Adsorption kinetics of montmorillonite clay and basic orange 2 dyestuff

Yıl 2022, Cilt: 24 Sayı: 2, 555 - 566, 08.07.2022

Baybars Ali Fil

Öz

In this study, the adsorption kinetics of BO2 (Basic Orange2) dyestuff on montmorillonite clay was investigated. The experiments were carried out in batch mode. Adsorption kinetics studies were investigated under the influence of parameters such as initial dyestuff concentration, initial pH value, mixing speed, adsorbent dose and ion concentration. The compatibility of the experimental data with pseudo-first-order, pseudo-second-order, Elovich and intra-particle adsorption kinetic models were investigated. It was determined that the adsorption kinetic data of BO2 dyestuff on the montmorillonite surface were consistent with the pseudo-second order kinetics. It was determined that the adsorption rate increased with increasing pH, mixing speed and ion concentration, and decreased with the initial dye concentration and adsorbent dose. It reveals that montmorillonite is a suitable low-cost adsorbent for the removal of cationic dyestuffs such as BO2.

Anahtar Kelimeler

Montmorillonite, Adsorption kinetic, basic orange2 (BO2)

Montmorillonit kili ile basic orange 2 boyar maddesinin adsorpsiyon kinetiği

Öz

Bu çalışmada, BO2 (Basic Orange2) boyar maddesinin montmorillonit kili üzerinde adsorpsiyon kinetiği araştırılmıştır. Deneyler kesikli modda gerçekleştirilmiştir. Adsorpsiyon kinetiği çalışmaları başlangıç boyar madde konsantrasyonu, başlangıç pH değeri, karıştırma hızı, adsorbent dozu ve iyon konsantrasyonu gibi parametrelerin etkisi altında araştırılmıştır. Deneysel verilerin yalancı birinci mertebe, yalancı ikinci mertebe, Elovich ve parçacık içi adsorpsiyon kinetik modellerine uyumluluğu araştırılmıştır. Montmorillonit yüzeyinde BO2 boyar maddesinin adsorpsiyon kinetiğini verilerinin yalancı ikinci mertebe kinetiğine uyum gösterdiği belirlenmiştir. Adsorpsiyon hızının artan pH, karıştırma hızı ve iyon konsantrasyonu ile arttığı, başlangıç boyar madde konsantrasyonu ve adsorbent dozu ile azaldığı belirlenmiştir. Montmorillonitin BO2 gibi katyonik boyar maddelerin uzaklaştırılması için uygun düşük maliyetli adsorbent olduğunu ortaya koymaktadır.

Anahtar Kelimeler

Montmorillonit, Adsorpsiyon kinetiği, basic orange2 (BO2)

Kaynakça

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