In this study, the (1‐benzofurane‐2‐yl)‐3‐oxo‐prop‐1‐en‐1‐yl]‐2‐methoxyphenyl 2‐methyl acrylate monomer were synthesized from the acylation reaction of this compound with methacryloyl chloride that commercially purchased. Free radicalic or atom transfer radical polymerization methods were used for preparation of copolymers. FT‐IR, 1H and 13C‐NMR techniques were used for structure characterization of polymers. The thermal behaviors of polymers were relatively investigated by DSC and TGA, and the results were compared with each other. The dielectric behaviors of polymers were investigated as a function of temperature and frequency. The results obtained were associated with their the structures. The spectroscopic properties of the polymers were investigated by UV‐Vis and fluorescence spectroscopies. Effects of the solvent polarity on emission measurement were investigated with fluorescence spectroscopy. Under cover of dimerization property of chalcone, the chalcone ended polymer was photodimerizatied.
Jeong, J.W., Kwon, Y., Han, Y.S., Park, L.S., 2005.
Electroluminescent property and
photolithographic process of photosensitive
random copolymers. Molecular Crystals and
Liquid Crystals, 443, 59‐68.
Zhang, L.Z., Li, Y., Liang, Z.X., Yu, Q.S., Cai, Z.G.,
1999. New crosslinked polymer systems with
high and stable optical nonlinearity. Reactive
and Functional Polymer, 40, 255‐262.
Mizoguchi, K., Hasegawa, E., 1996. Photoactive
polymers applied to advanced
microelectronic devices. Polymers for
Advanced Technologies, 7, 471‐477.
Song, D.M., Jung, K.H., Moon, J.H., Shin, D.M.,
2002. Photochemistry of chalcone and the
application of chalcone‐derivatives in photoalignment
layer of liquid crystal display.
Optical Materials, 21, 667‐671.
Allen, N.S., Khan, L., Edge, M., Billings, M., Vercs,
J., 1998. Studies on UV and thermally radical
induced cross‐linked polymer networks as
charge‐transport layers in
electrophotographic coating applications.
Journal of Photochemistry and Photobiology
A: Chemistry, 116, 235‐244.
Trenor, S.R., Shultz, A.R., Love, B.J., Long, T.E.,
2004. Coumarins in polymers: from light
harvesting to photo‐cross‐linkable tissue
scaffolds. Chemical Reviews, 104, 3059‐3077.
Tamilvanan, M., Pandurangan, A., Reddy, B.S.R.,
Subramanian, K., 2007. Synthesis,
characterization and properties of
photoresponsive polymers comprising
photocrosslinkable pendant chalcone
moieties. Polymer International, 56, 104‐
111.
Santhi, R., Babu, K.V., Penlidis, A., Nanjundan, S.,
2006. Studies on copolymers of 3‐
methacryloyloxystyryl‐4′‐methylphenyl
ketone and methyl methacrylate. Reactive &
Functional Polymers, 66, 1215‐1226.
Park, H.H., Choi, Y., Park, D.J., Cho, S.Y., Yun, Y.S.,
Jin, H.J., 2013. Enhanced dielectric
properties of electrospun titanium
dioxide/polyvinylidene fluoride nanofibrous
composites. Fibers and Polymers, 14(9),
1521‐1525.
Coskun, D., Ahmedzade, M., 2008. 3‐(Substituted
aryl)‐1‐(benzofuran‐2‐yl)‐2‐propenones, Part
1: synthesis and characterization of some
novel chalcones. Synthetic Communications,
38, 3613‐3622.
Bezgin, F., 2011. Synthesis of polymers containing
coumarin spectroscopic and dielectric
properties. PhD Thesis, University of Firat
Graduate School of Sciences, Elazig.
Singh, K.P., Gupta, P.N., 1998. Study of dielectric
relaxation in polymer electrolytes. European
Polymer Journal, 34, 1023‐1029.
Rao, V., Ashokan, P.V., Shridhar, M.H., 2000.
Studies of dielectric relaxation and ac
conductivity in cellulose acetate hydrogen
Polymersphthalate–poly (methyl methacrylate)
blends. Materials Sciences and Engineering:
A, 281, 213‐220.
Selvam, P., Babu, K.V., Penlidis, A., Nanjundan, S.,
2005. Studies on photocrosslinkable
copolymers of 4‐methacryloyloxyphenyl‐3 ',4
'‐dimethoxystyryl ketone and methyl
methacrylate. European Polymer Journal,
41, 831‐841.
Balaji, R., Grande, D., Nanjundan, S., 2004.
Photoresponsive polymers having pendant
chlorocinnamoyl moieties: synthesis,
reactivity ratios and photochemical
properties. Polymer, 45, 1089‐1099.
Unal, M., 2008. Some Benzimidazole Derivative
Fluorimetric Investigation of Properties. Ph
Thesis, University of Selcuk Graduate School
of Sciences, Konya.
Bu çalışmada, (1‐benzofuran‐2‐il)’ in vanilin ile reaksiyonundan (1‐benzofuran‐2‐il)‐3‐(4‐ hidroksi‐3‐metoksifenil)prop‐2‐en‐1‐on sentezlendi. Sentezlenen bu bileşik ile ticari olarak hazır alınan metakriloilklorür ile açilleme reaksiyonundan (1‐benzofuran‐2‐il)‐3‐okso‐prop‐1‐ en‐1‐il]‐2‐metoksifenil 2‐metilakrilat monomeri sentezlendi. Homopolimer ve kopolimerlerin hazırlanmasında serbest radikalik polimerizasyon ve atom transfer radikal polimerizasyon metodları kullanıldı. Yapı karakterizasyonunda ağırlıklı olarak FT‐IR, 1H ve 13C‐NMR teknikleri kullanıldı. Polimerlerin termal davranışları karşılaştırmalı olarak DSC ve TGA ile ölçüldü ve sonuçlar birbirleriyle karşılaştırıldı. Ortalama molekül ağırlıkları ve polidispersiteleri GPC ile ölçüldü. Sıcaklık ve frekansın bir fonksiyonu olarak polimerlerin dielektrik davranışları incelendi ve yapılarıyla ilişkilendirildi. Polimerlerin spektroskopik özellikleri UV‐Vis ve floresans spektroskopileriyle araştırıldı. Floresans spektroskopisiyle emisyon ölçümleri üzerine çözücü polarlığının etkisi araştırıldı. Kalkonun dimerleşme özelliğinden yararlanılarak kalkon uçlu polimer fotodimerleştirildi.
Jeong, J.W., Kwon, Y., Han, Y.S., Park, L.S., 2005.
Electroluminescent property and
photolithographic process of photosensitive
random copolymers. Molecular Crystals and
Liquid Crystals, 443, 59‐68.
Zhang, L.Z., Li, Y., Liang, Z.X., Yu, Q.S., Cai, Z.G.,
1999. New crosslinked polymer systems with
high and stable optical nonlinearity. Reactive
and Functional Polymer, 40, 255‐262.
Mizoguchi, K., Hasegawa, E., 1996. Photoactive
polymers applied to advanced
microelectronic devices. Polymers for
Advanced Technologies, 7, 471‐477.
Song, D.M., Jung, K.H., Moon, J.H., Shin, D.M.,
2002. Photochemistry of chalcone and the
application of chalcone‐derivatives in photoalignment
layer of liquid crystal display.
Optical Materials, 21, 667‐671.
Allen, N.S., Khan, L., Edge, M., Billings, M., Vercs,
J., 1998. Studies on UV and thermally radical
induced cross‐linked polymer networks as
charge‐transport layers in
electrophotographic coating applications.
Journal of Photochemistry and Photobiology
A: Chemistry, 116, 235‐244.
Trenor, S.R., Shultz, A.R., Love, B.J., Long, T.E.,
2004. Coumarins in polymers: from light
harvesting to photo‐cross‐linkable tissue
scaffolds. Chemical Reviews, 104, 3059‐3077.
Tamilvanan, M., Pandurangan, A., Reddy, B.S.R.,
Subramanian, K., 2007. Synthesis,
characterization and properties of
photoresponsive polymers comprising
photocrosslinkable pendant chalcone
moieties. Polymer International, 56, 104‐
111.
Santhi, R., Babu, K.V., Penlidis, A., Nanjundan, S.,
2006. Studies on copolymers of 3‐
methacryloyloxystyryl‐4′‐methylphenyl
ketone and methyl methacrylate. Reactive &
Functional Polymers, 66, 1215‐1226.
Park, H.H., Choi, Y., Park, D.J., Cho, S.Y., Yun, Y.S.,
Jin, H.J., 2013. Enhanced dielectric
properties of electrospun titanium
dioxide/polyvinylidene fluoride nanofibrous
composites. Fibers and Polymers, 14(9),
1521‐1525.
Coskun, D., Ahmedzade, M., 2008. 3‐(Substituted
aryl)‐1‐(benzofuran‐2‐yl)‐2‐propenones, Part
1: synthesis and characterization of some
novel chalcones. Synthetic Communications,
38, 3613‐3622.
Bezgin, F., 2011. Synthesis of polymers containing
coumarin spectroscopic and dielectric
properties. PhD Thesis, University of Firat
Graduate School of Sciences, Elazig.
Singh, K.P., Gupta, P.N., 1998. Study of dielectric
relaxation in polymer electrolytes. European
Polymer Journal, 34, 1023‐1029.
Rao, V., Ashokan, P.V., Shridhar, M.H., 2000.
Studies of dielectric relaxation and ac
conductivity in cellulose acetate hydrogen
Polymersphthalate–poly (methyl methacrylate)
blends. Materials Sciences and Engineering:
A, 281, 213‐220.
Selvam, P., Babu, K.V., Penlidis, A., Nanjundan, S.,
2005. Studies on photocrosslinkable
copolymers of 4‐methacryloyloxyphenyl‐3 ',4
'‐dimethoxystyryl ketone and methyl
methacrylate. European Polymer Journal,
41, 831‐841.
Balaji, R., Grande, D., Nanjundan, S., 2004.
Photoresponsive polymers having pendant
chlorocinnamoyl moieties: synthesis,
reactivity ratios and photochemical
properties. Polymer, 45, 1089‐1099.
Unal, M., 2008. Some Benzimidazole Derivative
Fluorimetric Investigation of Properties. Ph
Thesis, University of Selcuk Graduate School
of Sciences, Konya.
Coşkun, M. F., Şentürk, A., & Coşkun, D. (2016). Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 16(2), 230-238.
AMA
Coşkun MF, Şentürk A, Coşkun D. Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. Nisan 2016;16(2):230-238.
Chicago
Coşkun, Mehmet Fatih, Adem Şentürk, ve Demet Coşkun. “Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 16, sy. 2 (Nisan 2016): 230-38.
EndNote
Coşkun MF, Şentürk A, Coşkun D (01 Nisan 2016) Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 16 2 230–238.
IEEE
M. F. Coşkun, A. Şentürk, ve D. Coşkun, “Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, c. 16, sy. 2, ss. 230–238, 2016.
ISNAD
Coşkun, Mehmet Fatih vd. “Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 16/2 (Nisan 2016), 230-238.
JAMA
Coşkun MF, Şentürk A, Coşkun D. Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2016;16:230–238.
MLA
Coşkun, Mehmet Fatih vd. “Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, c. 16, sy. 2, 2016, ss. 230-8.
Vancouver
Coşkun MF, Şentürk A, Coşkun D. Synthesis, Characterization of Chalcone Containing Methacrylate Polymers: Investigation of Fluorescence, Thermal and Dielectric Properties. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2016;16(2):230-8.