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Ageing Behavior of Temperature Sensitive Leathers

Yıl 2017, Cilt: 24 Sayı: 107, 195 - 202, 30.09.2017

Öz

Enhancing fastness properties of thermochromic dyes and pigments provide unique and assertive design opportunities and an innovative approach for leather industry. For this purpose, the ageing behavior of thermochromic pigments (cold and touch activated) used in leather finishing process by the addition of UV absorbent and cross-linker was investigated. The color changing effect of thermochromic leathers was determined spectrophotometrically prior and subsequent to accelerated ageing tests performed under two different conditions (only heat and heat associated with relative humidity). No significant effect of ageing was found on thermochromic leathers. However, a partial decrease was determined for the cold activated leathers and it was prevented by the use of UV absorbent and cross-linker. 

Kaynakça

  • Şeren, A., Adıgüzel Zengin, A. C., Bitlisli, B. O., (2013), Thermo-chromic Pigments in Leather Finishing, XXXII Congress of IULTCS, 29-31 May 2013, Istanbul, Turkey, 34.
  • Salom A., Adiguzel Zengin A.C., Bitlisli B.O., (2016), Temperature Sensitive Colour Changing Leathers with Thermochromic Pigments, Journal of Society of Leather Technologists and Chemists, 100, 6, 314-320.
  • Bamfield, P., Hutchings, M., (2010), Chromic Phenomena Technological Applications of Colour Chemistry, 2nd ed. Royal Society of Chemistry, Cambridge, Great Britain, 562.
  • Adiguzel Zengin, A.C., Kucukakin, E., Bitlisli, B.O., (2017), Ageing Behavior of Temperature Sensitive Leathers, 16th International the Recent Progress Symposium on Textile Technology and Chemistry, 4-6th May 2017, Bursa, Turkey, 313-320
  • Christie, R.M., Robertson S., Taylor, S., (2007), Design Concepts for a Temperature Sensitive Environment using Thermochromic Color Change, Color: Design and Creativity, 1, 1, 1-11.
  • Kulcar, R., Friskovec, M., Hauptman, N., Vesel A., Gunde, MK.,(2010), Colorimetric properties of reversible thermochromic printing inks, Dyes and Pigments, 86, 271-277.
  • Chowdhury, M.A., Joshi, M., Butola, B.S., (2014), Photochromic and Thermochromic Colorants in Textile Applications, Journal of Engineered Fibers and Fabrics, 9, 107-123.
  • Mather, R.R., (2001), Intelligent Textiles, Rev. Prog. Color., 31, 36- 41.
  • Gulumser, T., Karagöz, E., Kumbasar Akçakoca, E. P., (2008), Research about Dyeing of Cotton Fibers with Fluorescent Dyestuffs and Developing Light Fastness, Tekstil ve Konfeksiyon, 4, 284-288.
  • Brezova, V., Pigosova, J., Havlinova, B., Dvoranova, D., Durovic, M., (2004), EPR study of photochemical transformations of triarylmethane dyes, Dyes and Pigments, 61, 177-198.
  • Basaran, B., Bitlisli, B.O., Ocak, B., Onem, E., (2011), Effect of Different Atmospheric Conditions on Some Physical Properties of Leather, Tekstil ve Konfeksiyon, 2, 194-198.
  • Oda, H., (2008), Photostabilization of Organic Thermochromic Pigments: Action of Benzotriazole Type UV absorbers Bearing an Amphoteric Counter-Ion Moiety on the Light Fastness of Color Formers, Dyes and Pigments, 76, 1, 270-276.
  • Lopes, F., Neves, J., Campos, A., Hrdina, R., (2009), Wearing of Microencapsulated Thermochromic Pigments, Research Journal of Textile and Apparel, 13, 1, 78-89.
  • Christie, RM., Bryant, ID., (2005), An evaluation of thermochromic prints based on microencapsulated liquid crystals using variable temperature color measurement, Coloration Technology, 121, 187-192
  • Chowdhury, M. A., Butola, B. S. and Joshi, M., (2013), Application of thermochromic colorants on textiles: temperature dependence of colorimetric properties, Coloration Technology, 129, 232-237.
  • Tamilmani, V., Kanadasan, D., Muthazhagan, R., Sreeram, K.J., Raghava Rao, J., Nair, B.U., (2015), Thermochromism for Smart Leathers, Journal of American Leather Chemists Association, 110, 6, 161-164.
  • ISO 2418, (2002), Leather -- Chemical, physical and mechanical and fastness tests -- Sampling location, International Organizationfor Standardization (ISO), Geneva, Switzerland.
  • ISO 2419, (2012), Leather-Physical and mechanical tests-Sample preparation and conditioning, International Organization for Standardization (ISO), Geneva, Switzerland.
  • TS EN ISO 17228, (2009), Leather-Tests for colour fastness-Change in color with accelerated ageing, Turkish Standard Institute, Ankara, Turkey.
  • McLaren, K., (1983), The color science of dyes and pigments, Adam Hilger Ltd. Bristol, UK, 186.
  • Mutlu, M.M., Crudu, M., Maier, S.S., Deselnicu, D., Albu, L., Gülümser, G., Bitlisli, B.O., Başaran, B., Tosun, C.C., Adıgüzel Zengin A.C., (2014), Eco-Leather: Properties of Chromium-Free Leathers Produced with Titanium Tanning Materials Obtained from the Wastes of Metal Industry, Ekoloji, 23, 91, 83-90.

Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları

Yıl 2017, Cilt: 24 Sayı: 107, 195 - 202, 30.09.2017

Öz

Termokromik boyaların ve pigmentlerin haslık özelliklerini artırmak deri endüstrisine benzersiz ve iddialı tasarım olanakları ile yenilikçi bir yaklaşım sağlar. Bu nedenle, finisaj işlem basamağında bir çapraz bağlayıcı ve UV absorban eşliğinde kullanılan termokromik pigmentlerin (soğuk ve dokunma aktiviteli) yaşlanma davranışları incelenmiştir. Termokromik derilerin renk değiştirme özellikleri sadece sıcaklık ve sıcaklık ile bağıl nemin beraber etkisinin incelendiği hızlandırılmış yaşlanma testlerinin öncesi ve sonrasında spektrofotometrik olarak belirlenmiştir. Sonuç olarak, termokromik deriler üzerine yaşlanmanın anlamlı bir etkisi tespit edilememiştir. Fakat soğuk aktiviteli derilerde kısmi bir azalma belirlenmiş ve bu solma UV absorban ve çapraz bağlayıcı kullanımı ile engellenmiştir. 

Kaynakça

  • Şeren, A., Adıgüzel Zengin, A. C., Bitlisli, B. O., (2013), Thermo-chromic Pigments in Leather Finishing, XXXII Congress of IULTCS, 29-31 May 2013, Istanbul, Turkey, 34.
  • Salom A., Adiguzel Zengin A.C., Bitlisli B.O., (2016), Temperature Sensitive Colour Changing Leathers with Thermochromic Pigments, Journal of Society of Leather Technologists and Chemists, 100, 6, 314-320.
  • Bamfield, P., Hutchings, M., (2010), Chromic Phenomena Technological Applications of Colour Chemistry, 2nd ed. Royal Society of Chemistry, Cambridge, Great Britain, 562.
  • Adiguzel Zengin, A.C., Kucukakin, E., Bitlisli, B.O., (2017), Ageing Behavior of Temperature Sensitive Leathers, 16th International the Recent Progress Symposium on Textile Technology and Chemistry, 4-6th May 2017, Bursa, Turkey, 313-320
  • Christie, R.M., Robertson S., Taylor, S., (2007), Design Concepts for a Temperature Sensitive Environment using Thermochromic Color Change, Color: Design and Creativity, 1, 1, 1-11.
  • Kulcar, R., Friskovec, M., Hauptman, N., Vesel A., Gunde, MK.,(2010), Colorimetric properties of reversible thermochromic printing inks, Dyes and Pigments, 86, 271-277.
  • Chowdhury, M.A., Joshi, M., Butola, B.S., (2014), Photochromic and Thermochromic Colorants in Textile Applications, Journal of Engineered Fibers and Fabrics, 9, 107-123.
  • Mather, R.R., (2001), Intelligent Textiles, Rev. Prog. Color., 31, 36- 41.
  • Gulumser, T., Karagöz, E., Kumbasar Akçakoca, E. P., (2008), Research about Dyeing of Cotton Fibers with Fluorescent Dyestuffs and Developing Light Fastness, Tekstil ve Konfeksiyon, 4, 284-288.
  • Brezova, V., Pigosova, J., Havlinova, B., Dvoranova, D., Durovic, M., (2004), EPR study of photochemical transformations of triarylmethane dyes, Dyes and Pigments, 61, 177-198.
  • Basaran, B., Bitlisli, B.O., Ocak, B., Onem, E., (2011), Effect of Different Atmospheric Conditions on Some Physical Properties of Leather, Tekstil ve Konfeksiyon, 2, 194-198.
  • Oda, H., (2008), Photostabilization of Organic Thermochromic Pigments: Action of Benzotriazole Type UV absorbers Bearing an Amphoteric Counter-Ion Moiety on the Light Fastness of Color Formers, Dyes and Pigments, 76, 1, 270-276.
  • Lopes, F., Neves, J., Campos, A., Hrdina, R., (2009), Wearing of Microencapsulated Thermochromic Pigments, Research Journal of Textile and Apparel, 13, 1, 78-89.
  • Christie, RM., Bryant, ID., (2005), An evaluation of thermochromic prints based on microencapsulated liquid crystals using variable temperature color measurement, Coloration Technology, 121, 187-192
  • Chowdhury, M. A., Butola, B. S. and Joshi, M., (2013), Application of thermochromic colorants on textiles: temperature dependence of colorimetric properties, Coloration Technology, 129, 232-237.
  • Tamilmani, V., Kanadasan, D., Muthazhagan, R., Sreeram, K.J., Raghava Rao, J., Nair, B.U., (2015), Thermochromism for Smart Leathers, Journal of American Leather Chemists Association, 110, 6, 161-164.
  • ISO 2418, (2002), Leather -- Chemical, physical and mechanical and fastness tests -- Sampling location, International Organizationfor Standardization (ISO), Geneva, Switzerland.
  • ISO 2419, (2012), Leather-Physical and mechanical tests-Sample preparation and conditioning, International Organization for Standardization (ISO), Geneva, Switzerland.
  • TS EN ISO 17228, (2009), Leather-Tests for colour fastness-Change in color with accelerated ageing, Turkish Standard Institute, Ankara, Turkey.
  • McLaren, K., (1983), The color science of dyes and pigments, Adam Hilger Ltd. Bristol, UK, 186.
  • Mutlu, M.M., Crudu, M., Maier, S.S., Deselnicu, D., Albu, L., Gülümser, G., Bitlisli, B.O., Başaran, B., Tosun, C.C., Adıgüzel Zengin A.C., (2014), Eco-Leather: Properties of Chromium-Free Leathers Produced with Titanium Tanning Materials Obtained from the Wastes of Metal Industry, Ekoloji, 23, 91, 83-90.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Konular Mühendislik
Bölüm Makaleler
Yazarlar

Arife Candaş Adıgüzel Zengin

Eylül Küçükakın Bu kişi benim

Behzat Oral Bitlisli Bu kişi benim

Yayımlanma Tarihi 30 Eylül 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 24 Sayı: 107

Kaynak Göster

APA Adıgüzel Zengin, A. C., Küçükakın, E., & Bitlisli, B. O. (2017). Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları. Tekstil Ve Mühendis, 24(107), 195-202.
AMA Adıgüzel Zengin AC, Küçükakın E, Bitlisli BO. Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları. Tekstil ve Mühendis. Eylül 2017;24(107):195-202.
Chicago Adıgüzel Zengin, Arife Candaş, Eylül Küçükakın, ve Behzat Oral Bitlisli. “Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları”. Tekstil Ve Mühendis 24, sy. 107 (Eylül 2017): 195-202.
EndNote Adıgüzel Zengin AC, Küçükakın E, Bitlisli BO (01 Eylül 2017) Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları. Tekstil ve Mühendis 24 107 195–202.
IEEE A. C. Adıgüzel Zengin, E. Küçükakın, ve B. O. Bitlisli, “Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları”, Tekstil ve Mühendis, c. 24, sy. 107, ss. 195–202, 2017.
ISNAD Adıgüzel Zengin, Arife Candaş vd. “Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları”. Tekstil ve Mühendis 24/107 (Eylül 2017), 195-202.
JAMA Adıgüzel Zengin AC, Küçükakın E, Bitlisli BO. Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları. Tekstil ve Mühendis. 2017;24:195–202.
MLA Adıgüzel Zengin, Arife Candaş vd. “Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları”. Tekstil Ve Mühendis, c. 24, sy. 107, 2017, ss. 195-02.
Vancouver Adıgüzel Zengin AC, Küçükakın E, Bitlisli BO. Sıcaklığa Duyarlı Derilerin Yaşlanma Davranışları. Tekstil ve Mühendis. 2017;24(107):195-202.