BibTex RIS Kaynak Göster

N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini

Yıl 2012, Cilt: 14 Sayı: 2, 7 - 14, 01.12.2012

Öz

N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin yapısı tek kristal X-ışını kristalografisi ile belirlenmiştir. Moleküller arası π···π etkileşimi gözlenememiştir. Kristal paketlenmesi sadece zayıf π···H-C etkileşimleriyle kararlılaştırılmıştır. Hesaplanan bağ uzunlukları ve bağ açıları X-ışını kırınım analizinden elde edilen değerlerle karşılaştırılmıştır. Molekülde N1-N1’ bağ uzunlukları ve bu atomlar etrafındaki bağ açılarının dışındaki diğer deneysel ve hesaplanan değerler arasında iyi bir uyum görünmektedir

Kaynakça

  • [1] Hirschfeld, S., Assaying for a multiplicity of antigens or antibodies with a detection compound, US Patent 4514508 (1985).
  • [2] Otieno, M. A., Baggs, R. B., Hayes J. D., Anders, M. W., Immunolocalization of microsomal glutathiones-transferase in Rat Tissues, Drug Metabolism and Disposition, 25, 12-20, (1997).
  • [3] Haq, M. R., Kalatzis, V., Gubler, M. C., Town, M. M., Antignac, C., Van't Hoff W. G., Woolf, A. S., Immunolocalization of cystinosin, the protein defective in cystinosins, Journal of the American Society of Nephrology, 13, 2046-2051, (2002).
  • [4] Comas, T. C., Tai, T., Kimmel, D., Scheithauer, B. W., Burger, P. C., Pearl, D. K., Jewell S. D., Yates, A. J., Immunohistochemical staining for ganglioside GD1b as a diagnostic and prognostic marker for primary human brain tumors, Neuro-oncology, 1, 261-267, (1999).
  • [5] Peciuraite, V., Vaitkeviciene, V., Grigalevicius, S., Grazulevicius J. V., Jankauskas V., Di(9-alkylcarbazol-3-yl)arylamines as electroactive amorphous materials for optoelectronics, Monatshefte für Chemie, 137, 1053-1062, (2006).
  • [6] Puodziukynaite, E., Burbulis, E., Grazulevicius, J. V., Getautis V., Jankauskas J., Carbazole-based bis(enamines) as effective charge-transporting amorphous molecular materials, Synthetic Metals, 158, 993-998, (2008).
  • [7] Mishra, A. K., Jacob J., Mullen, K., Synthesis of aminocarbazole-anthraquinone fused dyes and polymers, Dyes and Pigments, 75, 1-10, (2007).
  • [8] Gibson, H. W., Olin G. R., Pochan, J. M., Linear free energy relationships. Part 10. Synthesis, thermal, spectral, electrochemical, and hole transport (conduction) properties of some novel carbazole derivatives, Journal of Chemical Society, Perkin Transactions II, 1267-1273, (1981).
  • [9] Grigoras, M.; Antonoaia, N.C., Synthesis and characterization of some carbazolebased imine polymers, European Polymer Journal, 41, 1079-1089, (2005).
  • [10] Segura, J. L., The chemistry of electroluminescent organic materials, Acta Polymerica, 1998, 49, 319-344, (1998).
  • [11] SIR92 - Altomare, A., Cascarano, G., Giacovazzo C., Guagliardi, A., Completion and refinement of crystal structures with SIR92, Journal of Applied Crystallography, 26, 343-350, (1993).
  • [12] Sheldrick, G. M., SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, (1997).
  • [13] Farrugia, L. J., WinGX suite for small-molecule single-crystal crystallography, Journal of Applied Crystallography, 32, 837-838, (1999).
  • [14] Burkert, U., Allinger, N. L., Molecular Mechanics, ACS Monograph, No. 177 (1982).
  • [15] Allinger, N. L., Conformational analysis. 130. MM2. A hydrocarbon force field utilizing V1 and V2 torsional terms, Journal of the American Chemical Society, 99, 8127-8134, (1977).
  • [16] Dewar, M. J. S.; Zoebisch, E. G.; Healey E. F.; Stewart, J. J. P., Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model, Journal of the American Chemical Society, 107, 3902-3909, (1985).
  • [17] HyperChem 8.05 for Windows, Hypercube Inc., 1115 NW 4th Street, Gainesville, FL 32601, USA., (2008).
  • [18] Asker, E., Masnovi, J.,1,3-Bis(9-ethylcarbazol-3-yl)propane, Acta Crystallographica Section E, 61, o2781-o2783, (2005).
  • [19] Hang, Y.-C., Chen M.-D., Wang Y., 9-Ethyl-3-(2-methylbenzoyl)-9 H-carbazole, Acta Crystallographica Section E, E65, o279, (2009).
  • [20] Portilla, J., Cobo, J., de la Torre, J. M., Low J. N., Glidewell, C., N,N’- Bis(isonicotinoyl)hydrazine dihydrate at 120 (2) K: a three-dimentional framework built from N-H…O, O-H…O, O-H…N and C-H…O hydrogen bonds, Acta Crystallographica Section E, E63, o1687-o1690, (2007).
  • [21] Zheng P.-W., Zhao B., N,N’-Bis(9-anthracenylidene)hydrazine, Acta Crystallographica Section E, E62, o2077-o2078, (2006).
  • [22] Nesterov, V. V., Antipin, M. Y., Nesterov, V. N., Penn, B. G., Frazier D. O., Timofeeva T. V., Thermally stable imines as new potential nonlinear optical materials, Crystal Growth & Design, 4, 521-531, (2004).
  • [23] a) Asker E., Masnovi, J., 9,9’-Diethyl-3,3’-di-9H-carbazolyl, Acta Crystallographica Section E, 2006, E62, o1133o1135, (2006); b) Asker E.; Masnovi, Bis(-ethylcarbazol-3yl)ethane, Acta Crystallographica Section E, 2006, E62, o1213-o1215, (2006).

Single Crystal X-ray Structure Determination of N,N’-di(9-ethyl-9H-carbazole-3-yl)hydrazine

Yıl 2012, Cilt: 14 Sayı: 2, 7 - 14, 01.12.2012

Öz

The structure of N,N’-di(9-ethyl-9H-carbazole-3-yl)hydrazine has been determined by single crystal X-ray crystallography. No π···π interactions were observed among the molecules. The crystal packing is stabilized only by the week π···H-C interactions. The calculated values of the bond lengths and bond angles have been compared with those obtained from X-ray diffraction analyses. There is a good agreement between experimental and calculated values of the data, except the N1-N1 bond length and the angles around these atoms in the molecule. ’

Kaynakça

  • [1] Hirschfeld, S., Assaying for a multiplicity of antigens or antibodies with a detection compound, US Patent 4514508 (1985).
  • [2] Otieno, M. A., Baggs, R. B., Hayes J. D., Anders, M. W., Immunolocalization of microsomal glutathiones-transferase in Rat Tissues, Drug Metabolism and Disposition, 25, 12-20, (1997).
  • [3] Haq, M. R., Kalatzis, V., Gubler, M. C., Town, M. M., Antignac, C., Van't Hoff W. G., Woolf, A. S., Immunolocalization of cystinosin, the protein defective in cystinosins, Journal of the American Society of Nephrology, 13, 2046-2051, (2002).
  • [4] Comas, T. C., Tai, T., Kimmel, D., Scheithauer, B. W., Burger, P. C., Pearl, D. K., Jewell S. D., Yates, A. J., Immunohistochemical staining for ganglioside GD1b as a diagnostic and prognostic marker for primary human brain tumors, Neuro-oncology, 1, 261-267, (1999).
  • [5] Peciuraite, V., Vaitkeviciene, V., Grigalevicius, S., Grazulevicius J. V., Jankauskas V., Di(9-alkylcarbazol-3-yl)arylamines as electroactive amorphous materials for optoelectronics, Monatshefte für Chemie, 137, 1053-1062, (2006).
  • [6] Puodziukynaite, E., Burbulis, E., Grazulevicius, J. V., Getautis V., Jankauskas J., Carbazole-based bis(enamines) as effective charge-transporting amorphous molecular materials, Synthetic Metals, 158, 993-998, (2008).
  • [7] Mishra, A. K., Jacob J., Mullen, K., Synthesis of aminocarbazole-anthraquinone fused dyes and polymers, Dyes and Pigments, 75, 1-10, (2007).
  • [8] Gibson, H. W., Olin G. R., Pochan, J. M., Linear free energy relationships. Part 10. Synthesis, thermal, spectral, electrochemical, and hole transport (conduction) properties of some novel carbazole derivatives, Journal of Chemical Society, Perkin Transactions II, 1267-1273, (1981).
  • [9] Grigoras, M.; Antonoaia, N.C., Synthesis and characterization of some carbazolebased imine polymers, European Polymer Journal, 41, 1079-1089, (2005).
  • [10] Segura, J. L., The chemistry of electroluminescent organic materials, Acta Polymerica, 1998, 49, 319-344, (1998).
  • [11] SIR92 - Altomare, A., Cascarano, G., Giacovazzo C., Guagliardi, A., Completion and refinement of crystal structures with SIR92, Journal of Applied Crystallography, 26, 343-350, (1993).
  • [12] Sheldrick, G. M., SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, (1997).
  • [13] Farrugia, L. J., WinGX suite for small-molecule single-crystal crystallography, Journal of Applied Crystallography, 32, 837-838, (1999).
  • [14] Burkert, U., Allinger, N. L., Molecular Mechanics, ACS Monograph, No. 177 (1982).
  • [15] Allinger, N. L., Conformational analysis. 130. MM2. A hydrocarbon force field utilizing V1 and V2 torsional terms, Journal of the American Chemical Society, 99, 8127-8134, (1977).
  • [16] Dewar, M. J. S.; Zoebisch, E. G.; Healey E. F.; Stewart, J. J. P., Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model, Journal of the American Chemical Society, 107, 3902-3909, (1985).
  • [17] HyperChem 8.05 for Windows, Hypercube Inc., 1115 NW 4th Street, Gainesville, FL 32601, USA., (2008).
  • [18] Asker, E., Masnovi, J.,1,3-Bis(9-ethylcarbazol-3-yl)propane, Acta Crystallographica Section E, 61, o2781-o2783, (2005).
  • [19] Hang, Y.-C., Chen M.-D., Wang Y., 9-Ethyl-3-(2-methylbenzoyl)-9 H-carbazole, Acta Crystallographica Section E, E65, o279, (2009).
  • [20] Portilla, J., Cobo, J., de la Torre, J. M., Low J. N., Glidewell, C., N,N’- Bis(isonicotinoyl)hydrazine dihydrate at 120 (2) K: a three-dimentional framework built from N-H…O, O-H…O, O-H…N and C-H…O hydrogen bonds, Acta Crystallographica Section E, E63, o1687-o1690, (2007).
  • [21] Zheng P.-W., Zhao B., N,N’-Bis(9-anthracenylidene)hydrazine, Acta Crystallographica Section E, E62, o2077-o2078, (2006).
  • [22] Nesterov, V. V., Antipin, M. Y., Nesterov, V. N., Penn, B. G., Frazier D. O., Timofeeva T. V., Thermally stable imines as new potential nonlinear optical materials, Crystal Growth & Design, 4, 521-531, (2004).
  • [23] a) Asker E., Masnovi, J., 9,9’-Diethyl-3,3’-di-9H-carbazolyl, Acta Crystallographica Section E, 2006, E62, o1133o1135, (2006); b) Asker E.; Masnovi, Bis(-ethylcarbazol-3yl)ethane, Acta Crystallographica Section E, 2006, E62, o1213-o1215, (2006).
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA22DA72HP
Bölüm Araştırma Makalesi
Yazarlar

Ece Uzkara Bu kişi benim

Fahrettin Filiz Bu kişi benim

Orhan Zeybek Bu kişi benim

Erol Asker Bu kişi benim

Yayımlanma Tarihi 1 Aralık 2012
Gönderilme Tarihi 1 Aralık 2012
Yayımlandığı Sayı Yıl 2012 Cilt: 14 Sayı: 2

Kaynak Göster

APA Uzkara, E., Filiz, F., Zeybek, O., Asker, E. (2012). N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14(2), 7-14.
AMA Uzkara E, Filiz F, Zeybek O, Asker E. N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini. BAUN Fen. Bil. Enst. Dergisi. Aralık 2012;14(2):7-14.
Chicago Uzkara, Ece, Fahrettin Filiz, Orhan Zeybek, ve Erol Asker. “N,N’-di(9-Etil-9H-Karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14, sy. 2 (Aralık 2012): 7-14.
EndNote Uzkara E, Filiz F, Zeybek O, Asker E (01 Aralık 2012) N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14 2 7–14.
IEEE E. Uzkara, F. Filiz, O. Zeybek, ve E. Asker, “N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini”, BAUN Fen. Bil. Enst. Dergisi, c. 14, sy. 2, ss. 7–14, 2012.
ISNAD Uzkara, Ece vd. “N,N’-di(9-Etil-9H-Karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14/2 (Aralık 2012), 7-14.
JAMA Uzkara E, Filiz F, Zeybek O, Asker E. N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini. BAUN Fen. Bil. Enst. Dergisi. 2012;14:7–14.
MLA Uzkara, Ece vd. “N,N’-di(9-Etil-9H-Karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, c. 14, sy. 2, 2012, ss. 7-14.
Vancouver Uzkara E, Filiz F, Zeybek O, Asker E. N,N’-di(9-etil-9H-karbazol-3-il)hidrazinin Tek Kristal X-Işını Yapı Tayini. BAUN Fen. Bil. Enst. Dergisi. 2012;14(2):7-14.