Kaolin Yüzeyine Dekore Edilmiş Bakır Katkılı Çinko Oksit Nanokompoziti Kullanılarak Reaktif Mavi 21 Tekstil Boyar Maddesinin Adsorpsiyonu, Kinetiği ve Termodinamiği

Yıl 2023, Cilt: 23 Sayı: 3, 753 - 771, 28.06.2023

Eda Keleş Güner , Agah Özdemir , Bilge Doğan , Bülent Çağlar

https://doi.org/10.35414/akufemubid.1173331

Öz

Bu çalışmanın amacı; tekstil endüstrisinde yaygın olarak kullanılan bir boyarmadde olan Reaktif Mavi 21 (RM21)’in atık sulardan adsorpsiyon yöntemiyle uzaklaştırılmasında kaolin yüzeyine dekore edilmiş bakır katkılı çinko oksit nanokompozitinin adsorban olarak kullanılabilirliğinin araştırılmasıdır. Adsorpsiyon üzerine, başlangıç RM21 konsantrasyonu, adsorban miktarı, sıcaklık ve denge süresi gibi çeşitli deneysel parametrelerin etkileri incelenmiştir. Adsorpsiyon hızının ikinci mertebeden hız ifadesine uyduğu ve kaolin yüzeyine dekore edilmiş bakır katkılı çinko oksit nanokompozitinin RM21 üzerine adsorpsiyonunun Redlich-Peterson izoterm modeliyle uyum sağladığı görülmüştür. Bu çalışmanın sonuçları, RM21’nin sulu çözeltilerden uzaklaştırılmasında kaolin yüzeyine dekore edilmiş bakır katkılı çinko oksit nanokompozitinin etkili bir adsorban olarak kullanılabileceğini göstermiştir.

Anahtar Kelimeler

adsorpsiyon, boyar madde, reaktif mavi 21, bakır oksit, çinko oksit

Adsorption, Kinetics and Thermodynamics of Reactive Blue 21 Textile Dyestuff Using Copper Doped Zinc Oxide Nanocomposite Decorated on Kaolin Surface

Öz

The aim of this study is to investigate the usability of copper-doped zinc oxide nanocomposite decorated on kaolin surface as an adsorbent in the removal of Reactive Blue 21 (RM21), a widely used dyestuff in the textile industry, from wastewater by adsorption method. The effects of various experimental parameters such as initial RM21 concentration, amount of adsorbent, temperature and equilibrium time on adsorption were investigated. It was observed that the adsorption rate matched the second-order rate expression and the adsorption of copper-doped zinc oxide nanocomposite decorated on the kaolin surface on RM21 was consistent with the Redlich-Peterson isotherm model. The results of this study showed that copper doped zinc oxide nanocomposite decorated on kaolin surface can be used as an effective adsorbent in the removal of RM21 from aqueous solutions.

Anahtar Kelimeler

adsorption, dyestuff, reactive blue 21, copper oxide, zinc oxide

Kaynakça

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