Process‛, The European Physical Journal-Applied Physics, Vol. 74, No. 3, pp. 30101.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Osman Düzen Bu kişi benim

Volkan Kalem

Yayımlanma Tarihi 1 Haziran 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 5 Sayı: 2

Kaynak Göster

APA Düzen, O., & Kalem, V. (2017). PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 5(2), 144-152. https://doi.org/10.15317/Scitech.2017.78
AMA Düzen O, Kalem V. PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU. sujest. Haziran 2017;5(2):144-152. doi:10.15317/Scitech.2017.78
Chicago Düzen, Osman, ve Volkan Kalem. “PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5, sy. 2 (Haziran 2017): 144-52. https://doi.org/10.15317/Scitech.2017.78.
EndNote Düzen O, Kalem V (01 Haziran 2017) PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5 2 144–152.
IEEE O. Düzen ve V. Kalem, “PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU”, sujest, c. 5, sy. 2, ss. 144–152, 2017, doi: 10.15317/Scitech.2017.78.
ISNAD Düzen, Osman - Kalem, Volkan. “PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5/2 (Haziran 2017), 144-152. https://doi.org/10.15317/Scitech.2017.78.
JAMA Düzen O, Kalem V. PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU. sujest. 2017;5:144–152.
MLA Düzen, Osman ve Volkan Kalem. “PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 5, sy. 2, 2017, ss. 144-52, doi:10.15317/Scitech.2017.78.
Vancouver Düzen O, Kalem V. PMN-PT-PMS SERAMİKLERİNDE SİNTERLEME SICAKLIĞI ETKİSİYLE YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİN OPTİMİZASYONU. sujest. 2017;5(2):144-52.

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