Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları

Abstract

Bu çalışma Biga Yarımadası (KB Türkiye)’nda yer alan Karadoru (Biga, Çanakkale) ve Karaköy (Yenice, Çanakkale) arasındaki Pb-Zn-Cu cevherleşmelerinin jeokimyasını ve kükürt izotop oranlarıile kökenini ortaya koymaya yöneliktir. İncelenen cevherleşmeler, Karadoru, Peynirderesi, Madençeşme (Biga, Çanakkale) ve Karaköy (Yenice, Çanakkale) olmak üzere toplam 4 lokasyonda gözlenmektedir. Bölgenin en alt tektonostratigrafik birimini Karakaya Kompleksi oluşturmaktadır. Karakaya Kompleksinin birimi olan ve başlıca metabazik kayaçları içeren Nilüfer birimi onun üzerinde de kireçtaşları, spilitik bazalt, diyabaz ve arkozik kumtaşlarını kapsayan Hodul birimi yer alır. Karakaya Kompleksine ait birimlerini Oligosen-Miyosen yaşlı Karadoru, Sarıçayır ve Soğucak granitoyidleri kesmektedir. Bölgede yüzlek veren birçok plütonik kütlelerin Karakaya Kompleksi (Nilüfer ve Hodul)’ne ait birimleri kestiği lokasyonlarda skarn zonları gelişmiştir. Karadoru, Sarıçayır ve Soğucak granitoyid kayaçları üzerine Miyosen yaştaki Çan volkanitleri gelir. İncelenen Pb-Zn-Cu cevherleşmeleri Karakaya Kompleksi içerisindeki Karadoru ve Madençeşme lokasyonlarında Nilüfer biriminde (epimetamorfikler), Peynirderesi ve Karaköy (Arapuçandere) mevkiilerinde Hodul birimi (metadiyabazve kristalize kireçtaşı) içerisinde damar şeklinde yataklanmaktadır. Cevherleşmenin mineral parajenezini galen, kalkopirit, sfalerit cevher mineralleri ile pirit, limonit, hematit, malakit, manganoksit, kuvars, kalsit ve klorit oluşturmaktadır. Çalışma alanındaki cevherli zonlardan alınan galen ve pirit numunelerinin δ34S değerleri sırasıyla Karadoru ‰ -3,4 ve ‰-3,9, Karaköy ‰-1,7 ve ‰ -1,6, Peynirderesi ‰ -1,7 ve ‰ -4,0 şeklindedir. İncelenen Pb-Zn-Cu cevherleşmelerinde galenlerde Sb/Bi oranının 0,06-0,34 ppm, piritlerde Co/Ni oranı 1-10 ppm arasında olması, kükürt izotop oranlarının negatif değerlerde olması, cevherleşmenin magmatik hidrotermal kökenli ve I-tipi bir magmatik aktiviteye bağlı olduğunaişaret etmektedir. Buna ek olarak, Pb-Zn-Cu cevherleşmelerinin damar şeklinde epijenetik yataklanması, iz element içeriklerinin (Pb, Zn, Cu, Bi, Sb, Ag, Au, W, As) yüksekliği ve silisleşme, serizitleşme, killeşme ve limonitleşme alterasyonlarının gözlenmesi de cevherleşmenin hidrotermal kökenli olduğunu destekler niteliktedir.

Keywords

• Biga Yarımadası
• Karakaya Kompleksi
• Karadoru-Karaköy Pb-Zn-Cu cevherleşmesi
• S34/32 izotop oranları
• köken.

Origin, Geochemistry and Sulfur Isotope Ratios of Pb-Zn-Cu Mineralization between Karadoru and Karaköy (Biga Peninsula, Çanakkale)

Abstract

This study aims to investigate the geochemistry and sulfur isotope ratios, as well as the origin of Pb-Zn-Cu mineralization, between Karadoru (Biga, Çanakkale) and Karaköy (Yenice, Çanakkale) in the Biga Peninsula (NW Turkey). Mineralization was observed at four locations: Karadoru, Peynirderesi, Madençeşme (Biga, Çanakkale) and Karaköy (Yenice, Çanakkale). The lowest tectonostratigraphic unit in the region is the Karakaya Complex. The Nilüfer unit, which is part of the Karakaya Complex and mainly consists of metabasic rocks, is overlain by the Hodul unit. The Hodul unit comprises limestones, spilitic basalt, diabase, and arkosic sandstones. The Karadoru, Sarıçayır, and Soğucak granitoids, which are Oligocene-Miocene in age, cut through units of the Karakaya Complex. Skarn zones developed in locations where many plutonic masses intersect with the units of the Karakaya Complex (Nilüfer and Hodul). The Çan volcanics, which date back to the Miocene era, are found on top of the Karadoru, Sarıçayır, and Soğucak granitoid rocks. The Pb-Zn-Cu mineralizations were deposited as veins in the Nilüfer unit (epimetamorphics) in the Karadoru and Madençeşme locations within the Karakaya Complex, and in the Hodul unit (metadiabase and crystallized limestone) in the Peynirderesi and Karaköy (Arapuçandere) locations. The paragenesis includes galena, chalcopyrite, sphalerite, pyrite, limonite, hematite, malachite, manganese, quartz, calcite, and chlorite. The δ34S values of galena and pyrite samples taken from the ore zones in the study area are as follows: Karadoru -3.4‰ and -3.9‰, Karaköy -1.7‰ and -1.6‰, and Peynirderesi -1.7‰ and -4.0‰. The examined Pb-Zn-Cu mineralizations had Sb/Bi ratio in galena ranging from 0.06-0.34 ppm, and Co/Ni ratio in pyrites ranging from 1-10 ppm. The sulfur isotope ratios are negative, indicating that the mineralization has magmatic hydrothermal origin and is due to I-type magmatic activity. The mineralization contains vein-shaped epigenetic deposits of Pb-Zn-Cu mineralization, high trace element contents (Pb, Zn, Cu, Bi, Sb, Ag, Au, W, As), and silicification, sericitization, argillization, and limonitization are observed. These characteristics support the view that the mineralization has hydrothermal origin.

Keywords

• Biga Peninsula
• Karakaya Complex
• Karadoru-Karaköy Pb-Zn-Cu mineralization
• S34/32 isotope ratios
• origin.

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