Near Net Shape Fabrication Of Pmn Scaffolds
Yıl 2009,
Cilt: 9 Sayı: 3, 155 - 160, 01.12.2009
Aylin Şakar-deliormanlı
Erdal Çelik
Mehmet Polat
Öz
Solid free form fabrication techniques are commonly employed in near net shaping of ceramics
especially in the manufacture of microelectronics. Lead magnesium niobate (PMN) is an important
relaxor ferroelectric material with perovksite structure used in the production of these multilayer
ceramic devices. In this study two dimensional PMN arrays and three dimensional periodic structures
were produced by robocasting which is a direct writing technique. Aqueous colloidal gels have been
formulated for use as ink in solid freeform fabrication process. Results showed that complex PMN
shapes having rod size down to 100 μm can be successfully produced by robocasting process to be
used in microelectronic applications.
Kaynakça
- 1. Gentil,S., Damjanoviç, D., and Setter, N., Pb(Mg1/3Nb2/3)O3 and (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 relaxor
ferroelectric thick films: processing and electrical characterization, Journal of Electroceramics, Vol.12,
Pages 151-161, 2004.
- 2. Tzou, H.S., Lee, H.J, and Arnold, S.M., Smart Materials, Precision sensors/actuators, smart structures, and
structronic systems, Mechanics of Advanced Materials and Structures, Vol.11, Pages 367-393, 2004.
- 3. Moulson, J.A., and Herbert, J.M., Electroceramics Materials Properties and Applications, (Chapman &
Hall) 1990.
- 4. Fengbing, S., Qiang, L., Haisheng, Z., Chunhong, L., Shix,Z., and Dezhong, S., Phase formation and
transitions in the lead magnesium niobate-lead titanate system, Materials Chemistry and Physics, Vol. 83,
Pages 135-139, 2004.
- 5. Swartz, S.L., Shrout, T.R., Schulze, W.A., and Cross, L.E., Dielectric properties of lead magnesium
niobate ceramics, Journal of American Ceramic Society, Vol.67, Pages 311-315, 1984.
- 6. Prasad, S.E., Ahmed, A., and Wheat, T.A., The role of smart materials and structure in robotics, Smart
Materials and Structures. Pages 133-147, 1998.
- 7. Blackwood, G.H., and Ealey, M.A., Electrostrictive behavior in lead magnesium niobate (PMN) actuators
part I: materials perspective, Smart Materials and Structures, Vol. 2, Pages 124-133, 1993.
- 8. Calvert, P., Ink jet printing for materials and devices, Chemistry of Materials, Vol. 13, Pages 3299-3305,
2001.
- 9. Calvert, P., and Crockett, R., Chemical Solid Freeform Fabrication: Making Shapes without Molds,
Chemistry of Materials, Vol. 9, Pages, 650-663, 1997.
- 10. Xiaogang, L., Lei, F., Seunghun, H., Dravid, V.P., and Mirkin, C.A., Arrays of Magnetic Nanoparticles
Patterned via Dip Pen Nanolithography, Advanced Materials, Vol. 14, No: 3, Pages 231-234, 2002.
- 11. Yoo, J., Cima, M., Scahs, E., and Suresh, S., Fabrication and Microstructural Control of Advanced Ceramic
Components by Three Dimensional Printing, Ceramic Engineering and Science Proceedings, Vol. 16, Pages
755-762, 1995.
- 12. Brennan, R.E., Turcu, S., Hall, A., Hagh, N.M., and Safari A., Fabrication of Electroceramic Components
by Layered Manufacturing, Ferroelectrics, Vol. 293, Pages 3-17, 2003.
- 13. Cesarano III, J., Segalman, R., and Calvert, P., Robocasting Provides Moldless Fabrication from Slurry
Deposition, Ceramic Industry, Vol. 148, Pages 4, 1998.
- 14. Safari, A., Cesarano, J., Clem, P.G., and Bender, B., Fabrication of Advanced Functional Electroceramics
Components by Layered Manufacturing (LM) Methods, Proceedings of the 13th IEEE International
Symposium on Applications of Ferroelectrics, Japan, Pages 1-6, 2002.
- 15. Rao, R.B., Krafcik, K.L., Morales, A.M., and Lewis J.A., Microfabricated Deposition Nozzles for DirectWrite Assembly of Three Dimensional Periodic Structures, Advanced Materials, Vol. 17, No.3, Pages 289-
293, 2005.
- 16. Smay,J.E., Cesarano III, J., and Lewis, J.A., Colloidal inks for directed assembly of 3-D periodic structures,
Langmuir, Vol. 18, Pages 5429-5437, 2002.
- 17. Therriault, D., Shepherd, R.E., White, S.R., and Lewis, J.A., Fugitive Inks for Direct Write Assembly of
Three Dimensional Microvascular Networks, Advanced Materials, Vol. 17, No.4, Pages 395-399, 2005.
- 18. Wu, B.M., Borland, S.W., Giordano, R.A., Cima, L.G., Sachs, E.M., and Cima, M.J., Solid Free-Form
Fabrication of Drug Delivery Devices, Journal of Controlled Release, Vol. 40, No: 1, Pages 77-87, 1996.
- 19. Gratson, G.M., Garcia-Santamaria, F., Lousse, V., Xu, M., Fan, S., Lewis, J.A., and Braun, P.V., Direct
Write Assembly of Three Dimensional Photonic Crystals: Conversion of Polymer Scaffolds to Silicon
Hollow Woodpile Structures, Advanced Materials, Vol. 18, Pages 461-465, 2006.
- 20. Morissette, S.L., Cesarano III, J., Lewis, J.A., and Dimos, D.B., Solid Freeform Fabrication Using
Chemically Suspensions, US Patent. No: 6454972, 2002.
- 21. Li, Q., and Lewis, J.A., Nanoparticle Inks for Directed Assembly of Three Dimensional Periodic Structures,
Advanced Materials, Vol. 15, Pages 1639-43, 2003.
- 22. Nadkarni, S.S., and Smay, J.E., Concentrated Barium Titanate Colloidal Gels Prepared by Bridging
Flocculation for Use in Solid Freeform Fabrication, Journal of the American Ceramic Society, Vol. 89,
No.1, 96-103, 2006.
- 23. Smay, J.E., Gratson, G.M., Shepherd, R.F., Cesarano III, J., and Lewis, J.A., Directed Colloidal Assembly of
3D Periodic Structures, Advanced Materials, Vol. 14, No.18, Pages 1279-83, 2002.
- 24. Lewis, J.A., Smay, J.E., Stuecker, J., and Cesarano III, J., Direct Ink Writing of Three Dimensional Ceramic
Structures, Journal of the American Ceramic Society, Vol. 89, No.12, Pages 3599-3609, 2006.
- 25. Şakar-Deliormanlı, A., Çelik, E., and Polat, M., Rheological Behaviour of PMN Gels for Solid Freeform
Fabrication, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 326, Pages 159-166,
2008.
Near Net Shape Fabrication Of Pmn Scaffolds
Yıl 2009,
Cilt: 9 Sayı: 3, 155 - 160, 01.12.2009
Aylin Şakar-deliormanlı
Erdal Çelik
Mehmet Polat
Öz
Solid free form fabrication techniques are commonly employed in near net shaping of ceramics
especially in the manufacture of microelectronics. Lead magnesium niobate (PMN) is an important
relaxor ferroelectric material with perovksite structure used in the production of these multilayer
ceramic devices. In this study two dimensional PMN arrays and three dimensional periodic structures
were produced by robocasting which is a direct writing technique. Aqueous colloidal gels have been
formulated for use as ink in solid freeform fabrication process. Results showed that complex PMN
shapes having rod size down to 100 μm can be successfully produced by robocasting process to be
used in microelectronic applications.
Anahtar Kelimeler
Shaping
Kaynakça
- 1. Gentil,S., Damjanoviç, D., and Setter, N., Pb(Mg1/3Nb2/3)O3 and (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 relaxor
ferroelectric thick films: processing and electrical characterization, Journal of Electroceramics, Vol.12,
Pages 151-161, 2004.
- 2. Tzou, H.S., Lee, H.J, and Arnold, S.M., Smart Materials, Precision sensors/actuators, smart structures, and
structronic systems, Mechanics of Advanced Materials and Structures, Vol.11, Pages 367-393, 2004.
- 3. Moulson, J.A., and Herbert, J.M., Electroceramics Materials Properties and Applications, (Chapman &
Hall) 1990.
- 4. Fengbing, S., Qiang, L., Haisheng, Z., Chunhong, L., Shix,Z., and Dezhong, S., Phase formation and
transitions in the lead magnesium niobate-lead titanate system, Materials Chemistry and Physics, Vol. 83,
Pages 135-139, 2004.
- 5. Swartz, S.L., Shrout, T.R., Schulze, W.A., and Cross, L.E., Dielectric properties of lead magnesium
niobate ceramics, Journal of American Ceramic Society, Vol.67, Pages 311-315, 1984.
- 6. Prasad, S.E., Ahmed, A., and Wheat, T.A., The role of smart materials and structure in robotics, Smart
Materials and Structures. Pages 133-147, 1998.
- 7. Blackwood, G.H., and Ealey, M.A., Electrostrictive behavior in lead magnesium niobate (PMN) actuators
part I: materials perspective, Smart Materials and Structures, Vol. 2, Pages 124-133, 1993.
- 8. Calvert, P., Ink jet printing for materials and devices, Chemistry of Materials, Vol. 13, Pages 3299-3305,
2001.
- 9. Calvert, P., and Crockett, R., Chemical Solid Freeform Fabrication: Making Shapes without Molds,
Chemistry of Materials, Vol. 9, Pages, 650-663, 1997.
- 10. Xiaogang, L., Lei, F., Seunghun, H., Dravid, V.P., and Mirkin, C.A., Arrays of Magnetic Nanoparticles
Patterned via Dip Pen Nanolithography, Advanced Materials, Vol. 14, No: 3, Pages 231-234, 2002.
- 11. Yoo, J., Cima, M., Scahs, E., and Suresh, S., Fabrication and Microstructural Control of Advanced Ceramic
Components by Three Dimensional Printing, Ceramic Engineering and Science Proceedings, Vol. 16, Pages
755-762, 1995.
- 12. Brennan, R.E., Turcu, S., Hall, A., Hagh, N.M., and Safari A., Fabrication of Electroceramic Components
by Layered Manufacturing, Ferroelectrics, Vol. 293, Pages 3-17, 2003.
- 13. Cesarano III, J., Segalman, R., and Calvert, P., Robocasting Provides Moldless Fabrication from Slurry
Deposition, Ceramic Industry, Vol. 148, Pages 4, 1998.
- 14. Safari, A., Cesarano, J., Clem, P.G., and Bender, B., Fabrication of Advanced Functional Electroceramics
Components by Layered Manufacturing (LM) Methods, Proceedings of the 13th IEEE International
Symposium on Applications of Ferroelectrics, Japan, Pages 1-6, 2002.
- 15. Rao, R.B., Krafcik, K.L., Morales, A.M., and Lewis J.A., Microfabricated Deposition Nozzles for DirectWrite Assembly of Three Dimensional Periodic Structures, Advanced Materials, Vol. 17, No.3, Pages 289-
293, 2005.
- 16. Smay,J.E., Cesarano III, J., and Lewis, J.A., Colloidal inks for directed assembly of 3-D periodic structures,
Langmuir, Vol. 18, Pages 5429-5437, 2002.
- 17. Therriault, D., Shepherd, R.E., White, S.R., and Lewis, J.A., Fugitive Inks for Direct Write Assembly of
Three Dimensional Microvascular Networks, Advanced Materials, Vol. 17, No.4, Pages 395-399, 2005.
- 18. Wu, B.M., Borland, S.W., Giordano, R.A., Cima, L.G., Sachs, E.M., and Cima, M.J., Solid Free-Form
Fabrication of Drug Delivery Devices, Journal of Controlled Release, Vol. 40, No: 1, Pages 77-87, 1996.
- 19. Gratson, G.M., Garcia-Santamaria, F., Lousse, V., Xu, M., Fan, S., Lewis, J.A., and Braun, P.V., Direct
Write Assembly of Three Dimensional Photonic Crystals: Conversion of Polymer Scaffolds to Silicon
Hollow Woodpile Structures, Advanced Materials, Vol. 18, Pages 461-465, 2006.
- 20. Morissette, S.L., Cesarano III, J., Lewis, J.A., and Dimos, D.B., Solid Freeform Fabrication Using
Chemically Suspensions, US Patent. No: 6454972, 2002.
- 21. Li, Q., and Lewis, J.A., Nanoparticle Inks for Directed Assembly of Three Dimensional Periodic Structures,
Advanced Materials, Vol. 15, Pages 1639-43, 2003.
- 22. Nadkarni, S.S., and Smay, J.E., Concentrated Barium Titanate Colloidal Gels Prepared by Bridging
Flocculation for Use in Solid Freeform Fabrication, Journal of the American Ceramic Society, Vol. 89,
No.1, 96-103, 2006.
- 23. Smay, J.E., Gratson, G.M., Shepherd, R.F., Cesarano III, J., and Lewis, J.A., Directed Colloidal Assembly of
3D Periodic Structures, Advanced Materials, Vol. 14, No.18, Pages 1279-83, 2002.
- 24. Lewis, J.A., Smay, J.E., Stuecker, J., and Cesarano III, J., Direct Ink Writing of Three Dimensional Ceramic
Structures, Journal of the American Ceramic Society, Vol. 89, No.12, Pages 3599-3609, 2006.
- 25. Şakar-Deliormanlı, A., Çelik, E., and Polat, M., Rheological Behaviour of PMN Gels for Solid Freeform
Fabrication, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 326, Pages 159-166,
2008.