Adsorption kinetics of montmorillonite clay and basic orange 2 dyestuff

Öz

In this study, the adsorption kinetics of BO2 (Basic Orange2) dyestuff on montmorillonite clay was investigated. The experiments were carried out in batch mode. Adsorption kinetics studies were investigated under the influence of parameters such as initial dyestuff concentration, initial pH value, mixing speed, adsorbent dose and ion concentration. The compatibility of the experimental data with pseudo-first-order, pseudo-second-order, Elovich and intra-particle adsorption kinetic models were investigated. It was determined that the adsorption kinetic data of BO2 dyestuff on the montmorillonite surface were consistent with the pseudo-second order kinetics. It was determined that the adsorption rate increased with increasing pH, mixing speed and ion concentration, and decreased with the initial dye concentration and adsorbent dose. It reveals that montmorillonite is a suitable low-cost adsorbent for the removal of cationic dyestuffs such as BO2.

Anahtar Kelimeler

• Montmorillonite
• Adsorption kinetic
• basic orange2 (BO2)

Montmorillonit kili ile basic orange 2 boyar maddesinin adsorpsiyon kinetiği

Öz

Bu çalışmada, BO2 (Basic Orange2) boyar maddesinin montmorillonit kili üzerinde adsorpsiyon kinetiği araştırılmıştır. Deneyler kesikli modda gerçekleştirilmiştir. Adsorpsiyon kinetiği çalışmaları başlangıç boyar madde konsantrasyonu, başlangıç pH değeri, karıştırma hızı, adsorbent dozu ve iyon konsantrasyonu gibi parametrelerin etkisi altında araştırılmıştır. Deneysel verilerin yalancı birinci mertebe, yalancı ikinci mertebe, Elovich ve parçacık içi adsorpsiyon kinetik modellerine uyumluluğu araştırılmıştır. Montmorillonit yüzeyinde BO2 boyar maddesinin adsorpsiyon kinetiğini verilerinin yalancı ikinci mertebe kinetiğine uyum gösterdiği belirlenmiştir. Adsorpsiyon hızının artan pH, karıştırma hızı ve iyon konsantrasyonu ile arttığı, başlangıç boyar madde konsantrasyonu ve adsorbent dozu ile azaldığı belirlenmiştir. Montmorillonitin BO2 gibi katyonik boyar maddelerin uzaklaştırılması için uygun düşük maliyetli adsorbent olduğunu ortaya koymaktadır.

Anahtar Kelimeler

• Montmorillonit
• Adsorpsiyon kinetiği
• basic orange2 (BO2)

Kaynakça

1. Doh-Ura, K., Tamura, K., Karube, Y., Naito, M., Tsuruo, T., Kataoka, Y., Chelating compound, chrysoidine, is more effective in both antiprion activity and brain endothelial permeability than quinacrine. Cellular and molecular neurobiology, 27, 3, 303-316, (2007).
2. Gui, W.J., Xu, Y., Shou, L.F., Zhu, G.N., Ren, Y.P., Liquid chromatography-tandem mass spectrometry for the determination of chrysoidine in yellow-fin tuna. Food Chemistry, 122, 1230-1234, (2010).
3. Tonogai, Y., Ogawa, S., Ito, Y., Iwaida, M., Actual survey on TLm (median tolerance limit) values of environmental pollutants, especially on amines, nitriles, aromatic nitrogen compounds and artificial dyes. The Journal of Toxicological Sciences, 7, 3, 193-203, (1982).
4. Reyns, T., Fraselle, S., Laza, D., Van Loco, J., Rapid method for the confirmatory analysis of chrysoidine in aquaculture products by ultra-performance liquid chromatography-tandem mass spectrometry. Biomedical chromatography, 24, 982-989, (2010).
5. Farizoğlu, B., Fil, B.A., Uzuner, S., Bıçakcı, S., Er, E., Kara, E.N., Reactive black 5 removal with electro-oxidation method using ti/ıro2/ruo2 anode and stainless steel cathode. International Journal of Electrochemical Science, 13, 4, 3288-3296, (2018).
6. Gautam, K., Kamsonlian, S., Kumar, S., Removal of Reactive Red 120 dye from wastewater using electrocoagulation: optimization using multivariate approach, economic analysis, and sludge characterization. Separation Science and Technology, 55, 18, 3412-3426, (2020).
7. Ebratkhahan, M., Naghash Hamed, S., Zarei, M., Jafarizad, A., Rostamizadeh, M., Removal of Neutral Red Dye via Electro-Fenton Process: A Response Surface Methodology Modeling. Electrocatalysis, 12, 5, 579-594, (2021).
8. Sözüdoğru, O., Fil, B.A., Boncukcuoğlu, R., Aladağ, E., Kul, S., Adsorptive removal of cationic (BY2) dye from aqueous solutions onto Turkish clay: Isotherm, kinetic, and thermodynamic analysis. Particulate Science and Technology, 34, 1, 103-111, (2016).

9. Yang, D.M., Yuan, J.M., COD and Color Removal from Real Dyeing Wastewater by Ozonation. Water Environment Research, 88, 5, 403-407, (2016).
10. Pan, Y., Zhu, T., He, Z., Enhanced Removal of Azo Dye by a Bioelectrochemical System Integrated with a Membrane Biofilm Reactor. Industrial and Engineering Chemistry Research, 57, 16433– 16441, (2018).
11. Qiu, Q., Jiang, X., Lv, G., Chen, Z., Lu, S., Ni, M., Yan, J., Deng, X., Adsorption of heavy metal ions using zeolite materials of municipal solid waste incineration fly ash modified by microwave-assisted hydrothermal treatment. Powder Technology, 335, 156-163, (2018).
12. Mojoudi, N., Mirghaffari, N., Soleimani, M., Shariatmadari, H., Belver, C., Bedia, J., Phenol adsorption on high microporous activated carbons prepared from oily sludge: equilibrium, kinetic and thermodynamic studies. Scientific Reports, 9, 1, 19352, (2019).
13. Hatch, C.D., Wiese, J.S., Crane, C.C., Harris, K.J., Kloss, H.G., Baltrusaitis, J., Water Adsorption on Clay Minerals As a Function of Relative Humidity: Application of BET and Freundlich Adsorption Models. Langmuir, 28, 3, 1790-1803, (2012).
14. Lagergren, S., About the theory of so-called adsorption of soluble substances. Kungliga svenska vetenskapsakademiens. Handlingar, 24, 4, 1-39, (1898).
15. Ho, Y., McKay, G., The kinetics of sorption of basic dyes from aqueous solution by sphagnum moss peat. The Canadian Journal of Chemical Engineering, 76, 4, 822-827, (1998).
16. Aharoni, C., Tompkins, F., Kinetics of adsorption and desorption and the Elovich equation. Advances in Catalysis, 21, 1-49, (1970).
17. Weber, W.J., Morris, J.C., Kinetics of adsorption on carbon from solution. Journal of the Sanitary Engineering Division, 89, 2, 31-60, (1963).
18. Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., El Albani, A., Barka, N., Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics. Water Resources and Industry, 9, 16-29, (2015).
19. Baskaralingam, P., Pulikesi, M., Elango, D., Ramamurthi, V., Sivanesan, S., Adsorption of acid dye onto organobentonite. Journal of Hazardous Materials, 128, 2, 138-144, (2006).
20. Anirudhan, T.S., Ramachandran, M., Adsorptive removal of basic dyes from aqueous solutions by surfactant modified bentonite clay (organoclay): Kinetic and competitive adsorption isotherm. Process Safety and Environmental Protection, 95, 215-225, (2015).
21. Aladağ, E., Fil, B.A., Boncukcuoğlu, R., Sözüdoğru, O., Yılmaz, A.E., Adsorption of methyl violet dye, a textile industry effluent onto montmorillonite—batch study. Journal of Dispersion Science and Technology, 35, 12, 1737-1744, (2014).
22. Li, Y., Du, Q., Liu, T., Peng, X., Wang, J., Sun, J., Wang, Y., Wu, S., Wang, Z., Xia, Y., Xia, L., Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chemical Engineering Research and Design, 91, 2, 361-368, (2013).
23. Ghazi Mokri, H.S., Modirshahla, N., Behnajady, M.A., Vahid, B., Adsorption of C.I. Acid Red 97 dye from aqueous solution onto walnut shell: kinetics, thermodynamics parameters, isotherms. International Journal of Environmental Science and Technology, 12, 4, 1401-1408, (2015).
24. Ruthiraan, M., Abdullah, E.C., Mubarak, N.M., Noraini, M.N., A promising route of magnetic based materials for removal of cadmium and methylene blue from waste water. Journal of Environmental Chemical Engineering, 5, 2, 1447-1455, (2017).
25. Fil, B.A., Yilmaz, M.T., Bayar, S., Elkoca, M.T., Investigation of adsorption of the dyestuff astrazon red violet 3rn (basic violet 16) on montmorillonite clay. Brazilian Journal of Chemical Engineering, 31, 171-182, (2014).
26. Dogan, M., Özdemir, Y., Alkan, M., Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dyes and Pigments, 75, 3, 701-713, (2007).
27. Ho, Y.S., McKay, G., The kinetics of sorption of basic dyes from aqueous solution by sphagnum moss peat. The Canadian Journal of Chemical Engineering, 76, 822-827, (1998).
28. Ho, Y.S., McKay, G., A comparison of chemisorptions kinetic models applied to pollutant removal on various sorbents. Process Safety and Environmental Protection, 76, 332-340, (1998).
29. Gürses, A., Dogar, Ç., YalçIn, M., AçIkyIldIz, M., Bayrak, R., Karaca, S., The adsorption kinetics of the cationic dye, methylene blue, onto clay. Journal of Hazardous Materials, 131, 1-3, 217-228, (2006).
30. Grégorio, C., Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymer. Dyes and Pigments, 77, 415-426, (2008).
31. Tehrani Bagha, A., Nikkar, H., Mahmoodi, N.M., Menger, F.M., The sorption of cationic dyes onto kaolin: Kinetic, isotherm and thermodynamic studies. Desalination, 266, 274-280, (2011).