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Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri

Yıl 2010, Cilt: 12 Sayı: 1, 112 - 135, 01.06.2010

Öz

Doğada insan, bitki ya da hayvanlara zarar veren varlıkların etkilerini önleme, yok etme, azaltma ya da bu varlıkları geri püskürtme amacıyla kullanılan kimyasal madde veya madde karışımlarına “pestisit” adı verilmektedir. Pestisitler, balık yemleri, dezenfektanlar gibi kullanımlarının yanı sıra tarımda verimi etkileyen zararlı bitki, hayvan ya da mikroorganizmalara karşı savaşta da önemli bir yere sahiptirler. Ancak bu faydalarına rağmen pestisitler insan sağlığına zararlı pek çok etkiye de sahiptirler. Bu nedenle su ve çeşitli gıda ürünlerinde (sebze, meyve vb.) pestisit kalıntılarının duyarlı bir şekilde tayin edilmesi ve bu tayin için amaca uygun ve güvenilir yöntemlerin kullanılması oldukça önemlidir. Bu çalışmada fungusit olarak kullanılan ditiyokarbamat pestisitlerinin (DC) literatürde verilen farklı tayin yöntemleri incelenmiş, yöntemlerin özellikleri ile iyi ve kötü yönleri karşılaştırılarak bu konuda toplu bir bilgi oluşması sağlanmaya çalışılmıştır

Kaynakça

  • [1] Ni, Y., Qiu, P. ve Kokot, S.,Simultaneous determination of three organophosphorus pesticides by differential pulse stripping voltammetry and chemometrics, Analytica Chimica Acta, 516, 7–17, (2004).
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  • http://www.zmo.org.tr/yayinlar/kitap_goster.php?kodu=83.
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Dithiocarbamate Pesticides and Determination Methods

Yıl 2010, Cilt: 12 Sayı: 1, 112 - 135, 01.06.2010

Öz

Chemicals or chemical mixtures used to prevent harmful influence of pests on human, animals or plants are called as pesticides. Besides their usage as fish feeds and disinfectants, they are used against various plants, animals or microorganisms that affect yield of agricultural products. However although they are beneficifial for agriculture, they have many harmful effects on human health. For this reason, determination of pesticide residues in water and various food products (vegetables and fruits etc.) by sensitive methods and using reliable and convenient methods is quite important. In this study, different determination methods of dithiocarbamate pesticides (DC) was reviewed and compared with each other

Kaynakça

  • [1] Ni, Y., Qiu, P. ve Kokot, S.,Simultaneous determination of three organophosphorus pesticides by differential pulse stripping voltammetry and chemometrics, Analytica Chimica Acta, 516, 7–17, (2004).
  • [2] Kozak, B., Pestisit kullanımı ve sorunları,.www.tarim.gen.tr, (26. 02. 2009).
  • [3] Delen, N., Durmuşoğlu, E., Güncan, A., Güngör, N., Turgut, C., Burçak, A., Türkiye’de pestisit kullanımı, kalıntı ve organizmalarda duyarlılık azalışı sorunları, Türkiye Ziraat Mühendisliği 6. Teknik Kongre, Ankara, (2005).
  • [4] EPA,.http://www.epa.gov/pesticides/,(26.02.2009).
  • [5] Durmuşoğlu, E., Tiryaki, O. ve Canhilal, R.,Türkiye'de pestisit kullanımı, kalıntı ve dayanıklılık sorunları, Ziraat Mühendisliği VII. Teknik Kongresi, Ankara (2010), http://www.zmo.org.tr/yayinlar/kitap_goster.php?kodu=82.
  • [6] PUS STATS, Pesticide Usage Statistics, (2009), http://pusstats.csl.gov.uk/myindex.cfm, (11. 03. 2010).
  • [7] National Agricultural Statistics Service, NASS: Agricultural Chemical Use Database, http://www.pestmanagement.info/nass/ ,(11. 05. 2010).
  • [8] Delen, N., Kınay, P., Yıldız, F., Yıldız, M., Altınok, H. H., Uçkun, Z., Türkiye tarımında kimyasal savaşımın durumu ve entegre savaşım olanakları, Türkiye Ziraat Mühendisliği 7. Teknik Kongre, Ankara , (2010).
  • http://www.zmo.org.tr/yayinlar/kitap_goster.php?kodu=83.
  • [9] Extoxnet, Movement of pesticides in the environment, http://extoxnet.orst.edu/tibs/movement.htm, (06. 06. 2009)
  • [10] Extoxnet, Entry and fate of chemicals in Humans, http://pmep.cce.cornell.edu/profiles/extoxnet/TIB/entry.html, (06..06.. 2009)
  • [11] EPA, Types of pesticides, http://www.epa.gov/pesticides/about/types.htm, (17. 03 . 2010).
  • [12] Beyond Pesticides, California’s Pesticide Use Declined, Yet Millions of Pounds of Toxic Pesticides Continue, (2010), http://www.beyondpesticides.org/dailynewsblog/?p=3019, (11. 03. 2010).
  • [13] Ripley, B. D. ve Cox, D. F., Residues of ethylenebis(dithiocarbamate) and ethylenethiourea in treated tomatoes and commercial tomato products, Journal of Agricultural and Food Chemistry, 26, 1137-1143, (1978).
  • [14] Guven, K., Deveci, E., Akba, O., A., Onen, Pomerai, D., The accumulation and histological effects of organometallic fungicides Propineb and Maneb in the kidneys of fetus and female rats during pregnancy, Toxicology Letters, 99, 91– 98, (1998).
  • [15] Belpoggi, F., Soffritti, M., Guariono, M., Lambertini, L., Cevolani, D., Malton, C., Results of long-term experimental studies on the carcinogenicity of ethylene-bisdithiocarbamate (Mancozeb) in rats annals, New York Academy of Sciences, 982, 123–136, (2002).
  • [16] Extoxnet, Extoxnet-PIP zineb, http://extoxnet.orst.edu/pips/zineb.htm, (06. 06. 2009).
  • [17] EPA, EPA R.E.D. Facts, http://www.epa.gov/oppsrrd1/REDs/factsheets/0641fact.pdf, (07. 06. 2009).
  • [18] Nabam, http://sitem.herts.ac.uk/aeru/footprint/en/Reports/479.htm, (07. 06. 2009).
  • [19] Osaba, L., Rey, M. J., Aguirre, A., Alonso, A., Graf, U., Evaluation of genotoxicity of captan, maneb and zineb in the wing spot test of Drosophila melanogaster: role of nitrosation, Mutation Research, 518, 95–106, (2002) .
  • [20] Humeres, E., Debacher, N. A. ve Sierra, M.M. de S., Mechanisms of acid decomposition of dithiocarbamates. 2. efficiency of the intramolecular general acid catalysis, Journal of Organic Chemistry, 64, 1807-1813, (1999).
  • [21] Marshall, W. D. ve Jarvis, W.R., Procedures for the removal of field residues of ethylenebis(dithiocarbamate) (EBDC) fungicide and ethylenethiourea (ETU) from tomatoes prior to processing into juice, Journal of Agricultural and Food Chemistry,27, 4, 766-769, (1979)
  • [22] Wang, G-J., Yin, C-M., Wang, Y., Kong, Y-H., Wang, G-H., Wu, C-Y., Zhang, LF., Liu, Z-R., The thermal behaviour of ethylene-bis dithiocarbamates maneb, zineb and mancozeb. Part 1. The mechanism of the thermal decomposition, Thermochimica Acta, 220, 213-227, (1993).
  • [23] Nash, R. G., Uptake of ethylenebis(dithiocarbamate) fungicides and ethylenethiourea by soybeans, Journal of Agricultural and Food Chemistry, 24, 3, 596-601, (1976).
  • [24] Rhodes, R. C., Studies with manganese [14C]ethylenebis(dithiocarbamate) ([14C]maneb) fungicide and [14C]ethylenethiourea ([14C]ETU) in plants, soil, and water, Journal of Agricultural and Food Chemistry, 25, 3, 528-533, (1977).
  • [25] Knio, K. M., Dagher, S. ve Saad,A.,The fate and persistence of zineb, maneb, and ethylenethiourea on fresh and processed tomatoes, Food Additives & Contaminants, 17, 5, 393 – 398, (2000).
  • [26] Marshall W. D., Thermal decomposition of ethylenebis(dithiocarbamate) fungicides to ethylenethiourea in aqueous media, Journal of Agricultural and Food Chemistry, 25, 2, 357-361, (1977).
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Toplam 80 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA22DF36AU
Bölüm Araştırma Makalesi
Yazarlar

Özlem Karakoç Bu kişi benim

Nuri Nakiboğlu Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2010
Gönderilme Tarihi 1 Haziran 2010
Yayımlandığı Sayı Yıl 2010 Cilt: 12 Sayı: 1

Kaynak Göster

APA Karakoç, Ö., & Nakiboğlu, N. (2010). Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 12(1), 112-135.
AMA Karakoç Ö, Nakiboğlu N. Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri. BAUN Fen. Bil. Enst. Dergisi. Haziran 2010;12(1):112-135.
Chicago Karakoç, Özlem, ve Nuri Nakiboğlu. “Ditiyokarbamat Pestisitleri Ve Tayin Yöntemleri”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 12, sy. 1 (Haziran 2010): 112-35.
EndNote Karakoç Ö, Nakiboğlu N (01 Haziran 2010) Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 12 1 112–135.
IEEE Ö. Karakoç ve N. Nakiboğlu, “Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri”, BAUN Fen. Bil. Enst. Dergisi, c. 12, sy. 1, ss. 112–135, 2010.
ISNAD Karakoç, Özlem - Nakiboğlu, Nuri. “Ditiyokarbamat Pestisitleri Ve Tayin Yöntemleri”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi 12/1 (Haziran 2010), 112-135.
JAMA Karakoç Ö, Nakiboğlu N. Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri. BAUN Fen. Bil. Enst. Dergisi. 2010;12:112–135.
MLA Karakoç, Özlem ve Nuri Nakiboğlu. “Ditiyokarbamat Pestisitleri Ve Tayin Yöntemleri”. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, c. 12, sy. 1, 2010, ss. 112-35.
Vancouver Karakoç Ö, Nakiboğlu N. Ditiyokarbamat Pestisitleri ve Tayin Yöntemleri. BAUN Fen. Bil. Enst. Dergisi. 2010;12(1):112-35.