The Green Inhibitive Effect of Ptychostomum schleicheri (Bryophyta) Extract on Mild Steel Corrosion

Yıl 2022, Cilt: 8 Sayı: 2, 114 - 122, 30.11.2022

Demet Özkır

https://doi.org/10.26672/anatolianbryology.1193546

Cited By: 2

Öz

In present study, the inhibitive impact of Ptychostomum schleicheri extract, a moss species of Bryaceae family, on the mild steel corrosion in 1 M HCl at ambient temperature was firstly analysed by Tafel extrapolation method, electrochemical impedance spectroscopy (EIS) and linear polarization (LPR) techniques. Electrochemical tests were conducted by 1 h immersing mild steels in HCl solutions containing four various concentrations of moss extract. At a concentration of 0.200% (w/v), the moss extract displayed around 90 percent inhibition efficiency by three electrochemical methods, and it was also observed that its protective effect increased depending on the upsurge in the concentration of Ptychostomum schleicheri extract. The morphologies of mild steels surface in 1 M HCl with and without P. schleicheri extract at the end of 1 h immersion time were visualized by a metal microscope. Finally, according to the electrochemical data and surface morphology results, it can be said that the extract molecules adsorbed on the mild steel surface to achieve almost maximal coverage and contact.

Anahtar Kelimeler

Bryaceae, Ptychostomum schleicheri, Eco-friendly inhibitor, Corrosion, Metal microscope

Teşekkür

The author would like to thank, in the process of providing and identifying the Ptychostomum schleicheri material to Prof. Dr. Tülay Ezer, and also to Prof. Dr. Tuncay Türkeş and Prof. Dr. Osman Seyyar for photographed in their laboratory of the P. schleicheri material.

Ptychostomum schleicheri (Bryophyta) Ekstraktının Yumuşak Çeliğin Korozyonu Üzerine Yeşil Önleyici Etkisi

Öz

Bryaceae familyasının bir yosun türü olan Ptychostomum schleicheri ekstraktının 1 M HCl içerisindeki yumuşak çeliğin korozyonu üzerine önleyici etkisi, oda sıcaklığında Tafel ekstrapolasyon yöntemi, lineer polarizasyon (LPR) ve elektrokimyasal impedans spektroskopisi (EIS) yöntemleri ile ilk kez, mevcut çalışmada analiz edilmiştir. Elektrokimyasal deneyler, dört farklı derişimde yosun ekstraktı içeren HCl çözeltilerine, yumuşak çeliklerin 1 saat daldırılması ile gerçekleştirilmiştir. % 0,200 (w/v) derişiminde yosun ekstraktı, üç elektrokimyasal yöntemle yüzde 90 civarında inhibisyon etkinliği göstermiş ve ayrıca Ptychostomum schleicheri ekstraktının derişiminin artmasına bağlı olarak, koruyucu etkisinin de arttığı gözlemlenmiştir. Yosun ekstraktı içeren ve içermeyen 1 M HCl içerisindeki yumuşak çeliklerin yüzey morfolojileri, 1 saatlik daldırma süresinin sonunda metal mikroskobu yardımıyla görüntülenmiştir. Son olarak, elektrokimyasal veriler ve yüzey morfolojisi sonuçlarına göre, ekstrakt moleküllerinin yumuşak çelik yüzeyine neredeyse maksimum kaplama ve temas elde etmek için adsorplandığı söylenebilir.

Anahtar Kelimeler

Bryaceae, Ptychostomum schleicheri, Çevre-dostu inhibitör, Korozyon, Metal mikroskopu

Kaynakça

• Abdul Aziz M.A.A. Hamzah E. Selamat M. 2022. Performances of plant based corrosion inhibitors in controlling corrosion of mild steel in sodium chloride environment. Mater. Today: Proc. 51: 1344-1349.
• Allaoui M. Rahim O. Sekhri L. 2017. Electrochemical Study on Corrosion Inhibition of Iron in Acidic Medium by Moringa Oleifera Extract. Orient. J. Chem. 33:2, 637-646.
• Deyab M.A. Mohsen Q. Guo L. 2022. Aesculus hippocastanum seeds extract as eco-friendly corrosion inhibitor for desalination plants: Experimental and theoretical studies. J. Mol. Liq. 361: 119-594.
• Du P. Deng S. Li X. 2022. Mikania micrantha extract as a novel inhibitor for the corrosion of cold rolled steel in Cl2HCCOOH solution. J. Mater. Res. Technol. 19: 2526-2545.
• Ehsani A. Mahjani M.G. Hosseini M. Safari R. Moshrefi R. Shiri H.M. 2017. Evaluation of Thymus vulgaris plant extract as an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by means of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory. J. Colloid Interf. Sci. 490: 444-451.
• Fang Y. Suganthan B. Ramasamy R.P. 2019. Electrochemical characterization of aromatic corrosion inhibitors from plant extracts. J. Electroanal. Chem. 840: 74-83.
• Haldhar R. Prasad D. Bhardwaj N. 2019. Extraction and experimental studies of Citrus aurantifolia as an economical and green corrosion inhibitor for mild steel in acidic media. J. Adhes. Sci. Technol. 33: 1169–1183.
• Huang L. Zhao Q. Li H-J. Wang J-Y. Wang X-Y. Wu Y-C. 2022a. Investigation of adsorption and corrosion inhibition property of Hyperoside as a novel corrosion inhibitor for Q235 steel in HCl medium. J. Mol. Liq. 364: 120009.
• Huang L. Wang Z-M. Wang S-S. Wang Y-H. Li H-J. Wu Y-C. 2022b. Environmentally benign cinchonain IIa from Uncaria laevigata for corrosion inhibition of Q235 steel in HCl corrosive medium: Experimental and theoretical investigation. Environ. Res. 215:2, 114376.
• Kalkhambkar A.G. Rajappa S.K. Manjanna J. Malimath G.H. 2022. Saussurea obvallatta leaves extract as a potential eco-friendly corrosion inhibitor for mild steel in 1 M HCl. Inorg. Chem. Commun. 143: 109799.
• Kumar C.B.P. Mohana K.N. 2014. Phytochemical screening and corrosion inhibitive behavior of Pterolobium hexapetalum and Celosia argentea plant extracts on mild steel in industrial water medium. Egypt. J. Pet. 23: 201-211.
• Kumar P. Soni I. Jayaprakash G.K. Kumar S. Rao S. Flores-Moreno R. Sowmyashree A.S. 2022. Experimental and theoretical studies of hexylmeythylimidazolium tetrafluoroborate ionic liquid as cathodic corrosion inhibitor for mild steel. Inorg. Chem. Commun. 146: 110110.
• Mehta R.K. Gupta S.K. Yadav M. 2022. Studies on pyrimidine derivative as green corrosion inhibitor in acidic environment: Electrochemical and computational approach. J. Environ. Chem. Eng. 10: 108499. Mobin M. Basik M. Aslam J. 2019. Pineapple stem extract (Bromelain) as an environmental friendly novel corrosion inhibitor for low carbon steel in 1 M HCl. Measurement.134: 595-605.
• Özkır D. Ezer T. 2020. A New Inhibitor Approach to the Corrosion of Mild Steel in Acidic Solution with Long-Term Impedance Tests: A New Application Area for Hypnum cupressiforme (Bryophyta). Anatolian Bryology. 6:2: 119-128.
• Özkır D. Kayakırılmaz K. 2020. The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel. J. Electrochem. Sci. Technol. 11:3, 257-272.
• Özkır D. 2021a. An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution. Anatolian Bryol. 7:2, 119-130.
• Popoola L.T. 2019. Progress on pharmaceutical drugs, plant extracts and ionic liquids as corrosion inhibitors. Heliyon. 5: e01143.
• Ramezanzadeh M. Sanaei Z. Bahlakeh G. Ramezanzadeh B. 2018. Highly effective inhibition of mild steel corrosion in 3.5% NaCl solution by green nettle leaves extract and synergistic effect of eco-friendly cerium nitrate additive: experimental, MD simulation and QM investigations. J. Mol. Liq. 256: 67-83.
• Shaw A.J. Szövényi P. Shaw B. 2011. Bryophyte Diversity And Evolution: Windows Into The Early Evolution Of Land Plants, American Journal of Botany. 98:3, 352–369.
• Tripathy D.B. Murmu M. Banerjee P. Quraishi M.A. 2019. Palmitic acid based environmentally benign corrosion inhibiting formulation useful during acid cleansing process in MSF desalination plants. Desalination. 472: 114128.
• Umoren S.A. Solomon M.M. Obot I.B. Suleiman R.K. 2019. A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals. J. Ind. Eng. Chem. 76: 91-115.
• URL1. https://www.britishbryologicalsociety.org.uk/learning/about-bryophytes/ [Accessed: 18 October 2022].
• Wang Q. Zheng H. Liu L. Zhang Q. Wu X. Yan Z. Sun Y. Li X. 2022. Insight into the anti–corrosion behavior of Reineckia Carnea leaves extract as an eco–friendly and high–efficiency corrosion inhibitor. Ind. Crop. Prod. 188: 115640.