Alümina Takviyeli Alüminyum Esaslı Kompozit Malzemelerin Polipirol ile Kaplanması ve Korozyon Davranışının İncelenmesi
Yıl 2020,
Cilt: 20 Sayı: 1, 118 - 128, 17.03.2020
Kubilay Karacif
,
Hasan Karabulut
Öz
Bu
çalışmada, alümina (Al2O3) takviyeli alüminyum esaslı toz
metal kompozit malzemeler, korozyon dayanımını geliştirmek amacıyla iletken
polimer polipirol (Ppy) ile kaplanmış ve yapılan kaplama işleminin kompozit
malzemenin korozyon davranışına etkileri incelenmiştir. Toz metalürjisi yöntemi
ile üretilen alüminyum esaslı kompozit malzemenin polipirol kaplama işlemi,
elektrokimyasal yöntem ile potansiyel taraması uygulanarak yapılmıştır.
Kaplamasız ve dört farklı sayıda potansiyel taraması yapılarak polipirol
kaplanan alümina takviyeli alüminyum esaslı kompozit numunelere tuzlu ortamında
potansiyodinamik yöntem ile elektrokimyasal korozyon testleri uygulanmıştır.
Çalışma sonucunda, alümina takviyeli
alüminyum esaslı kompozit malzemenin uygun şartlar altında elektrokimyasal
yöntem kullanılarak polipirol ile kaplanabildiği ve yapılan kaplamanın kompozit
malzemenin korozyon dayanımını geliştirdiği belirlenmiştir.
Kaynakça
- Akundy G.S. and Iroh J.O., 2001. Polypyrrole coatings on aluminum synthesis and characterization. Polymer, 42, 9665–9669.
- Arenas M.A., Bajos L.G., Damborenea J.J. and Ocon P., 2008. Synthesis and electrochemical evaluation of polypyrrole coatings electrodeposited onto AA-2024 alloy. Progress in Organic Coatings, 62, 79–86.
- Balaskas A.C., Kartsonakis I.A., Kordas G., Cabral A.M. and Morais P.J., 2011. Influence of the doping agent on the corrosion protection properties of polypyrrole grown on aluminium alloy 2024-T3. Progress in Organic Coatings, 71, 181–187.
- Dobrzanski L.A., Wlodarczyk A. and Adamiak M., 2005. Structure, properties and corrosion resistance of PM composite materials based on EN AW-2124 aluminum alloy reinforced with the Al2O3 ceramic particles. Journal of Materials Processing Technology, 162, 27–32.
- Durai T.G., Das K. and Das S., 2008. Corrosion behavior of Al-Zn/Al2O3 and Al–Zn–X/Al2O3 composites synthesized by mechanical–thermal treatment. Journal of Alloys and Compounds, 462, 410–415.
- Ghanaraja S., Vinuth Kumar K.L., Raju H.P. and Ravikumar K.S., 2015. Processing and mechanical properties of hot extruded Al (Mg)-Al2O3 composites. Materials Today: Proceedings, 2, 1291–1300.
- Ghanaraja S., Vinuth Kumar K.L., Ravikumar K.S.and Madhusudan B.M., 2017. Mechanical properties of Al2O3 reinforced cast and hot extruded Al based metal matrix composites. Materials Today: Proceedings, 4, 2771–2776.
- Joseph S., McClure J.C., Sebastian P.J., Moreira J. and Valenzuela E., 2008. Polyaniline and polypyrrole coatings on aluminum for PEM fuel cell bipolar plates. Journal of Power Sources, 177, 161–166.
- Jun D., Liu Y.H., Yu S.R. and Li W.F., 2004. Dry sliding friction and wear properties of Al2O3 and carbon short fibres reinforced Al-12Si alloy hybrid composites. Wear, 257, 930–940.
- Kumara A.M., Babu R.S., Ramakrishna S. and Barros A.L.F., 2017. Electrochemical synthesis and surface protection of polypyrrole-CeO2 nanocomposite coatings on AA2024 alloy. Synthetic Metals, 234, 18–28.
- Lehr I.L. and Saidman S.B., 2006. Characterisation and corrosion protection properties of polypyrrole electropolymerised onto aluminium in the presence of molybdate and nitrate. Electrochimica Acta, 51, 3249–3255.
- Lehr I.L. and Saidman S.B., 2006. Electrodeposition of polypyrrole on aluminium in the presence of sodium bis (2–ethylhexyl) sulfosuccinate. Materials Chemistry and Physics, 100, 262–267.
- Martins J.I., Costa S.C., Bazzaoui M., Gonçalves G., Fortunato E. and Martins R., 2006. Electrodeposition of polypyrrole on aluminium in aqueous tartaric solution. Electrochimica Acta, 51, 5802–5810.
- Martins N.C.T., Moura Silva T., Montemor M.F., Fernandes J.C.S. and Ferreira M.G.S., 2008. Electrodeposition and characterization of polypyrrole films on aluminium alloy 6061–T6. Electrochimica Acta, 53, 4754–4763.
- Mert B.D., 2016. Corrosion protection of aluminum by electrochemically synthesized composite organic coating. Corrosion Science, 103, 88–94.
- Mert B. D. and Yazıcı B., 2011. The electrochemical synthesis of poly(pyrrole-co-o-anisidine) on 3102 aluminum alloy and its corrosion protection properties. Materials Chemistry and Physics, 125, 370–376.
- Mert B.D., Solmaz R., Kardas G. and Yazıcı B., 2011. Copper/polypyrrole multilayer coating for 7075 aluminum alloy protection. Progress in Organic Coatings, 72, 748–754.
- Mrad M., Dhouibi L., Montemor M.F. and Triki E., 2011. Effect of doping by corrosion inhibitors on the morphological properties and the performance against corrosion of polypyrrole electrodeposited on AA6061-T6. Progress in Organic Coatings, 72, 511–516.
- Paloumpa I., Yfantis A., Hoffmann P., Burkov Y., Yfantis D. and Schmeißer D., 2004. Mechanisms to inhibit corrosion of Al alloys by polymeric conversion coatings. Surface and Coatings Technology, 180–181, 308–312.
- Riahi A.R. and Alpas A.T., 2001. The role of tribo-layers on the sliding wear behavior of graphitic aluminum matrix composites. Wear, 251, 1396–1407.
- Saidman S.B. and Bessone J.B., 2002. Electrochemical preparation and characterisation of polypyrrole on aluminium in aqueous solution. Journal of Electroanalytical Chemistry, 521, 87–94.
- Saraswathi Y.L., Das S. and Mondal D.P., 2006. Influence of microstructure and experimental parameters on the erosion-corrosion behavior of Al alloy composites. Materials Science and Engineering A 425, 244–254.
- Shimizu Y., Nishimura T. and Matsushima I., 1995. Corrosion resistance of Al–based metal matrix composites. Materials Science and Engineering A, 198, 113–118.
- Tallman D.E., Levine K.L., Siripirom C., Gelling V. G., Bierwagen G.P. and Croll S.G., 2008. Nanocomposite of polypyrrole and alumina nanoparticles as a coating filler for the corrosion protection of aluminium alloy 2024–T3. Applied Surface Science, 254, 5452–5459.
- Tsirimpis A., Kartsonakis I., Danilidis I., Liatsi P. and Kordas G., 2010. Synthesis of conductive polymeric composite coatings for corrosion protection applications. Progress in Organic Coatings, 67, 389–397.
- Zhu J. and Hihara L.H., 2010. Corrosion of continuous alumina-fibre reinforced Al–2 wt.% Cu-T6 metal matrix composite in 3.15 wt.% NaCl solution. Corrosion Science, 52, 406–415.